The onset of ultrashort pulse‐induced nanogratings

The fundamental formation process of nanogratings induced by focused ultrashort laser pulses inside the bulk of transparent materials is still object of intense debate. In particular the initial evolutionary steps, including the formation of anisotropic pores, alignment and arrangement in highly periodic grating planes could not been clarified up to now. To this end we have performed a comprehensive investigation of this process by optical retardance measurements, small‐angle X‐ray scattering, and focused ion beam milling in combination with scanning electron microscopy. The results show that the formation of nanogratings starts with isotropic, deterministic voids after the first incident laser pulse which start to elongate perpendicular to the laser scan direction with further illumination and the appearance of cracks along the scan direction. For increasing pulse overlap these cracks as well as randomly aligned voids build the template for the subsequent pore growth perpendicular to the laser polarization. The process of grating formation and subsequent period reduction occurs via increasing number of sheets and mutual realignment forming a more porous glass matrix.

     

Photo-cross-linkable polyelectrolyte multilayers for 2-D and 3-D patterning

We report the synthesis of poly(acrylic acid-ran-vinylbenzyl acrylate) (PAArVBA), a photo-cross-linkable weak polyelectrolyte, and its incorporation into polyelectrolyte multilayer (PEM) films. PEM films assembled from PAArVBA and poly(allylamine hydrochloride) (PAH) are found to exhibit similar thickness trends with assembly pH as those previously reported for poly(acrylic acid) (PAA)/PAH multilayers. Swelling properties of the as-built and photo-cross-linked films are studied by in situ ellipsometry. Two-dimensional masking techniques are used to pattern regions of high and low swelling, as confirmed by atomic force microscopy (AFM), and to provide spatial control over the low-pH-induced microporosity transition exhibited by PAH/PAA PEMs. Films containing alternating blocks of PAH/PAArVBA bilayers and PAH/PAA bilayers were assembled, laterally photopatterned, and exposed to low-pH solution to generate nanoporosity leading to patterned Bragg reflectors, thereby demonstrating three-dimensional control over film structure in these weak PEM assemblies.     

Enhanced responsivity of non-steady-state photoinduced electromotive force sensors using asymmetric interdigitated contacts

The responsivity at a constant detection area of non-steady-state photoinduced electromotive force (photo-emf) detectors is improved by a factor equal to the number of contact pairs contained in asymmetric interdigitated surface contacts. The polar nature of photo-emf current generation requires contact asymmetry in which one increases the total signal by blocking the illumination between alternate contact pairs, in distinct contrast to the behavior of conventional interdigitated contacts fabricated upon isotropic photoconductors.     

Nanostructuring with spatially localized femtosecond laser pulses

Spatially localized femtosecond pulses have been produced by a combination of scanning near-field optical microscopy with ultrashort pulse lasers. With these pulses direct ablative writing on metal surfaces is demonstrated. Possible applications of this technique for nanostructuring, repair, and production of lithographic masks are discussed.     

Oscillatory mode coupling and electrically strobed gratings in photorefractive quantum-well diodes

Oscillatory mode coupling between two coherent laser beams is produced when an interference pattern moves against a quasi-static electrically strobed grating in a photorefractive AlGaAs/GaAs multiple-quantum-well diode operated in the quantum-confined Stark geometry. The oscillation frequency is equal to the frequency difference between the two laser beams and provides a method to measure high-frequency Doppler shifts or large surface displacements for laser-based ultrasound. Combined photorefractive gains (normally forbidden by symmetry in the Stark geometry) and absorptive gains approach 1200cm(-1)during two-wave mixing using moving gratings.