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101.
Fraser-Reid B Lopez JC Radhakrishnan KV Mach M Schlueter U Gomez AM Uriel C 《Journal of the American Chemical Society》2002,124(13):3198-3199
Glycosidation of several vicinal diols reveals that exquisite regioselectivity can be achieved by using 2-O-benzoyl n-pentenyl glycoside donors and/or their cyclic 1,2-ortho ester counterparts. The regioselective preferences for both are the same, although ratios and yields may differ. In stark contrast, glycosidation of the diols with the corresponding 2-O-benzylated donors gives poor, if any, regioselectivity. 相似文献
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Peter B. Weber Raphael Hellwig Tobias Paintner Dr. Marie Lattelais Mateusz Paszkiewicz Pablo Casado Aguilar Peter S. Deimel Dr. Yuanyuan Guo Dr. Yi‐Qi Zhang Dr. Francesco Allegretti Dr. Anthoula C. Papageorgiou Dr. Joachim Reichert Dr. Svetlana Klyatskaya Prof. Dr. Mario Ruben Prof. Dr. Johannes V. Barth Dr. Marie‐Laure Bocquet Dr. Florian Klappenberger 《Angewandte Chemie (International ed. in English)》2016,55(19):5754-5759
Organocobalt complexes represent a versatile tool in organic synthesis as they are important intermediates in Pauson–Khand, Friedel–Crafts, and Nicholas reactions. Herein, a single‐molecule‐level investigation addressing the formation of an organocobalt complex at a solid–vacuum interface is reported. Deposition of 4,4′‐(ethyne‐1,2‐diyl)dibenzonitrile and Co atoms on the Ag(111) surface followed by annealing resulted in genuine complexes in which single Co atoms laterally coordinated to two carbonitrile groups undergo organometallic bonding with the internal alkyne moiety of adjacent molecules. Alternative complexation scenarios involving fragmentation of the precursor were ruled out by complementary X‐ray photoelectron spectroscopy. According to density functional theory analysis, the complexation with the alkyne moiety follows the Dewar–Chatt–Duncanson model for a two‐electron‐donor ligand where an alkyne‐to‐Co donation occurs together with a strong metal‐to‐alkyne back‐donation. 相似文献
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Wielopolski M Atienza C Clark T Guldi DM Martín N 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(21):6379-6390
A series of donor-acceptor arrays (exTTF-oPPE-C60) containing pi-conjugated oligo(phenyleneethynylene) wires (oPPE) of different length between pi-extended tetrathiafulvalene (exTTF) as electron donor and fullerene (C60) as electron acceptor has been prepared by following a convergent synthesis. The key reaction in these approaches is the bromo-iodo selectivity of the Hagihara-Sonogashira reaction and the deprotecting of acetylenes with different silyl groups to afford the corresponding donor-acceptor conjugates in moderate yields. The electronic interactions between the three electroactive species were determined by using UV-visible spectroscopy and cyclic voltammetry. Our studies clearly confirm that, although the C60 units are connected to the exTTF donor through pi-conjugated oPPE frameworks, no significant electronic interactions are observed in the ground state. Theoretical calculations predict how a simple exchange from C=C double bonds (i.e., oligo(p-phenylenevinylene) to C triple chemical bond C triple bonds (i.e., oPPE) in the electron donor-acceptor conjugates considerably alters long-range electron transfer. Photoexcitation of exTTF-oPPE-C60 leads to the following features: a transient photoproduct with maxima at 660 and 1000 nm, which are unambiguously attributed to the photolytically generated radical-ion-pair state, [exTTF*+-oPPE-C60*]. Both charge-separation and charge-recombination processes give rise to a molecular-wire behaviour of the oPPE moiety with an attenuation factor (beta) of (0.2+/-0.05) A(-1). 相似文献
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Hyeongrae Cho Dirk Henkensmeier Mateusz Brela Artur Michalak Jong Hyun Jang Kwan‐Young Lee 《Journal of Polymer Science.Polymer Physics》2017,55(3):256-265
A methylated polybenzimidazole with an aliphatic chain in the backbone (Me‐PBI‐C10) was synthesized and formed into membranes. Literature suggests that alkyl chains on C2 of imidazolium ions increase their alkaline stability. While this may be true for model compounds or ions attached as a side chain, both our DFT calculations and experimental results show that Me‐PBI‐C10 does not withstand alkaline conditions. To increase the alkaline stability, blend membranes with PBI‐OO were fabricated. A blend membrane with 50% PBI‐OO showed a chloride conductivity of up to 6 mS/cm, indicating that these membranes could find use in non‐alkaline applications like vanadium redox flow batteries (VRFB). The high mechanical stability (tensile strength: 70.25 ± 14.85 MPa, Young modulus: 1.65 ± 0.16 GPa) would be an advantage over currently used Nafion membranes. Finally, three different models were successfully applied to qualitatively predict the water uptake of Me‐PBI‐C10 exchanged with different anions. The results match with experimental data. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 256–265 相似文献
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Kamila Saasiska Maciej Celiski Kamila Mizera Mateusz Barczewski Pawe Kozikowski Micha K. Leszczyski Agata Domaska 《Molecules (Basel, Switzerland)》2021,26(4)
In this paper, the fire behavior of unsaturated polyester resin (UP) modified with L-histidinium dihydrogen phosphate-phosphoric acid (LHP), being a novel intumescent fire retardant (IFR), was investigated. Thermal and thermomechanical properties of the UP with different amounts of LHP (from 10 to 30 wt. %) were determined by thermogravimetric analysis (TG) as well as dynamic mechanical thermal analysis (DMTA). Reaction to small flames was studied by horizontal burning (HB) test, while fire behavior and smoke emission were investigated with the cone calorimeter (CC) and smoke density chamber. Further, the analysis of volatile products was conducted (TGA/FT-IR). It was observed that the addition of LHP resulted in the formation of carbonaceous char inhibiting the thermal decomposition, burning rate and smoke emission. The most promising results were obtained for the UP containing 30 wt. % of LHP, for which the highest reduction in maximum values of heat release rate (200 kW/m2) and total smoke release (3535 m2/m2) compared to unmodified polymer (792 kW/m2 and 6895 m2/m2) were recorded. However, some important disadvantage with respect to water resistance was observed. 相似文献
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Micha Kosowski Joanna Smolarczyk-Kosowska Marcin Hachua Mateusz Maligwka Marcin Basiak Grzegorz Machnik Robert Pudlo Bogusaw Okopie 《Molecules (Basel, Switzerland)》2021,26(10)
Statins are among the most widely used drug classes in the world. Apart from their basic mechanism of action, which is lowering cholesterol levels, many pleiotropic effects have been described so far, such as anti-inflammatory and antiatherosclerotic effects. A growing number of scientific reports have proven that these drugs have a beneficial effect on the functioning of the nervous system. The first reports proving that lipid-lowering therapy can influence the development of neurological and psychiatric diseases appeared in the 1990s. Despite numerous studies about the mechanisms by which statins may affect the functioning of the central nervous system (CNS), there are still no clear data explaining this effect. Most studies have focused on the metabolic effects of this group of drugs, however authors have also described the pleiotropic effects of statins, pointing to their probable impact on the neurotransmitter system and neuroprotective effects. The aim of this paper was to review the literature describing the impacts of statins on dopamine, serotonin, acetylcholine, and glutamate neurotransmission, as well as their neuroprotective role. This paper focuses on the mechanisms by which statins affect neurotransmission, as well as on their impacts on neurological and psychiatric diseases such as Parkinson’s disease (PD), Alzheimer’s disease (AD), vascular dementia (VD), stroke, and depression. The pleiotropic effects of statin usage could potentially open floodgates for research in these treatment domains, catching the attention of researchers and clinicians across the globe. 相似文献
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Chemistry of Heterocyclic Compounds - An efficient Pd-catalyzed C–N bond formation for the synthesis of different pyrazole derivatives using XPhos as a ligand and KOH as a base is presented.... 相似文献