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21.
S. V. Bulyarskii N. A. Butylkina N. S. Grushko A. E. Luk'yanov M. V. Nazarov I. O. Stepin 《Russian Physics Journal》1991,34(4):339-342
Latent macroscopic defects in silicon are detected by electrical and electron microscope measurements. They lead to anomalous temperature dependence of the Fermi level position and growth in the hole capture coefficient. A level with energy of 0.55 eV measured from the conduction zone controls the recombination process. It is proposed that macroscopic defects develop upon association of oxygen-silicon vacancy complexes. Action of an electron beam leads to reversible changes which increase upon multiple scanning, affecting the value of the diffusion length.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 71–75, April, 1991. 相似文献
22.
Maxim Braverman Valentin Silantyev 《Transactions of the American Mathematical Society》2006,358(8):3329-3361
We extend the Novikov Morse-type inequalities for closed 1-forms in 2 directions. First, we consider manifolds with boundary. Second, we allow a very degenerate structure of the critical set of the form, assuming only that the form is non-degenerated in the sense of Kirwan. In particular, we obtain a generalization of a result of Floer about the usual Morse inequalities on a manifold with boundary. We also obtain an equivariant version of our inequalities.
Our proof is based on an application of the Witten deformation technique. The main novelty here is that we consider the neighborhood of the critical set as a manifold with a cylindrical end. This leads to a considerable simplification of the local analysis. In particular, we obtain a new analytic proof of the Morse-Bott inequalities on a closed manifold.
23.
Grounds and applications of Bargmann-Michel-Telegdi equations for the precession of the polarization vector of relativistic particles are considered. A critical question in the discussion is the orientation of the rest frame reference vectors. Møller reference frames which keep constant the mutual orientation of the two infinitely close in time rest frames are shown to have a special role. The generally covariant form of the equations is discussed. The assertion that the principle of relativity is violated in the phenomenon of spin precession is proved to be untrue. 相似文献
24.
Aarnts MP Wilms MP Peelen K Fraanje J Goubitz K Hartl F Stufkens DJ Baerends EJ Vlcek A 《Inorganic chemistry》1996,35(19):5468-5477
Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) was synthesized and characterized by UV-vis, IR, (1)H NMR, (13)C NMR, (119)Sn NMR, and mass (FAB(+)) spectroscopies and by single-crystal X-ray diffraction, which proved the presence of a nearly linear Sn-Ru-Sn unit. Crystals of Ru(SnPh(3))(2)(CO)(2)(iPr-DAB).3.5C(6)H(6) form in the triclinic space group P&onemacr; in a unit cell of dimensions a = 11.662(6) ?, b = 13.902(3) ?, c = 19.643(2) ?, alpha = 71.24(2) degrees, beta = 86.91(4) degrees, gamma = 77.89(3) degrees, and V = 2946(3) ?(3). One-electron reduction of Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) produces the stable radical-anion [Ru(SnPh(3))(2)(CO)(2)(iPr-DAB)](*-) that was characterized by IR, and UV-vis spectroelectrochemistry. Its EPR spectrum shows a signal at g = 1.9960 with well resolved Sn, Ru, and iPr-DAB (H, N) hyperfine couplings. DFT-MO calculations on the model compound Ru(SnH(3))(2)(CO)(2)(H-DAB) reveal that the HOMO is mainly of sigma(Sn-Ru-Sn) character mixed strongly with the lowest pi orbital of the H-DAB ligand. The LUMO (SOMO in the reduced complex) should be viewed as predominantly pi(H-DAB) with an admixture of the sigma(Sn-Ru-Sn) orbital. Accordingly, the lowest-energy absorption band of the neutral species will mainly belong to the sigma(Sn-Ru-Sn)-->pi(iPr-DAB) charge transfer transition. The intrinsic strength of the Ru-Sn bond and the delocalized character of the three-center four-electron Sn-Ru-Sn sigma-bond account for the inherent stability of the radical anion. 相似文献
25.
A. M. Nazarov A. I. Nikolaev S. Yu. Serenko V. D. Komissarov 《Russian Chemical Bulletin》1990,39(11):2257-2260
Data were obtained on the composition of products and kinetics of the reaction of SO2 with Ph(R)CN2 (R=Ph, Me) in solutions of isooctane, 1,4-di-oxane, and ethanol at 295 K. A mechanism was proposed for the process in accordance with which the sulfene being formed participates in concurrent reactions with the starting reagents. The relative rate constants for the process stages were determined.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2496–2500, November, 1990. 相似文献
26.
N. I. Baram F. G. Kamaev Kh. L. Ziyaev L. Biktimirov A. I. Ismailov G. B. Nazarov B. T. Ibragimov 《Chemistry of Natural Compounds》1988,24(5):550-553
A number of new Schiff's bases of gossypol with aromatic amines and sulfanilamide compounds has been obtained. It has been shown by UV and PMR spectroscopy and x-ray structural analysis that in some solvents they exist predominantly in the quinoid form. For dianilinegossypol (in the solid state) the quinoid structure has been demonstrated and two polymorphic modifications have been revealed by x-ray structural analysis.A. S. Sadykov Institute of Bioorganic Chemistry, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 650–654, September–October, 1988. 相似文献
27.
Aggregated aromatic molecule--cyclodextrin-precipitant complexes exhibit long-lived phosphorescence at room temperature in water after the chemical binding of oxygen. The temperature dependences of the phosphorescence lifetimes of naphthalene-h8, naphthalene-de, and phenanthrene in the aggregates were measured. For example, the phosphorescence lifetimes of naphthalene-d8 aggregated with -cyclodextrin and cyclohexane are equal to 25.1, 17.6, and 6.8 s at 77, 276, and 347 K, respectively, and that of phenanthrene aggregated with isooctane and -cyclodextrin are 3.24, 3.06, and 1.26 s at 268, 274, and 335 K, respectively. The temperature dependences of the phosphorescence lifetimes at room temperature are determined by the rate constants of the radiative and nonradiative transitions from the triplet state of an aromatic molecule.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2225–2228, September, 1996. 相似文献
28.
Borsdorf H Nazarov EG Eiceman GA 《Journal of the American Society for Mass Spectrometry》2002,13(9):1078-1087
The ionization pathways were determined for sets of isomeric non-polar hydrocarbons (structural isomers, cis/trans isomers) using ion mobility spectrometry and mass spectrometry with different techniques of atmospheric pressure chemical ionization to assess the influence of structural features on ion formation. Depending on the structural features, different ions were observed using mass spectrometry. Unsaturated hydrocarbons formed mostly [M - 1]+ and [(M - 1)2H]+ ions while mainly [M - 3]+ and [(M - 3)H2O]+ ions were found for saturated cis/trans isomers using photoionization and 63Ni ionization. These ionization methods and corona discharge ionization were used for ion mobility measurements of these compounds. Different ions were detected for compounds with different structural features. 63Ni ionization and photoionization provide comparable ions for every set of isomers. The product ions formed can be clearly attributed to the structures identified. However, differences in relative abundance of product ions were found. Although corona discharge ionization permits the most sensitive detection of non-polar hydrocarbons, the spectra detected are complex and differ from those obtained with 63Ni ionization and photoionization. 相似文献
29.
Maxim A. Mironov Maria N. Ivantsova Maria I. Tokareva Vladimir S. Mokrushin 《Tetrahedron letters》2005,46(23):3957-3960
An accelerating effect of nucleophilic additives was revealed for the Passerini multi-component reaction. The influence of aqueous solutions on the reaction rate was studied in detail and the direct involvement of water in the bond-making step was attributed as the basis of an accelerating effect. Other nucleophiles were tested as alternatives to water; as a result N-hydroxysuccinimide is proposed as an accelerant of the Passerini reaction. 相似文献
30.
Summary Reaction of methylmagnesium iodide and of ethylmagnesium bromide with 2-bromo-1,3-cyclohexanedione (IV) gave 2-bromo-3-methyl- and 2-bromo-3-ethyl-2-cyclohexen-1-ones (X) and (XI)-, respectively. When these products were vacuum-distilled, they were converted into the m-substituted phenols (XII) and (XIII).Treatment of the bromocyclohexenones (X) and (XI) with dilute alkali gave the cyclic a-diketones (XVI) and (XVII). 相似文献