全文获取类型
收费全文 | 1724篇 |
免费 | 90篇 |
国内免费 | 26篇 |
专业分类
化学 | 1035篇 |
晶体学 | 5篇 |
力学 | 87篇 |
数学 | 299篇 |
物理学 | 414篇 |
出版年
2024年 | 5篇 |
2023年 | 14篇 |
2022年 | 31篇 |
2021年 | 45篇 |
2020年 | 82篇 |
2019年 | 55篇 |
2018年 | 59篇 |
2017年 | 46篇 |
2016年 | 113篇 |
2015年 | 84篇 |
2014年 | 103篇 |
2013年 | 138篇 |
2012年 | 149篇 |
2011年 | 157篇 |
2010年 | 110篇 |
2009年 | 71篇 |
2008年 | 73篇 |
2007年 | 88篇 |
2006年 | 80篇 |
2005年 | 57篇 |
2004年 | 56篇 |
2003年 | 40篇 |
2002年 | 37篇 |
2001年 | 20篇 |
2000年 | 9篇 |
1999年 | 4篇 |
1998年 | 10篇 |
1997年 | 7篇 |
1996年 | 12篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 5篇 |
1977年 | 2篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 8篇 |
1973年 | 4篇 |
1969年 | 2篇 |
1930年 | 1篇 |
1925年 | 1篇 |
排序方式: 共有1840条查询结果,搜索用时 15 毫秒
81.
Shamsabadi Amir Shahin Tavanai Hossein Ranjbar Mehdi 《Journal of Cluster Science》2021,32(5):1121-1127
Journal of Cluster Science - This work reports on the outcome of the calcination of gold nanoparticles incorporated polyacrylonitrile nanofibers in air which results in the formation of gold... 相似文献
82.
Omer Anis Ajjampura C. Vinayaka Nurit Shalev Dvora Namdar Stalin Nadarajan Seegehalli M. Anil Ofer Cohen Eduard Belausov Jacob Ramon Einav Mayzlish Gati Hinanit Koltai 《Molecules (Basel, Switzerland)》2021,26(2)
Cannabis sativa contains more than 500 constituents, yet the anticancer properties of the vast majority of cannabis compounds remains unknown. We aimed to identify cannabis compounds and their combinations presenting cytotoxicity against bladder urothelial carcinoma (UC), the most common urinary system cancer. An XTT assay was used to determine cytotoxic activity of C. sativa extracts on T24 and HBT-9 cell lines. Extract chemical content was identified by high-performance liquid chromatography (HPLC). Fluorescence-activated cell sorting (FACS) was used to determine apoptosis and cell cycle, using stained F-actin and nuclei. Scratch and transwell assays were used to determine cell migration and invasion, respectively. Gene expression was determined by quantitative Polymerase chain reaction (PCR). The most active decarboxylated extract fraction (F7) of high-cannabidiol (CBD) C. sativa was found to contain cannabichromene (CBC) and Δ9-tetrahydrocannabinol (THC). Synergistic interaction was demonstrated between CBC + THC whereas cannabinoid receptor (CB) type 1 and type 2 inverse agonists reduced cytotoxic activity. Treatments with CBC + THC or CBD led to cell cycle arrest and cell apoptosis. CBC + THC or CBD treatments inhibited cell migration and affected F-actin integrity. Identification of active plant ingredients (API) from cannabis that induce apoptosis and affect cell migration in UC cell lines forms a basis for pre-clinical trials for UC treatment. 相似文献
83.
We identify periodic solitons in nonlocal nonlinear media: multi-hump soliton solutions propagating in a fully periodic fashion. We also demonstrate recurrences and breathers whose evolution is statistically periodic and discuss why some systems support periodic solitons while others do not. 相似文献
84.
Safari Nasimeh Imanzadeh Gholamhassan Asgharzadeh Roghayyeh Hosseyni Seyyedeh Tahereh Shamkhali Amir Nasser Soltanzadeh Zahra 《Chemistry of Heterocyclic Compounds》2021,57(6):640-645
Chemistry of Heterocyclic Compounds - In this work, new pyrazole derivatives were prepared by one-pot three-component reaction emloying symmetric and asymmetric 1,2-disulfonyl-hydrazines,... 相似文献
85.
Sushant G. Ghosh Muhammed Amir 《The European Physical Journal C - Particles and Fields》2015,75(11):553
We investigate the horizon structure and ergosphere in a rotating Bardeen regular black hole, which has an additional parameter (g) due to the magnetic charge, apart from the mass (M) and the rotation parameter (a). Interestingly, for each value of the parameter g, there exists a critical rotation parameter (\(a=a_{E}\)), which corresponds to an extremal black hole with degenerate horizons, while for \(a<a_{E}\) it describes a non-extremal black hole with two horizons, and no black hole for \(a>a_{E}\). We find that the extremal value \(a_E\) is also influenced by the parameter g, and so is the ergosphere. While the value of \(a_E\) remarkably decreases when compared with the Kerr black hole, the ergosphere becomes thicker with the increase in g. We also study the collision of two equal mass particles near the horizon of this black hole, and explicitly show the effect of the parameter g. The center-of-mass energy (\(E_\mathrm{CM}\)) not only depend on the rotation parameter a, but also on the parameter g. It is demonstrated that the \(E_\mathrm{CM}\) could be arbitrarily high in the extremal cases when one of the colliding particles has a critical angular momentum, thereby suggesting that the rotating Bardeen regular black hole can act as a particle accelerator. 相似文献
86.
Elnaz Khalilzadeh Amir Chakhmachi Behrouz Maraghechi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2015,69(11):256
The influence of self-fields on the cyclotron maser instability in a hollow electron beam propagating parallel to a uniform axial magnetic field B 0 ê z in a dielectric loaded waveguide is investigated. The theoretical analysis is carried out within the framework of linearized Vlasov-Maxwell equations. It is assumed that the beam is thin with the radial thickness much smaller than the beam radius. A new dispersion relation for azimuthally symmetric electromagnetic perturbation is derived and analyzed numerically. The influence of self-fields on the cyclotron maser instability in a dielectric loaded waveguide for different dielectric medium is studied. It is found that unlike the hollow waveguide the growth rate is increased by increasing self-fields. The instability band width decreases due to the increasing self-fields. The maximum growth rate increases gradually as self-fields increase as regards a different dielectric medium. 相似文献
87.
Amir Beheshti Mehdi Shanbedi Saeed Zeinali Heris 《Journal of Thermal Analysis and Calorimetry》2014,118(3):1451-1460
Power transformers play a key role in power and electrical industries and thus boosting their efficiency is necessary. In this study, the effect of oxidized multi-walled carbon nanotubes on transformer oil thermophysical properties was experimentally investigated. The maximum amount of carbon nanotubes was chosen up to 0.01 mass% to assure the maximum purity of transformer oil. Heat transfer characteristics of transformer oil and nanofluids in two cases of free and forced convection were studied. Breakdown voltage, flash point, pour point, density, electrical and thermal conductivities, viscosity and shear stress, as eight important quality parameters, were determined. According to the experimental results, the Breakdown voltage decreased through concentration increasing. Electrical conductivity is not changed considerable with increasing concentration and temperature. Thermal conductivity of nanofluids and transformer oil changed with increasing temperature and concentration. Furthermore, at all concentrations and temperatures, the viscosity of the nanofluids was lower than that of transformer oil. 相似文献
88.
Enantioselective Synthesis of Boron‐Substituted Quaternary Carbon Stereogenic Centers through NHC‐Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones 下载免费PDF全文
Suttipol Radomkit Prof. Amir H. Hoveyda 《Angewandte Chemie (International ed. in English)》2014,53(13):3387-3391
The first examples of Lewis base catalyzed enantioselective boryl conjugate additions (BCAs) that generate products containing boron‐substituted quaternary carbon stereogenic centers are disclosed. Reactions are performed in the presence of 1.0–5.0 mol % of a readily accessible chiral accessible N‐heterocyclic carbene (NHC) and commercially available bis(pinacolato)diboron; cyclic or linear α,β‐unsaturated ketones can be used and rigorous exclusion of air or moisture is not necessary. The desired products are obtained in 63–95 % yield and 91:9 to >99:1 enantiomeric ratio (e.r.). The special utility of the NHC‐catalyzed approach is demonstrated in the context of an enantioselective synthesis of natural product antifungal (?)‐crassinervic acid. 相似文献
89.
Dr. Dorian Didier Dr. Pierre‐Olivier Delaye Marwan Simaan Biana Island Dr. Guillaume Eppe Dr. Hendrik Eijsberg Amir Kleiner Prof. Dr. Paul Knochel Prof. Dr. Ilan Marek 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(4):1038-1048
The copper‐catalyzed carbomagnesiation reaction of cyclopropenyl esters 1 leads to various substituted cyclopropanes species 3 in good yields with very high diastereoselectivities. The reaction proceeds through a syn‐chelated carbomagnesiation reaction and could be extended to various cyclopropenylmethyl ester derivatives 5 . The potential of this approach was illustrated by the preparation of two consecutive all‐carbon quaternary stereocenters. However, the carbometalation reaction needs to be performed at temperature ranging from ?35 to ?20 °C to avoid subsequent fragmentation reaction into stereodefined β,γ‐nonconjugated unsaturated esters 4 . Alternatively, the carbocupration reaction with organocopper species could also be performed to leads to configurationally stable cyclopropyl copper species 2[Cu] . Additionally, when the Lewis acid character of the copper center is decreased (i.e., RCuCNLi), the reaction proceed with an anti‐selectivity. The diastereodivergent behavior of these organometallic species is of synthetic interest, since both diastereomers syn‐ 3 and anti‐ 3 can be obtained, at will, from the same precursor cyclopropenyl esters 1 . 相似文献
90.
Shahrzad Abdolmohammadi Shahab Shariati Narges Elmi Fard Amir Samani 《Journal of heterocyclic chemistry》2020,57(7):2729-2737
In this work, a series of eight new spiro[3,4′]1,3-dihydro-2H-indol-2-one-2′-amino-4′,6′,7′,8′-tetrahydro-2′,5’(1’H,3’H)-quinazoline-diones were successfully synthesized through a three-component reaction of 1H-indole-2,3-diones (isatins), guanidine nitrate, and 1,3-cyclohexanediones, by use of Kit-6 mesoporous silica coated Fe3O4 nanoparticles (Fe3O4@SiO2@KIT-6) as a highly efficient magnetically separable nanocatalyst in aqueous media at 60°C. Several notable features of thiseco-friendly protocol are high yields of products, short reaction times, operational simplicity, and the use of easily available and recyclable catalyst. 相似文献