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991.
M. N. Vidyakin Yu. N. Lazareva Yu. P. Yampolskii A. Yu. Alentiev D. Yu. Likhachev A. L. Rusanov O. V. Kozlova 《Polymer Science Series A》2006,48(6):596-600
The correlation between chemical structure and gas transport properties is considered for a new class of membrane materials based on structurally similar polyphenylquinoxalines that are characterized by different numbers of flexible-O-ether bonds in the repeating unit and different chain rigidities. Permeability, diffusion, and solubility coefficients have been estimated for the gases H2, He, O2, N2, CO, CO2, and CH4; separation factors for various gas pairs have been determined. For the materials with a similar level of cohesive energy density, which characterizes interchain interactions, permeability decreases with a decrease in chain rigidity, whereas selectivity of gas separation increases. 相似文献
992.
This study has investigated the effect of shelf aging, for up to one year in air, on the properties of gamma-irradiated ultra-high molecular weight polyethylene (UHMWPE). A variety of techniques were used to characterize the properties of treated samples. Differential scanning calorimetery (DSC) was used to characterize the morphology. The extent of cross-linking in a polymer network was detected by swelling measurements. The durometer hardness test was used to measure the relative hardness of this material, and changes in density were also measured. Results from all these measurements were combined to explain the changes in the microstructure of the aged, irradiated UHMWPE. This study shows that crystallinity is increased with radiation dose and with aging due to chain scission, which leads to a reduction in the molecular weight of the material. This allows the chains to rearrange to form crystalline regions. Positron annihilation lifetime spectroscopy confirms these conclusions. Fractional free volumes have been deduced from lifetime parameters, which correlate with the data obtained by the other techniques. 相似文献
993.
994.
E. Ya. Paryev 《Physics of Atomic Nuclei》2006,69(2):332-354
Within the spectral function approach, we study the direct production and decay via the dikaon (dimuon) channel of ϕ mesons
in the interactions of 2.4-and 2.7-GeV protons with light and medium target nuclei. It is shown that the K
+
K
− (μ+ μ−) invariant-mass distribution consists of the two components, which correspond to the ϕ decay “outside” and “inside” the target nucleus. The first (narrow) component has the free ϕ width, while the second (broad) component is distorted by the nuclear matter owing to resonance-nucleon scattering and a
possible in-medium modification of the kaons and ρ meson at finite baryon density. The relative strength of the “inside” and “outside” components is analyzed in different scenarios
for the ϕ width and momentum cut. It is demonstrated that the width of the resulting dimuon invariant-mass distribution on medium nuclei
is larger than the free ϕ width by a factor of about 2 if the total ϕ in-medium width is used and the respective cutoff for the ϕ three-momentum is applied, whereas the resulting dikaon invariant-mass distribution has an insignificant sensitivity to the
ϕ in-medium properties owing to the strong absorption of the K
− in the surrounding nuclear matter. On the other hand, because of the distortion of the K
+ and K
− on their way out of the target nucleus mainly due to the hadronic kaon potentials, the latter distribution is broadened and
shifted to higher invariant masses, which means that the measurement of such broadening would give additional evidence for
the modification of the kaon and antikaon properties in the nuclear medium.
The text was submitted by the author in English. 相似文献
995.
E. D. Mishina N. É. Sherstyuk V. O. Val’dner A. V. Mishina K. A. Vorotilov V. A. Vasil’ev A. S. Sigov M. P. De Santo E. Cazzanelli R. Barberi Th. Rasing 《Physics of the Solid State》2006,48(6):1210-1213
Ferroelectric composite two-dimensional ferroelectric/aluminum oxide nanostructures were studied. A porous aluminum oxide matrix was used as a template into which a ferroelectric precursor was introduced, followed by annealing. The prepared nanostructures were studied using optical second harmonic generation and micro-Raman scattering. 相似文献
996.
L. I. Bryukvina E. A. Ermolaeva S. N. Pidgurskiĭ L. F. Suvorova V. M. Khulugurov 《Physics of the Solid State》2006,48(1):68-72
It was detected for the first time that films consisting of a transition-metal-based structure form (via thermal diffusion
of intracrystalline impurities) on the surface of alkali-halide (LiF, NaF) crystals activated by transition metals Co, Ni,
or Mn. The thickness, density, and composition of the films are shown to be different, depending on the heat treatment conditions.
The crystals were annealed at temperatures varying from 473 to 1073 K in vacuum and air. The surface structures forming upon
annealing in vacuum exhibit magnetic properties. The films were studied by optical, x-ray fluorescence, and electron spectroscopy
to reveal the mechanisms of transition-metal film formation during thermal annealing. 相似文献
997.
998.
999.
We fabricated high-quality InAlN/GaN heterostructures by metal–organic vapor phase epitaxy (MOVPE). X-ray diffraction measurements revealed that InAlN/GaN heterostructures grown under optimal conditions have flat surfaces and abrupt heterointerfaces. Electron mobility from 1200 to 2000 cm2/V s was obtained at room temperature. To our knowledge, this mobility is the highest ever reported for InAlN/GaN heterostructures. We also investigated the relationship between the Al composition and sheet electron density (Ns) for the first time. Ns increased from 1.0×1012 to 2.7×1013 cm−2 when the Al composition increased from 0.78 to 0.89. 相似文献
1000.
N. Raju T. Špaček J. Ježek I. M. Caminiti F. Leinisch K. Hideg P. Ježek W. E. Trommer 《Applied magnetic resonance》2006,30(3-4):373-383
Electron paramagnetic resonance (EPR) spectroscopy of spin-labeled fatty acids was used to investigate their interaction withEscherichia coli-expressed human mitochondrial uncoupling protein UCP2 refolded from inclusion bodies in nonaethylene glycol monododecyl ether (C12E9) micelles. 5-DOXYL-stearic acid and 4-PROXYL-palmitic acid bound to UCP2 exhibited additional clearly separated h+1I, h?1I “immobile” peaks in the low- and high-field region, respectively, separated by 42 and 44 Gauss, and extensively reduced h+1M, h?1M “mobile” peaks, separated by about 30 G, whereas with 7-DOXYL-stearic acid the I and M peaks were smoothed together into one wide peak. Competition of 4-PROXYL-palmitic acid with added palmitic acid, arachidonic acid, and all-cis-8,11,14-eicosatrienoic acid and of 7-DOXYL-stearic acid with arachidonic acid was indicated by the disappearance of the h+1I, h?1I “immobile” peaks, whereas redistribution in micelles without protein was indicated by the rising of the h+1M, h?1M “mobile” peaks. In conclusion, a competition of palmitic, arachidonic, and eicosatrienoic acid within a putative fatty acid binding site was observed for mitochondrial uncoupling protein UCP2. This finding together with the observation of EPR spectra of highly immobilized probes exclusively in the presence of the recombinant UCP2 suggest the existence of a fatty acid binding site on UCP2 which is a prerequisite of the fatty acid cycling mechanism as previously postulated for UCP1. 相似文献