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11.
Roksana Kordala-Markiewicz Hubert Rodak Bartosz Markiewicz Filip Walkiewicz Agata Sznajdrowska Katarzyna Materna Katarzyna Marcinkowska Tadeusz Praczyk Juliusz Pernak 《Tetrahedron》2014
Ammonium ionic liquids with the 4-chloro-2-methylphenoxyacetate anion were synthesized and characterized. Physicochemical properties, such as thermal stability, phase transition temperatures, viscosity, density, refractive index, as well as surface activity and herbicidal activity were determined. Improved physicochemical properties suggest a reduced environmental impact of newly formed group of herbicidal ionic liquids (HILs). HILs with a longer substituent can be characterized with better herbicidal activity in comparison with commercial products. 相似文献
12.
ABSTRACT An elastoplastic analysis of an axisymmetric cylinder subjected to linear body forces is presented. The effect of reinforcement and anisotropy are also included. Classical plasticity and familiar assumptions of plane stress and strain are used to arrive at closed-form solutions for the case of linear body forces. The problem is solved for the general case in which orthotropy is considered in the elastic range. For the case of plasticity, first the isotropic yield functions (von Mises and Tresca) are used and then the problem is extended to the case of Hill's yield criterion. Closed-form solutions are found for both the von Mises (plane strain) and Tresca (plane stress and strain) cases. 相似文献
13.
R. Bujakiewicz-Koronska L. Vasylechko E. Markiewicz D.M. Nalecz A. Kalvane 《Phase Transitions》2017,90(1):78-85
ABSTRACTThe crystal structure modifications of BaTiO3 induced by cobalt doping were studied. The polycrystalline (1 ? x)BaTiO3 + xCo2O3 samples, with x ≤ 10 wt.%, were prepared by high temperature sintering conventional method. According to X-ray phase and structural characterization, performed by full-profile Rietveld refinement technique, all synthesized samples showed tetragonal symmetry perovskite structure with minor amount of parasitic phases. Pure single-phase composition has been detected only in the low level of doping BaTiO3. It was indicated that substitution of Co for the Ti sites in the (1 ? x)BaTiO3 + xCo2O3 series led to decrease of tetragonality (c/a) of the BaTiO3 perovskite structure. This effect almost vanished in the (1 ? x)BaTiO3 + xCo2O3 samples with nominal Co content higher than ~1 wt.%, in which precipitation of parasitic Co-containing phases CoO and Co2TiO4 has been observed. Based on the results, the solubility limit of Co in Ti sub-lattice in the (1 ? x)BaTiO3 + xCo2O3 series is estimated as x = 0.75 wt.%. 相似文献
14.
In this paper we study modular extendability and equimodularity of endomorphisms and E0-semigroups on factors, when these definitions are recast to the context of faithful normal semifinite weights and this dependency is analyzed. We show that modular extendability is a property that does not depend on the choice of weights, it is a cocycle conjugacy invariant and it is preserved under tensoring. Furthermore, we prove a necessary and sufficient condition for equimodularity of endomorphisms in the context of weights. This extends previously known results regarding the necessity of this condition in the case of states. The classification of E0-semigroups on factors is considered: a modularly extendable E0-semigroup is said to be of type EI, EII or EIII if its modular extension is of type I, II or III, respectively. We prove that all types exist on properly infinite factors. We show that q-CCR flows are not extendable, and we extend previous results by the first author regarding the non-extendability of CAR flow to a larger class of quasi-free states. We also compute the coupling index and the relative commutant index for the CAR flows and q-CCR flows. As an application, by considering repeated tensors of the CAR flows we show that there are infinitely many non cocycle conjugate non-extendable E0-semigroups on the hyperfinite factors of types II1 and IIIλ, for . 相似文献
15.
A. Markiewicz D. V. Balbachas R. J. Fleming 《Journal of Thermal Analysis and Calorimetry》1991,37(6):1137-1152
Thermally stimulated luminescence (TSL) and thermally stimulated depolarization current (TSD) measurements were made simultaneously on low density polyethylene samples 0.175 mm thick, carrying evaporated gold electrodes. The samples were dc-polarized at room temperature at a field strength of 90 kV/cm, cooled to –190°C and X-irradiated with the field still applied, and then heated in short-circuit at 3 deg/min. Comparing the TSL and TSD data, particularly the effects of oxidizing the samples and immersing them in fuming nitric acid, it was shown that (1) the space-charge transport component of the TSD current between –190 and 30°C is negligible, (2) charge injection begins around –10°C (for evaporated gold electrodes) and increases rapidly with increasing temperature, and (3) all the injected charge is transported through the sample to the opposite electrode. Such transport takes place only through the amorphous regions of the sample.
Dedicated to Professor Dr. H. J. Seifert on the occasion of his 60th birthday 相似文献
Zusammenfassung Es wurden simultane TSL- und TSD-Messungen an 0.175 mm starken, über aufgedampfte Goldelektroden verfügende Polyethylenproben geringer Dichte durchgeführt. Die Proben wurden bei Raumtemperatur und einer Feldstärke von 90 kV/cm gleichstrompolarisiert, auf –190°C abgekühlt, bei noch anliegendem Feld röntgenbestrahlt und dann unter Kurzschluß mit 3 Grad/min erhitzt. Durch einen Vergleich der TSL- und TSD-Daten, insbesondere der Wirkung der Oxydation der Proben bzw. des Eintauchens in rauchende Salpetersäure, zeigten, daß (1) die Raumladungstransport-Komponente des TSD-Stromes zwischen –190 und 30°C vernachlässigbar ist, (2) die Ladungsinjektion bei etwa — 10°C beginnt (für aufgedampfte Goldelektroden) und mit steigender Temperatur schnell anwächst und (3) die gesamte injezierte Ladung durch die Probe hindurch an die gegenüberliegende Elektrode transportiert wird. Ein derartiger Transport erfolgt nur in den amorphen Regionen der Probe.
Dedicated to Professor Dr. H. J. Seifert on the occasion of his 60th birthday 相似文献
16.
D. Czakis-Sulikowska J. Radwańska-Doczekalska M. Markiewicz 《Monatshefte für Chemie / Chemical Monthly》1994,125(10):1075-1082
Summary New complexes of 2,2-dipyridyl and 4,4-dipyridyl with thulium salts TmX
3 (whereX=Cl–, Br–, NO
3
–
, NCS–, and ClO
4
–
) have been prepared and their solubilities in water at 21 °C were determined. The IR spectra of these compounds are discussed. The conditions of thermal decomposition of the complexes were also studied.
Synthese und Eigenschaften von 2,2-Dipyridyl- und 4,4-Dipyridylkomplexen mit Thuliumsalzen
Zusammenfassung Es wurden neue 2,2-Dipyridyl- und 4,4-Dipyridyl-Komplexen mit Thuliumsalzen TmX 3 (X=Cl–, Br– No 3 – , NCS–, ClO 4 – ) dargestellt und ihre Wasserlöslihkeit bei 21 °C bestimmt. Die IR-Spektren werden diskutiert. Das thermische Verhalten der erhaltenen Komplexe wurde untersucht.相似文献
17.
Agnieszka Czylkowska Danuta Czakis-Sulikowska Rafał Kruszyński Mirosława Markiewicz 《Structural chemistry》2010,21(2):415-423
A novel mixed-ligand complexes of Er(III), Yb(III) and Lu(III) with title ligands were prepared and characterized by chemical
and elemental analysis and IR spectroscopy, conductivity (in methanol, dimethyloformamide and dimethylsulphoxide). The thermal
properties of complexes in the solid state were studied. The mode of metal–ligand coordination was discussed. The title compounds
are isomorphic and isostructural in solid state. All atoms in studied compounds lie in general positions but occurrence of
inversion on the midpoint of the bond linking two pyridine rings leads to existence in asymmetric unit one complex molecule
and half of outer coordination sphere 4-bpy molecule. All chelating carboxylate groups are symmetrically bonded to the metal
cations. The molecules of studied compounds are connected to the three dimensional network via O–H···O and O–H···N intermolecular
hydrogen bonds. In the structures also exist C–H···O, C–H···Cl weak hydrogen bonds and π····π stacking interactions. 相似文献
18.
The Fermi surface (FS) of Bi2Sr2CaCu2O8+delta (Bi2212) predicted by band theory displays Bi-related pockets around the (pi, 0) point, which have never been observed experimentally. We show that when the effects of hole doping either by substituting Pb for Bi or by adding excess O in Bi2212 are included, the Bi-O bands are lifted above the Fermi energy (E(F)) and the resulting first-principles FS is in remarkable accord with measurements. With decreasing hole doping the Bi-O bands drop below and the system self-dopes below a critical hole concentration. Computations on other Bi- as well as Tl- and Hg-based compounds indicate that lifting of the cation-derived band with hole doping is a general property of the electronic structures of the cuprates. 相似文献
19.
ukasz Krupa Robert Staro Dorota Dulko Natalia oziska Alan R. Mackie Neil M. Rigby Adam Macierzanka Aleksandra Markiewicz Christian Jungnickel 《Molecules (Basel, Switzerland)》2021,26(23)
Determination of the cause of a biliary obstruction is often inconclusive from serum analysis alone without further clinical tests. To this end, serum markers as well as the composition of bile of 74 patients with biliary obstructions were determined to improve the diagnoses. The samples were collected from the patients during an endoscopic retrograde cholangiopancreatography (ERCP). The concentration of eight bile salts, specifically sodium cholate, sodium glycocholate, sodium taurocholate, sodium glycodeoxycholate, sodium chenodeoxycholate, sodium glycochenodeoxycholate, sodium taurodeoxycholate, and sodium taurochenodeoxycholate as well as bile cholesterol were determined by HPLC-MS. Serum alanine aminotransferase (ALT), aspartate transaminase (AST), and bilirubin were measured before the ERCP. The aim was to determine a diagnostic factor and gain insights into the influence of serum bilirubin as well as bile salts on diseases. Ratios of conjugated/unconjugated, primary/secondary, and taurine/glycine conjugated bile salts were determined to facilitate the comparison to literature data. Receiver operating characteristic (ROC) curves were determined, and the cut-off values were calculated by determining the point closest to (0,1). It was found that serum bilirubin was a good indicator of the type of biliary obstruction; it was able to differentiate between benign obstructions such as choledocholithiasis (at the concentration of >11 µmol/L) and malignant changes such as pancreatic neoplasms or cholangiocarcinoma (at the concentration of >59 µmol/L). In addition, it was shown that conjugated/unconjugated bile salts confirm the presence of an obstruction. With lower levels of conjugated/unconjugated bile salts the possibility for inflammation and, thus, neoplasms increase. 相似文献
20.
To assure safe ship operations on one hand side and to reduce operational restrictions to a minimum a proper knowledge of the ship's behavior in waves is necessary. One approach to achieve this is to generate an exact mathematical model of a ship and the fluid–structure–interaction in order to determine dangerous and safe operational conditions by analyzing the behavior with present numerical methods from nonlinear dynamics theory. Comparison between numerical simulations and experimental results as well as two sets of save and dangerous conditions for a given model of a real ship are shown. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献