Synthesis and Thermal Properties of Cobalt-Doped Hydroxyapatite Nanoparticles with Controlled Morphological Parameters

Russian Journal of General Chemistry - Cobalt-doped hydroxyapatite nanoparticles with various morphological parameters were obtained, and the effect of the dopant concentration and nanoparticle...     

Synthesis of bimetallic nanoparticles based on cobalt and nickel. Effects of their composition and structure on catalytic and magnetic properties

Russian Journal of General Chemistry - Bimetallic core-shell nanoparticles Co@Ni and Ni@Co and CoNi alloy ones have been prepared via polyol synthesis. Comparison of morphology, magnetic, and...     

Approaches to the Control of Morphological Parameters of Inorganic Nanoparticles in the Synthesis from Solutions

Russian Journal of General Chemistry - General regularities of nanoparticles formation from solutions under various conditions (organic and aqueous media, mild and rigid conditions) are presented...     

Superparamagnetism of magnetite nanoparticles: dependence on surface modification

Superparamagnetic iron oxide nanoparticles (SPION) with an average particle diameter of 6 nm are prepared by controlled chemical coprecipitations. Colloidal suspensions of noninteracting SPION, where the surface has been modified with three different types of biocompatible substances, namely, starch, gold (Au), and methoxypoly(ethylene glycol) (MPEG) have been fabricated via three different techniques. Starch-coated SPION are prepared by coprecipitation in a polymeric matrix, Au-coated SPION are fabricated by the microemulsion method, and MPEG-coated SPION are prepared using the self-assembly approach. The magnetic nanoparticles form a core-shell structure, and the magnetic dipole-dipole interactions are screened by a layer of coating agents. The amounts of coating agents and SPION are indirectly calculated from the thermogravimetric analysis and superconducting quantum interference device measurements by assuming passive oxidation on the surface of the SPION, and the other conditions do not influence the measurements. The dependency of the spectral characteristics of M?ssbauer spectroscopy as a function of an external magnetic field Hext is measured to investigate the effect of dipole-dipole screening of the different coating layers on the SPION. Uncoated SPION show a stable magnetic moment under Hext, and the superparamagnetic (SPM) fraction transforms to a ferrimagnetic state. Starch and Au-coated SPION retain the SPM fraction according to M?ssbauer spectroscopy and magnetization measurements. MPEG-coated SPION show hyperfine magnetic structure without the quadrupole effect with increasing the value of the blocking temperature.