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11.
A spectrum of HSiF(3) has been recorded at room temperature with a gas pressure of 20-50 Torr in the near-infrared region. A laser photoacoustic spectrometer consisting of a longitudinal resonant cell coupled to a titanium:sapphire ring laser was employed. The 5nu(1) and 6nu(1) overtone bands of H(28)SiF(3) associated with the Si-H stretching have been observed at high resolution (3 x 10(-2) cm(-1)) in the regions 10 900-10 960 and 12 875-12 925 cm(-1), respectively. About 450 lines of the 5nu(1)-0 band have been assigned (J = 45, K = 3p = 18). Within each J cluster of the P and R branches, the K structure has been deconvoluted. A set of parameters characterizing the upper vibration-rotation structure has been obtained. Perturbations have been evidenced for K = 9 and 15. The characterization of the perturbed 6nu(1)-0 band was limited to J = 38, and effective parameters have been determined with no detailed information on the K structure. Most perturbations are supposedly due to the cubic anharmonic constant φ(144) linking nnu(1) to (n - 1)nu(1) + 2nu(4) (n = 5, 6) and to their accompanying interacting rovibrational states. Copyright 2000 Academic Press. 相似文献
12.
The rotational and torsional structure of the nu(7) and nu(9) degenerate fundamentals of (70)Ge(2)H(6) has been analyzed under high resolution. The torsional structure of both v(7) = 1 and v(9) = 1 states can be fitted by a simple one-parameter formula. The x,y-Coriolis interaction with the parallel nu(5) fundamental was accounted for in the analysis of nu(7). A strong perturbation of the J structure of the E(3s) torsional component of the KDeltaK = -2 subbranches of nu(9) can be explained by the resonance with an E(3s) excited level of the pure torsional manifold. The perturber is centered at 361.58 cm(-1), very close to the value estimated with a barrier height of 285 cm(-1). This confirms that the fundamental torsional wavenumber is close to 103 cm(-1), in good agreement with the "ab initio" prediction. The torsional splittings of all the infrared active degenerate fundamentals, nu(7), nu(8), and nu(9), follow the trend predicted by theory, and have been fitted by exploratory calculations accounting only for the torsional Coriolis-coupling mechanism of all degenerate vibrational fundamentals in several torsional states. This confirms that torsional Coriolis coupling is the dominant mechanism responsible for the decrease of the torsional splitting in the degenerate vibrational states. A higher value of the barrier had to be used for the nu(9) mode. Copyright 2000 Academic Press. 相似文献
13.
Pracna P Margulès L Cosléou J Demaison J Mkadmi EB Bürger H 《Journal of Molecular Spectroscopy》2000,199(1):54-58
The nu(5) fundamental band of trifluorosilane-d (SiDF(3)) at 627 cm(-1) was studied for the first time by high-resolution FTIR spectroscopy at a resolution of 2.4 x 10(-3) cm(-1). The analysis was performed simultaneously with available microwave and newly measured submillimeter-wave data in the approximation of an isolated degenerate fundamental level of a C(3 Kv) symmetric top molecule leading to a standard deviation of 0.22 x 10(-3) cm(-1) for the reproduction of the infrared wavenumbers, 36 kHz for the microwave, and 198 kHz for the submillimeter-wave frequencies, respectively. The unitary equivalence between the two reductions (Q and D) of the effective Hamiltonian applied in the analysis is demonstrated. Copyright 2000 Academic Press. 相似文献
14.
Mkadmi EB Bürger H 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(7):1559-1569
The Fourier transform infrared spectrum of monoisotopic D3Si35Cl in the region of the nu2/nu5 band system was recorded with a resolution of 2.4x10(-3) cm-1. More than 9000 lines of the strongly Coriolis x,y-coupled bands, (nu2)0=701.936, and (nu5)0=688.898 cm-1, have been assigned, among them 276 forbidden but perturbation allowed transitions around avoided crossings according to Delta(k-l)=+/-3 mechanisms. Three different models taking into account redundancies in the framework of unitary equivalent reductions of the rovibrational Hamiltonian have been employed to fit the data. All three models reproduced consistently the full data set employing 28 refined parameters with an rms deviation of 0.31x10(-3) cm-1. The equivalence of the parameter sets was established by the agreement of parameter sums obtained with the different models. The analysis of the avoided crossings, together with the fit of the forbidden lines, allowed an independent determination of the ground state parameters A0 and D(K)0. Combined with existing data for nu1, nu3, nu4, and nu6, the present results allowed the determination of experimental values, Ae=1.4371895(94) and Be=0.19823049(59) cm-1. The experimental results are compared with those of previous ab initio calculations of the anharmonic force field. 相似文献
15.
Marcel Snels Giuseppe D'AmicoEl Bachir Mkadmi 《Journal of Molecular Spectroscopy》2002,216(2):191-196
The infrared spectra of isotopically pure CD235Cl2 have been recorded at a resolution of 0.0026 cm−1 (FWHM) in the range 600-1160 cm−1 with a Bruker IFS 120 HR Fourier transform interferometer. The absorption between 670 and 750 cm−1 is due to three fundamentals, ν3 (weak), ν7 (very weak), and ν9 (strong). A satisfactory analysis of the observed spectra has been obtained by including a c-Coriolis coupling between ν3 and ν9 and a b-Coriolis term between ν7 and ν9. Although no transitions could be observed for the very weak ν7 band, its band origin could be estimated from the Coriolis interaction with ν9. From the analysis of about 4200 assigned transitions of the ν3 and ν9 bands, excited state constants have been determined up to sextic terms. The Coriolis parameters obtained are compared to those calculated from a harmonic force field. 相似文献