Synthesis of substituted thiacrown ethers via a bromoalkoxylation reaction

A variety of alkyl- or phenyl-substituted thia-crown ethers were prepared in two or three steps via bromoalkoxylation reactions of olefins. Dialkyl- and phenyl-substituted mono-and dithia-crown ethers were obtained as single compounds, whereas monoalkyl-substituted derivatives were a mixture of two positional isomers reflecting the isomeric mixture formation in the bromoalkoxylation reaction.     

Optimum coupling of a Gaussian beam to a corner reflector with a four-wavelength antenna

The coupling of a Gaussian radiation beam to a corner reflector with a four-wavelength long wire antenna was studied theoretically and experimentally. The antenna configuration in conjunction with a Schottky barrier diode is recently used widely as a fast submillimeter wave detector. The optimum angle focusing the radiation to the antenna has been obtained and is 11° (half-width at the 8.7dB points).     

Radical polymerisation of styrene in porous coordination polymers

The first radical polymerisation of styrene in porous coordination polymers has been carried out, providing stable propagating radicals (living radicals), and a specific space effect of the host frameworks on the monomer reactivity is demonstrated.     

A New Proof of Bartholdi's Theorem

We give a new proof of Bartholdi's theorem for the Bartholdi zeta function of a graph. Supported by Grant-in-Aid for Science Research (C)