Ion-Assisted α-Al2O3 Coating Deposition by Anodic Arc Evaporation at 500–550°С

Russian Physics Journal - The paper studies the α-phase formation and structure of Al2O3 coatings deposited by the anodic arc evaporation in the low temperature range of...     

Determination of mechanical properties by instrumented indentation

The paper reviews the current state of the depth-sensing indentation (sometimes called nanoindentation), where the information on material behaviour and properties is obtained from the indenter load and depth, measured continuously during loading and unloading. It is shown how the contact parameters and principal characteristics are determined using pointed or spherical indenters. Indentation tests can be used for the measurement of hardness and elastic modulus, and also of the yield stress and for the construction of stress–strain diagrams, for the determination of the work of indentation and its components. Most devices use monotonic loading and unloading, but some also enable measurement under a small harmonic signal added to the basic monotonously increasing load. This makes possible continuous measurement of contact stiffness and the study of dynamic properties and the determination of properties of coatings. One section is devoted to the measurement on viscoelastic-plastic materials, where the delayed deforming must be considered during the measurement as well as in data evaluation. Instrumented indentation can also be used for the study of creep under high temperatures. The paper also discusses the errors arising in depth-sensing measurements and informs briefly about some other possibilities of the method.     

分子间费米共振增强二元溶液体系的受激拉曼散射研究

研究了液芯光纤内不同体积比的甲苯和间二甲苯二元混合溶液的受激拉曼散射.实验结果表明:在不同的体积比之下二元溶液的环呼吸振动模式1002 cm^-1,甲基的CH伸缩振动模式2920 cm^-1 以及芳香环CH对称伸缩振动模式3058 cm^-1的拉曼带同时产生受激拉曼辐射,并且2920 cm^-1 和 3058 cm^-1 拉曼带的一阶受激拉曼散射阈值要低于1002 cm^-1拉曼带的二阶 关键词： 分子间费米共振 二元溶液 受激拉曼散射 拉曼散射截面     

Random systems of equations in free abelian groups

We study the solvability of random systems of equations on the free abelian group ? ^m of rank m. Denote by SAT(? ^m , k, n) and \(SAT_{\mathbb{Q}^m } (\mathbb{Z}^m ,k,n)\) the sets of all systems of n equations of k unknowns in ? ^m satisfiable in ? ^m and ? ^m respectively. We prove that the asymptotic density \(\rho \left( {SAT_{\mathbb{Q}^m } (\mathbb{Z}^m ,k,n)} \right)\) of the set \(SAT_{\mathbb{Q}^m } (\mathbb{Z}^m ,k,n)\) equals 1 for n ≤ k and 0 for n > k. As regards, SAT(? ^m , k, n) for n < k, some new estimates are obtained for the lower and upper asymptotic densities and it is proved that they lie between (Π _j=k?n+1 ^k ζ(j))^?1 and \(\left( {\tfrac{{\zeta (k + m)}} {{\zeta (k)}}} \right)^n\) , where ξ(s) is the Riemann zeta function. For n ≤ k, a connection is established between the asymptotic density of SAT(? ^m , k, n) and the sums of inverse greater divisors over matrices of full rank. Starting from this result, we make a conjecture about the asymptotic density of SAT(? ^m , n, n). We prove that ρ(SAT(? ^m , k, n)) = 0 for n > k.     

Seasonal variations of the composition,structural features,and antitumor properties of polysaccharides from <Emphasis Type="Italic">Padina pavonica</Emphasis> (Lebanon) as a function of composition

The variation of the polysaccharide composition of the brown alga Padina pavonica from the Mediterranean Sea was studied as a function of the collection season (April–July). It was shown that the principal polysaccharide (8.0-13.3% of dry alga weight) was alginic acid. Its content did not undergo significant changes from April to July. The content of water-soluble polysaccharides (laminarans and fucoidans) was low (<0.3% of dry alga weight). Water-soluble polysaccharides of the studied alga were practically pure fucoidan. The amount of laminarans was insignificant (<0.01% of dry alga weight). The content of fucoidans increased in alga samples from May through July. It was shown that P. pavonica is a promising source of alginic acids, which have a high capacity for gelation, and fucoidans, which exhibit antitumor action against RPMI-7951 human melanoma cells.     

A computational study on the stability–aromaticity correlation of triply N-confused porphyrins: CMMSE-09

The B3LYP density functional theory methodology in conjunction with the 6-31G(d,p) basis set has been used to characterize triply N-confused meso-tetraphenylporphyrins. According to our computations, there is no a direct correlation between stability and aromaticity as already found for non-substituted confused porphyrins. The inclusion of these substituents in the calculations provokes a decrease of the planarity and aromaticity of these macrocycles along with a notable rise of their relative stability with respect to the non-substituted case. Steric repulsions, both among phenyl rings and β atoms in the pyrrolic rings, and among H atoms in the core of the macrocycles, dominate over aromaticity in the establishment of the most stable conformation of each isomer.     

On the stability of the detonation front in tetranitromethane-nitrobenzene and tetranitromethane-nitromethane liquid composite HEs

The stability of the detonation front and the detonation parameters of composite liquid HEs of fueloxidizer type prepared from tetranitromethane, nitrobenzene, and nitromethane are studied using laser interferometry.