全文获取类型
收费全文 | 18859篇 |
免费 | 2847篇 |
国内免费 | 2618篇 |
专业分类
化学 | 14480篇 |
晶体学 | 326篇 |
力学 | 847篇 |
综合类 | 193篇 |
数学 | 1965篇 |
物理学 | 6513篇 |
出版年
2024年 | 32篇 |
2023年 | 297篇 |
2022年 | 390篇 |
2021年 | 543篇 |
2020年 | 685篇 |
2019年 | 694篇 |
2018年 | 564篇 |
2017年 | 594篇 |
2016年 | 833篇 |
2015年 | 885篇 |
2014年 | 1109篇 |
2013年 | 1425篇 |
2012年 | 1629篇 |
2011年 | 1731篇 |
2010年 | 1274篇 |
2009年 | 1249篇 |
2008年 | 1431篇 |
2007年 | 1184篇 |
2006年 | 1140篇 |
2005年 | 977篇 |
2004年 | 804篇 |
2003年 | 631篇 |
2002年 | 723篇 |
2001年 | 520篇 |
2000年 | 417篇 |
1999年 | 374篇 |
1998年 | 278篇 |
1997年 | 224篇 |
1996年 | 252篇 |
1995年 | 180篇 |
1994年 | 173篇 |
1993年 | 169篇 |
1992年 | 147篇 |
1991年 | 145篇 |
1990年 | 93篇 |
1989年 | 112篇 |
1988年 | 67篇 |
1987年 | 69篇 |
1986年 | 55篇 |
1985年 | 55篇 |
1984年 | 31篇 |
1983年 | 27篇 |
1982年 | 19篇 |
1981年 | 19篇 |
1980年 | 14篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1976年 | 9篇 |
1973年 | 4篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
61.
62.
Longlan Cui Hong Xu Ping He Keiko Sumitomo Yoshinori Yamaguchi Hongchen Gu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5285-5295
A hybrid emulsion polymerization was formulated for synthesizing Fe3O4/polystyrene composite latex. This system, containing binary droplets that are magnetic (Mag)‐droplets with a diameter of 100–200 nm and styrene (St)‐droplets with a diameter of 3–4 μm, was obtained by mixing Mag‐miniemulsion and St‐macroemulsion. With extremely low surfactants concentration (?critical micelle concentration, CMC), the nucleated loci are selectively controlled in the Mag‐droplets, as the result of smaller droplet size and larger surface ratio. Both water‐soluble potassium persulfate (KPS) and oil‐soluble 2,2′‐azobis(2‐isobutyronitrile) was adopted to initiate the polymerization. In the presence of KPS, magnetic polystyrene latices with particles size of 60–200 nm, narrow size distribution, and high magnetite content (86 wt % measured by TGA) were attained successfully. The synthesized magnetic Fe3O4/polystyrene latices assembled into well‐ordered hexagonal structure in the surface of a carbon supported copper grid. The influence of various parameters on various aspects of the as‐synthesized Fe3O4/polystyrene was investigated in detail: type of initiator on composite morphology, feed ratio of Mag‐miniemulsion and St‐macroemulsion on magnetite content, and hydrophobic agent or amount of surfactant on size and size distribution. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5285–5295, 2007 相似文献
63.
Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
64.
CHEN Yue WANG Xuan-jun CONG Xian-ling ZHANG Pei-yin WU Xiu-li WEI Hong-fei WANG Li WAN Min WANG Li-ying YU Yong-li 《高等学校化学研究》2006,22(6):712-716
IntroductionClassical swine fever(CSF), included in the listA of the Office International des Epizooties(OIE), is ahighly contagious disease of domestic pigs and is con-sidered as the mostharmful disease occurring in pigs allover the world[1]. Outbreaks o… 相似文献
65.
66.
Morphological and chemical properties of both the surface and interface of poly(vinylidene fluoride)/poly(methyl methacrylate)-co-poly(ethyl acrylate) (PVDF/PMMA-co-PEA) blend films have been investigated before and after the samples were exposed to ultraviolet (UV) irradiation using a xenon arc lamp at 50 °C and 9% relative humidity (RH) for 7 months. Surface and interfacial morphologies were studied by atomic force microscopy (AFM). Chemical composition information was obtained by confocal Raman microscopy, attenuated total reflection-FTIR spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. Results show an enrichment of the PVDF material at the air surface, while the acrylic copolymer enriches the interface. Blends having greater than 50% mass fraction of PVDF show little change in the surface morphology after UV exposure for 7 months. However, for a lower PVDF content, blends exhibit significant degradation of PMMA-co-PEA copolymer and a much rougher surface after UV exposure. Microstructural changes in the PVDF spherulites are also observed after UV degradation. It is found that the surface and interfacial morphologies are correlated with the chemical properties. 相似文献
67.
68.
69.
Ben-Yuan Gu Yao Lu Tzong-Jer Yang 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(4):493-502
We present numerical investigations of the transmission properties of electrons in a normal quantum wire tangentially attached
to a superconductor ring threaded by magnetic flux. A point scatterer with a δ -function potential is placed at node to model
scattering effect. We find that the transmission characteristics of electrons in this structure strongly depend on the normal
or superconducting state of the ring. The transmission probability as a function of the energy of incident electrons, in the
case of a superconductor ring threaded by one quantum magnetic flux, emerges one deep dip, imposed upon the first broad bump
in spectrum. This intrinsic conductance dip originates from the superconductor state of the ring. When increasing the magnetic
flux from one quantum magnetic flux to two, the spectrum shifts toward higher energy region in the whole. This conductance
dip accordingly shifts and appears in the second bump. In the presence of a point-scatterer at the node, the spectrum is substantially
modified. Based on the condition of the formation of the standing wave functions in the ring and the broken of the time-reserve
symmetry of Schr?dinger equation after switching magnetic flux, the characteristics of transmission of electrons in this structure
can be well understood.
Received 6 November 2001 相似文献
70.
Wei-Yan Shao Ying-Nan Cao Wen-Jie Pan Xian-Zhang Bu Lin-Kun An Lian-Quan Gu Albert S.C. Chan 《Tetrahedron letters》2006,47(24):4085-4089
Seventeen unsymmetrical curcumin derivatives were synthesized in good yield and purity by a facile solid phase synthesis strategy. 相似文献