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排序方式: 共有1038条查询结果,搜索用时 187 毫秒
61.
A simple method for the preparation of enantiopure furo[2,3-b]pyrroles, a rare class of concave bicyclic nitrogen and oxygen heterocycle, in promising yield has been developed. The 3-substituted pyrrolidinediones prepared from (2S,3S)-tetrahydro-3-hydroxy-5-oxo-2,3-furandicarboxylic acid (Garcinia acid) have been cyclized diastereo as well as enantioselectively to furo[2,3-b]pyrroles. The cyclization follows Baldwin’s rule. 相似文献
62.
The vibrational spectral studies of the semi-organic material l- arginine acetate (LAA) are carried out with the help of density functional calculations to derive the equilibrium geometry as well as the vibrational wavenumbers and intensities of the spectral bands. The vibrational spectrum assignments are performed using normal coordinate analysis (NCA) in accordance with the scaled quantum mechanical force field approach (SQMFF). Vibrational spectra confirm the COO- modes split due to intra- and intermolecular association based on C–O….H, N–H….O, and O–H?O hydrogen bonding in the molecule, which lowers carboxylate wavenumbers. The natural bond orbital (NBO) analysis and DFT computations also confirm the occurrence of strong intra and intermolecular N–H?O and O–H?O ionic hydrogen bonding between charged species, providing the non-centrosymmetric structure in the LAA crystal. 相似文献
63.
Satheesh Chandran M Temina Mary Robert Sunitha K Dona Mathew C. P. Reghunadhan Nair 《先进技术聚合物》2014,25(8):881-890
This paper outlines the synthesis and characterization of O‐allyl aralkyl phenolic (O‐allyl Xylok, OAX) resins having low melt viscosity and its Alder‐ene blends with 2, 2′‐bis 4‐[(4′‐maleimido phenoxy) phenyl] propane. The blends manifested a three‐stage curing pattern that converged to a two‐stage pattern on enhancing the maleimide content. The polymerization kinetics of typical allyl and maleimide rich resin systems showed apparent activation energy increasing and pre‐exponential factor decreasing from ene to the Diels–Alder step. Increased allyl content improved mechanical and impact properties of the composites at ambient temperature, although it diminished the retention of interlaminar shear strength at elevated temperature. Increased maleimide content of the resin was conducive for the higher rigidity for the composite and its retention at elevated temperature. A substantial increase in Tg (from 153°C to 280°C) and thermal stability was observed with an increase in maleimide content. High allyl content resulted in improved mechanical properties thanks to better resin–reinforcement interaction as revealed from morphological analysis. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
64.
Priyadarsini Sreenivasan Jijo Wilson Prabha Damodaran Nair Lynda Velutheril Thomas 《先进技术聚合物》2020,31(5):1139-1149
This work reports a novel fabrication technique for development of channels on paper‐based microfluidic devices using the syringe module of a 3D printing syringe–based system. In this study, printing using polycaprolactone (PCL)‐based ink (Mw 70 000‐90 000) was employed for the generation of functional hydrophobic barriers on Whatman qualitative filter paper grade 1 (approximate thickness of 180 μm and pore diameter of 11 μm), which would effectively channelize fluid flow to multiple assay zones dedicated for different analyte detection on a microfluidic paper‐based analytical device (μPAD). The standardization studies reveal that a functional hydrophilic channel for sample conduction fabricated using the reported technique can be as narrow as 460.7 ± 20 μm and a functional hydrophobic barrier can be of any width with a lower limit of about 982.2 ± 142.75 μm when a minimum number of two layers of the ink is extruded onto paper. A comparison with the hydrodynamic model established for writing with ink is used to explain the width of the line printed by this system. A fluid flow analysis through a single channel system was also carried out to establish its conformity with the Washburn model, which governs the fluid flow in two‐dimensional μPAD. The presented fabrication technique proves to be a robust strategy that effectively taps the advantages of this 3D printing technique in the production of μPADs with enhanced speed and reproducibility. 相似文献
65.
A class of new benchmark deformational flow test cases for the two-dimensional horizontal linear transport problems on the sphere is proposed. The scalar field follows complex trajectories and undergoes severe deformation during the simulation; however, the flow reverses its course at half-time and the scalar field returns to its initial position and shape. This process makes the exact solution available at the end of the simulation, and facilitates assessment of the accuracy of the underlying transport scheme. A procedure to eliminate possible cancellations of errors when the flow reverses is proposed. 相似文献
66.
Nair Supriya Aswathy UV Mathew Ann Raghavan Rajeev 《Journal of Thermal Analysis and Calorimetry》2017,128(3):1731-1741
Journal of Thermal Analysis and Calorimetry - Thermal decomposition, thermal conductivity, specific heat and flammability of polydimethyl siloxane (PDMS) resin and three PDMS-based systems with... 相似文献
67.
Deepa Sathian Rupali Rohatgi V. Jayalakshmi P. K. Marathe Sarala Nair R. V. Kolekar G. Chourasiya S. Kannan 《Indian Journal of Physics》2009,83(6):863-869
CR-39 Solid State Nuclear Track Detecting foils (SSNTD), along with 1 mm thick polyethylene radiator, sealed in triple laminated
pouches, are used for country wide Fast Neutron Personnel Monitoring in India. With the present system of processing by elevated
temperature electrochemical etching (ETECE) and evaluation using automatic image analysis, only 16 foils are processed at
a time and it is useful over the dose equivalent range 0.2 mSv to 10 mSv. It has been reported that, by processing CR-39 of
good detection efficiency by chemical etching at elevated temperature, more numbers of foils can be processed simultaneously.
In the present study, CR-39 foils from Pershore Moulding (UK) have been chemically etched using 7 N KOH under various conditions
of temperature and etching durations and evaluated using high magnification microscope. The duration of chemical etching,
has been optimized at a constant temperature of 60°C for chemical etching process. The characteristics of the chemically etched
CR-39 foils are compared with the characteristics of the CR-39 foils processed by the existing system of ETECE and the detailed
results are presented in the full text of the paper. It has been observed that by chemical etching process, the dose equivalent
range of CR-39 foils can be extended above 60 mSv.
相似文献
68.
Guy Patchornik Irishi N.N. NamboothiriDivya K. Nair Ellen WachtelSidney R. Cohen Noga FriedmanMordechai Sheves 《Journal of colloid and interface science》2012,388(1):300-305
A strategy for clustering of native lipid membranes is presented. It relies on the formation of complexes between hydrophobic chelators embedded within the lipid bilayer and metal cations in the aqueous phase, capable of binding two (or more) chelators simultaneously Fig. 1. We used this approach with purple membranes containing the light driven proton pump protein bacteriorhodopsin (bR) and showed that patches of purple membranes cluster into mm sized aggregates and that these are stable for months when incubated at 19 °C in the dark. The strategy may be general since four different hydrophobic chelators (1,10-phenanthroline, bathophenanthroline, Phen-C10, and 8-hydroxyquinoline) and various divalent cations (Ni2+, Zn2+, Cd2+, Mn2+, and Cu2+) induced formation of membrane clusters. Moreover, the absolute requirement for a hydrophobic chelator and the appropriate metal cations was demonstrated with light and atomic force microscopy (AFM); the presence of the metal does not appear to affect the functional state of the protein. The potential utility of the approach as an alternative to assembled lipid bilayers is suggested. 相似文献
69.
[reaction: see text]. A facile one-pot synthesis of 1-amino-4-aryl-tetralin derivatives by the CAN-induced cyclodimerization of various styrenes in acetonitrile and acrylonitrile is described. 相似文献
70.
Suppose denote the ergodic averages for the natural numbers . Let denote the corresponding maximal function and let for . We show that for if there exists such that then there exists such that . Similar weak (1,1) inequalities follow for V
q
when you know them for M too also with q > 1. We also show this fails completely if q= 1. We also show that for certain polynomial like and random sequences , if
and
is of exponential growth then
for a certain positive constant C.
(Received 11 February 1998; in revised form 10 December 1998) 相似文献