Study of electric quadrupole interactions of111In and111Cd following ion implantation of111In into graphite

The nuclear electric quadrupole interaction of¹¹¹In ion-implanted in hightly oriented pyrolytic graphite has been observed by means of low-temperature nuclear orientation and by means of perturbed angular correlations. From the first kind of experiment, it is concluded that a relatively large number of indium nuclei experience a well-defined macroscopic orientation, which is partly lost after the radioactive decay to cadmium. Indeed, the second kind of experiment revealed a broad distribution of electrid field gradients interacting with the 245 keV Cd excited state, as well as a small faction experiencing a unique electric field gradient. The experimental results are compared with theoretical calculations of the electric field gradient at various lattice positions, in which carbon and indium electronic wavefunctions are allowed to hybridize. Lattice positions of the covalent indium atom between the graphite layers can explain the measured electric field gradient ofV ₂₂=+1.47(11)·10²² V/m², directed parallel to the graphitec-axis.     

Models of a structural phase transition with general anharmonicity and disorder

It is shown how the self-consistent phonon Ansatz leads to a new class of exactly soluble models of a structural phase transition. Both nonpolynomial anharmonicity and disorder are analyzed in detail. In the classical limit, the thermodynamics is obtained and sufficient conditions on the anharmonicity are given to ensure a soft-mode phase transition. Diagonal disorder has been studied numerically. It is found that in three dimensions a pronounced mobility edge, separating localized and delocalized phonon states, may exist.     

Quantum theory of a massless spinning particle

The classical and quantum mechanics of a free massless point-like fermion is presented. The action is invariant under local 1-dimensional reparametrizations and supersymmetry, as well as a large set of rigid symmetries, including conformal and chiral symmetries. An infinite set of rigid symmetries is derived starting from the chiral invariance, but only a finite subset does not vanish on shell. The BRST-transformations corresponding to thed=1 local symmetries are constructed and the quantization is performed. Finally, the BRST-cohomology is investigated and the conditions producing the physical states are derived.     

The boson gas on a Cayley tree

We analyze the free boson gas on a Cayley tree using two alternative methods. The spectrum of the lattice Laplacian on a finite tree is obtained using a direct iterative method for solving the associated characteristic equation and also using a random walk representation for the corresponding fermion lattice gas. The existence of the thermodynamic limit for the pressure of the boson lattice gas is proven and it is shown that the model exhibits boson condensation into the ground state. The random walk representation is also used to derive an expression for the Bethe approximation to the infinite-volume spectrum. This spectrum turns out to be continuous instead of a dense point spectrum, but there is still boson condensation in this approximation.     

The effect of the temperature on the reduction kinetics of oxidized Ni(111) surfaces by hydrogen

The reduction kinetics of oxidized Ni(111) surfaces are measured in situ with ellipsometry in a temperature range between 450 and 675 K. The reaction rate is proportional to the square root of the hydrogen pressure below reduction temperatures of 525 K. The rate limiting step is the reaction between chemisorbed oxygen and dissociated hydrogen and has an experimental activation energy of 57 ± 7 kJ/mol. This reaction takes only place on the oxide free part of the Ni surface. Above 600 K, the reaction rate is proportional to the hydrogen pressure. The rate limiting step is the formation of water and has no experimental activation energy. At temperatures above 600 K the distribution of oxygen throughout the Ni crystal has a large effect on the reduction curves. A new reduction model is proposed that describes all the observed curves satisfactorily.     

An algorithm for the construction of convex hulls in simple integer recourse programming

We consider the objective function of a simple integer recourse problem with fixed technology matrix and discretely distributed right-hand sides. Exploiting the special structure of this problem, we devise an algorithm that determines the convex hull of this function efficiently. The results are improvements over those in a previous paper. In the first place, the convex hull of many objective functions in the class is covered, instead of only one-dimensional versions. In the second place, the algorithm is faster than the one in the previous paper. Moreover, some new results on the structure of the objective function are presented.     

A generalized approach for the calculation and automation of potentiometric titrations Part 1. Acid-Base Titrations

Fast and accurate calculation procedures for pH and redox potentials are required for optimum control of automatic titrations. The procedure suggested is based on a three-dimensional titration curve V = f(pH, redox potential). All possible interactions between species in the solution, e.g., changes in activity coefficients and influences of redox potential on pH variations, are taken into account. The number of titrant additions can be reduced considerably without loss of precision, by using the fact that the pH of a protolyte or mixture of protolytes at some fraction titrated does not depend strongly on the actual concentration.     

Differences between eastern and western-type nuclear reactor pressure vessel steels as probed by Mössbauer spectroscopy

Mössbauer spectra (MS) at room temperature have been collected for non-irradiated Eastern- and Western-type nuclear reactor pressure vessel (RPV) steels. All samples showed a typical Mössbauer spectrum for steels with a low alloy-element concentration. Analysis with distributed hyperfine parameters revealed that the spectra consist of two magnetically split subspectra and that only for the Western-type RPV steels a small doublet is present. The analysis of the resulting H_hf-distribution profiles showed that for the Eastern-type steels the relative area for the ''perturbed'' component is more pronounced, and that it has a more complex structure than the corresponding profile for the Western-type steels. The additional doublet present in the MS of the Western-type steels could be assigned to Mn and/or Cr-substituted cementite, while no carbide doublet was observed for the Eastern-type RPV steel, Cr₂₃C₆, Cr₇C₃ and VC being the principal carbides. The distinctions between the two types of steel are due to compositional differences. The results further show that Mössbauer spectroscopy is sensitive to small changes in composition and hence is capable of distinguishing between different types of steel.     

2-(diphenylphosphinoyl) pyrrolidines; versatile reagents for the synthesis of heterocyclic enamines and enamides.

A method is described for the preparation of N-substituted 2-(diphenylphosphinoyl) pyrrolidines. Application of these phosphine oxides in the Horner-Wittig reaction affords heterocyclic enamines and enamides in good yields.