Ultrasonic butt welding of aluminum,aluminum alloy and stainless steel plate specimens

Welding characteristics of aluminum, aluminum alloy and stainless steel plate specimens of 6.0 mm thickness by a 15 kHz ultrasonic butt welding system were studied. There are no detailed welding condition data of these specimens although the joining of these materials are required due to anticorrosive and high strength characteristics for not only large specimens but small electronic parts especially. These specimens of 6.0 mm thickness were welded end to end using a 15 kHz ultrasonic butt welding equipment with a vibration source using eight bolt-clamped Langevin type PZT transducers and a 50 kW static induction thyristor power amplifier. The stainless steel plate specimens electrolytically polished were joined with welding strength almost equal to the material strength under rather large vibration amplitude of 25 microm (peak-to-zero value), static pressure 70 MPa and welding time of 1.0-3.0 s. The hardness of stainless steel specimen adjacent to a welding surface increased about 20% by ultrasonic vibration.     

Phonon effects on oscillator strengths and ƒ-sum of a defect center

We first propose a simple method to deal with the electron-phonon interaction for all states involved in optical transitions and then use the results obtained to derive the equations of the oscillator strengths ? and ?-sum for a defect center including the phonon effects adequately. The derived results are applied to the F center in KCl and discussed in relation to those excluding the dynamical phonon effect.     

Photosensitized oxygenation of phenylpyruvic acid derivatives as a model for p-hydroxyphenylpyruvate dioxygenase

Dye-sensitized photooxygenation of enol ethers of methyl phenylpyruvates ($\text{3}$) produced diendoperoxides $\text{4}$ in aprotic solvents, whereas in methanol hydroxylated product $\text{6}$ was obtained. The reaction scheme is discussed in comparison uith that for the enzymic transformation.     

Raman probe using a single hollow waveguide

A simple Raman probe was realized using a single flexible hollow waveguide (HW). A HW coated with a silver film, which had reasonable transmission and little optical background noise, was used as a bidirectional transmission fiber for both the excitation and collection of Raman scattered light. The HW itself generated no Raman scattering or fluorescence noise during transmission. A complex filtering system at the end of the waveguide was thus unnecessary. In addition, the measured Raman spectra showed better signal-to-noise ratios than a conventional Raman fiber probe. The HW's suitability as a Raman fiber probe was also demonstrated.     

Melting pattern of diquark condensates in quark matter

Thermal color superconducting phase transitions in high density three-flavor quark matter are investigated in the Ginzburg-Landau approach. The effects of nonzero strange quark mass, electric and color charge neutrality, and direct instantons are considered. Weak coupling calculations show that an interplay between the mass and electric neutrality effects near the critical temperature gives rise to three successive second-order phase transitions as the temperature increases: a modified color-flavor locked (mCFL) phase (ud, ds, and us pairings) --> a d-quark superconducting (dSC) phase (ud and ds pairings) --> an isoscalar pairing phase (ud pairing) --> a normal phase (no pairing). The dSC phase is novel in the sense that while all eight gluons are Meissner screened as in the mCFL phase, three out of nine quark quasiparticles are always gapless.     

Dopant-pair structures segregated on a hydrogen-terminated Si(100) surface

Novel atomic structures on a H-terminated Si(100)-(2x1)-H surface were found using scanning tunneling microscopy (STM). The structures are distinguishable only from Si dimers in empty-state STM images. They were observed on arsenic- and phosphorus-doped substrates, but not on boron-doped substrates. Surface density of these structures was found to be proportional to the dopant density in the substrate. First-principles calculations clarify that they are consisting of dopant pairs that are segregated from the bulk material. Hydrogen atoms attached to the dopant pair are found to flip between two positions on the surface due to a quantum effect.     

Measurement Accuracy in Phase-Shifting Point Diffraction Interferometer with Two Optical Fibers

A phase-shifting point diffraction interferometer (PS/PDI) with point sources of two single mode optical fibers has been developed, which will be appropriate for the surface figure measurement of large aperture optics on a sub-nanometer scale. To reduce the measurement error factors, a fiber optic plate (FOP) is used as a projection plane for interference pattern. Errors caused by imperfection of optical alignment, such as position of point sources and tilt of FOP, are minimized by analyzing the measured phase data with an original method. Measurement accuracy in the PS/ PDI is estimated with the interference pattern produced by the two optical fiber sources. If inhomogeneity of the FOP and a systematic error of the PS/PDI are eliminated, the measurement accuracy of the present system is estimated to be less than 4nm P-V and 0.7nm rms, respectively, at a measurement wavelength of 632.8 nm.     

Asymmetric total synthesis of rhinacanthin A

Starting from a reduced lapachol compound, the total synthesis of rhinacanthin A in both racemic and enantioenriched forms is achieved in eight steps without forming any undesired β-lapachone derivatives. For the synthesis of enantioenriched rhinacanthin A, the introduction of the asymmetric center was carried out by using the catalytic asymmetric epoxidation of an unfunctional trisubstituted olefin using Shi’s epoxidation diketal catalyst. The acidic treatment of a derived enantioenriched epoxynaphthol and the following CAN oxidation afforded the target molecule with high enantiomeric purity.