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991.
Safaei Mohadeseh Beitollahi Hadi Shishehbore Masoud Reza 《Russian Journal of Electrochemistry》2018,54(11):851-859
Russian Journal of Electrochemistry - A sensitive and convenient electrochemical sensor was developed for determination of epinephrine by using the Fe3O4@SiO2/GR nanocomposite modified graphite... 相似文献
992.
Micromeria persica Boiss. is medicinal and aromatic plant, belonging to the Lamiaceae family. The chemical composition of the essential oils (EOs) from aerial parts of M. persica were extracted using hydro-distillation method and analysed using GC and GC–MS. Fifty-two compounds were identified in the EOs of aerial parts of M. persica. The main chemical compositions were n-hexadecanoic acid (14.9%), thymol (9.5%), linoleic acid (8.0%), carvacrol (5.6%), (E)-nerolidol (5.5%), linolenic acid (5.5%), α-cadinol (2.7%), linalool (2.7%), borneol (2.6%), caryophyllene oxide (2.3%) and pulegone (2.0%). Presence of borneol, thymol, carvacrol and pulegone suggests the potential of this plant as a flavouring source in the food industry, being used in perfumery and cosmetics industry, vitamin E synthesis and exhibit strong fungicidal, antibacterial and antimicrobial activities. 相似文献
993.
Kobra Ghobadi Hamid R. Zare Hossein Khoshro Alireza Gorji Abbas A. Jafari 《Comptes Rendus Chimie》2018,21(1):14-18
A Ni(II) complex, [NiII(Me4-NO2Bzo[15]tetraeneN4)], was used for electrocatalytic reduction of CO2 in acetonitrile solvent. Then, the reduced form of CO2 (CO2?) was used for selective carboxylation of phenylacetylene to produce cinnamic acid at room temperature. The potential of the process is significantly less negative in comparison with those reported earlier. Using sacrificial magnesium electrode as anode, controlled potential coulometry was carried out in an undivided glass cell. The spectral characterizations of FTIR, 1H NMR, and 13C NMR demonstrated that cinnamic acid was the main product of the electrolysis. With respect to other catalysts, which have been previously reported in the literature, application of the Ni(II) complex in carboxylation of unsaturated compounds has three advantages: (1) the selectivity in the production of cinnamic acid; (2) more increase in the reduction current indicating that the carboxylation of phenylacetylene is fast; and (3) the potential shift of electrocatalytic reduction of CO2 to less negative values showing that the Ni(II) complex has an excellent electrocatalytic activity for CO2 reduction. According to the voltammetric and coulometric results, an EC′CCC′C mechanism was proposed for the electrocatalytic synthesis of cinnamic acid. 相似文献
994.
Nosrat O. Mahmoodi Masoud Mohammadi Zeydi 《Journal of the Iranian Chemical Society》2018,15(2):311-336
This review article explains sensible synthesis and applications of symmetrical tris-compounds in the past few years. The aim of this review is collecting the different procedures for the synthesis of tris-compounds with special cores. Many of these compounds principally were prepared from a precursor to the tris-structure under the various conditions. One of the key purposes of this review is to collect a series of symmetrical tris-compounds which represent varied biological and synthetical applications. 相似文献
995.
Habib Firouzabadi Nasser Iranpoor Abbas Ali Jafari 《Journal of organometallic chemistry》2005,690(6):1556-1559
An efficient solvent-free method is described for the addition of TMSCN to carbonyl groups employing dodecatungestophosphoric acid (H3PW12O40) as a heterogeneous and environmentally benign catalyst. By this method, aromatic, aliphatic, cyclic and heterocyclic aldehydes and ketones are converted into their corresponding cyanotrimethylsilyl ethers in excellent yields (89-98%) in short reaction times (<10 min). 相似文献
996.
The structures of metal-thiolate clusters in Zn(7)-MT, Cd(7)-MT, Cu(12)-MT, Ag(12)-MT, and Ag(17)-MT from rabbit liver have been investigated by sulfur K-edge X-ray absorption spectroscopy (XAS). In addition to providing metal-cysteinyl sulfur bond lengths, the sulfur K-edge EXAFS data provide the first direct evidence for mixtures of bridging and terminal sulfurs in Cu-MT and Ag-MT. The Zn-S and Cd-S bond lengths for tetrahedrally coordinated Zn(4)(SPh)(10)(2-) and Cd(4)(SPh)(10)(2-) compounds obtained from sulfur K-edge EXAFS data are 2.35 +/- 0.03 and 2.52 +/- 0.02 ?, respectively. Zn-S and Cd-S bond distances of 2.34 +/- 0.03 ? for Zn(7)-MT and 2.54 +/- 0.02 ? for Cd(7)-MT, respectively, calculated from sulfur K-edge EXAFS measurements, are consistent with the previously reported results from metal K-edge EXAFS data. Analysis of the sulfur K-edge EXAFS data for Cu(12)-MT indicates that Cu(I) is trigonally coordinated to sulfurs at a distance of 2.25 +/- 0.01 ?. Significant changes in CD spectra observed between Ag(12)-MT 1 and Ag(17)-MT 1 indicate that the modification of the three-dimensional structure occurs when Ag(17)-MT 1 is formed from Ag(12)-MT 1 as Ag(I) is added to the Ag(12)-MT 1. The Ag-S bond distances of 2.45 +/- 0.02 and 2.44 +/- 0.03 ? in Ag(1)(2)-MT 1 and Ag(1)(7)-MT 1, respectively, calculated from the sulfur K-edge EXAFS measurements, lead us to conclude that the Ag(I) in both Ag(1)(2)-MT 1 and Ag(1)(7)-MT 1 is digonally coordinated by thiolates. The number of metals bonded to sulfur in both model compounds and metal-containing metallothioneins is estimated from sulfur K-edge EXAFS measurements to be in the range 1.2-1.7, depending on the fraction of bridging sulfurs present in compounds. Unlike the spectral data recorded during Cu(I) binding, where sharp changes take place past 12 Cu(I), the CD data for Ag-MT 1 show little variation over the entire range of Ag(I):MT molar ratios. This result, established by both low- and high-energy optical methods, suggests that the three-dimensional structure of the metal-binding sites in metallothioneins is strongly influenced by the fraction of bridging sulfur. This analysis is the first to provide direct support for the presence of a clustered Ag-S structure for the Ag(17)-MT 1 species. These data also suggest that the structures in Ag(I) and Cu(I) metallothioneins are probably quite different. 相似文献
997.
Masoud MS Soayed AA Ali AE 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(8-9):1907-1915
Cobalt, nickel and copper complexes of adenine and guanine, as nucleic-acid constituents, were prepared. The adenine and guanine complexes are of tetrahedral and octahedral geometries, respectively. All are of high spin nature. The nickel complexes are of 2:1 metal:ligand ratio with Ni...Ni direct interaction in the guanine complex. The coordination bonds of adenine metal complexes are calculated and follow the order: Cu(II)-adenine < Ni(II)-adenine < Co(I)-adenine. The Cu(II)-adenine complex is the stronger following the softness of the copper, while that of guanine is less covalent. The copper complexes are with stronger axial field. The differential thermal analysis (DTA) and TGA of the complexes pointed to their stability. The mechanism of the thermal decomposition is detected. The thermodynamic parameters of the dissociation steps are evaluated. The complexes are of semi-conducting behaviour for their technical applications. Empirical equations are deduced between the electrical conducting and the energy of activation of the complexes. 相似文献
998.
Masoud Khayyami Nuria Peña Garcia Per-Olof Larsson Bengt Danielsson Gillis Johansson 《Electroanalysis》1997,9(7):523-526
A NAD+-analog was coimmobilized with lactate dehydrogenase (LDH) on reticulated vitreous carbon (RVC) to give an amperometric lactate biosensor. Both LDH and the NAD+ -analog were bound covalently with carbodiimide to the surface of the porous RVC-material. The electrode was operated in a FIA-arrangement in the presence or absence of a soluble mediator. Meldola Blue. The stability was poor when the electrode was operated at +400 mV (vs. Ag/AgCl) in the absence of mediator but improved most significantly in the presence of 5 μM mediator, so that 65% of the original activity remained after 16 days. The amperometric currents were smaller with regeneration by mediator at −100 mV than with direct electrochemical oxidation at +400 mV, indicating that the additional steps slow down the reaction rate. Linear calibration plots were obtained from the detection limit, 1 μM, to 500 μM lactate with 5 μM mediator, reoxidized at −100 mV. The sample throughput was about 60 h−1. 相似文献
999.
Masoud Salavati-Niasari Mohammad Reza Ganjali Parviz Norouzi 《Transition Metal Chemistry》2007,32(1):1-8
Nanocavity zeolite-Y (host) encapsulated Co(II), Ni(II) and Cu(II) complexes of unsaturated 16-membered octaaza; 3,4,11,12-tetramethyl-1,2,5,6,9,10,13,14-octaazacyclohexadecane
‘Me4[16]aneN8’; macrocycle (guest) were synthesized and characterized by chemical analyses, s.e.m., x.r.d., u.v.–vis., d.r.s., surface
area, pore volume, conductometric, magnetic measurements and i.r. spectroscopy with a view to confirming the encapsulation
of complexes and to arrive at the composition, structure and geometry of encapsulated complexes. The characterization data
show the absence of extraneous complexes, retention of zeolite crystaline structure and encapsulation in the nanocavities.
Host–Guest Nanocomposite Materials (HGNM) ‘[M(Me4[16]aneN8)]2+-NaY’ are catalytically very efficient as compared to other neat complexes for the partial oxidation of benzyl alcohol which
is stable and becomes recycled without much deterioration. 相似文献
1000.
Summary Synthesis of barbituric and thiobarbituric acid complexes derived from cobalt(II), nickel(II) and copper(II) salts were carried out. The elemental analyses suggest a range of stoichiometries, 11, 12 and 13. Electronic spectra and magnetic susceptibility measurements were used to infer the structures. The i.r. spectra of the ligands and their complexes are used to identify the type of bonding. 相似文献