Preconcentrative separation of chromium(III) species from chromium(VI) by cloud point extraction and determination by flame atomic absorption spectrometry

Microchimica Acta - We describe a high-throughput technique for the determination of chromium species in water samples by flame atomic absorption spectrometry (FAAS) after preconcentrative...     

Discrimination between ω-amino acids with chromogenic acyclic tripodal receptors functionalized with stilbazolium dyes

A tripodal receptor functionalized with a stilbazolium dye derivative has been designed, synthesized and has been used for the colorimetric discrimination between certain ω-amino acids in mixed DMSO-water 90:10 v/v solutions.     

Extending modules relative to a torsion theory

An R-module M is said to be an extending module if every closed submodule of M is a direct summand. In this paper we introduce and investigate the concept of a type 2 τ-extending module, where τ is a hereditary torsion theory on Mod-R. An R-module M is called type 2 τ-extending if every type 2 τ-closed submodule of M is a direct summand of M. If τ _I is the torsion theory on Mod-R corresponding to an idempotent ideal I of R and M is a type 2 τ _I -extending R-module, then the question of whether or not M/MI is an extending R/I-module is investigated. In particular, for the Goldie torsion theory τ _G we give an example of a module that is type 2 τ _G -extending but not extending.     

Ein Beitrag zur Theorie der linearen Holoide

Ohne Zusammenfassung     

Standardized method comparison for ACS:180 plus and Immulite sensitive PSA (sPSA) measurement methods

The aim of this study was to compare two immunoassay measurement methods, the ACS:180 Plus (Chiron Diagnostics) kit and the Immulite sPSA (DPC) kit. Method comparison analysis was performed according to EP9-A; approved guideline of NCCLS 51. Serum samples having a wide range of total prostate-specific antigen (PSA) concentrations were evaluated in split-sample analysis. F-test, t-test analysis and regression statistics were performed. In Deming regression analysis the coefficients were as follows; the slope=0.967; y-intercept=-0.148, r=0.989. An acceptable bias was seen since the systematical error was calculated to have a value less than the total allowable error calculated from biological variations. Non-parametric evaluation of the area under ROC curves for ACS:180 Plus and Immulite sPSA were 0.997 and 0.987, respectively. Diagnostic accuracy was at the level of p= 0.000 and no statistical difference was found between the two assay methods.     

Two non-linear azide containing heteronuclear complexes: crystal structure and thermal decomposition

Bis-N,N′(salicylidene)-2,2′-dimethyl-1,3-propanediamine (LDMH₂) has a high tendency to form polynuclear complexes. Two trinuclear complexes were obtained using this ligand and azide ions; (CuLDM)₂ · Mn(N₃)₂ · (DMF)₂, [(C₁₉H₂₀N₂O₂Cu)₂ · Mn(N₃)₂ · (C₃H₇NO)₂] and (CuLDM)₂ · Cd(N₃)₂ · (DMF)₂, [(C₁₉H₂₀N₂O₂Cu)₂ · Cd(N₃)₂ · (C₃H₇NO)₂]. The structures were identified with X-ray methods. TG and DSC methods were also employed to these complexes. Studies showed the (CuLDM)₂ · Mn(N₃)₂ · (DMF)₂ and (CuLDM)₂ · Cd(N₃)₂ · (DMF)₂ to be non-linear. Also μ-bridges were not encountered for the azide ions but were seen to form between the Cu and other metal via phenolic oxygens. Thermal analysis showed exothermic degradation of the azide ions destroying the trinuclear structure. Although azide containing structures show explosive characteristics, this was not observed for the present compounds.     

M?ssbauer spectroscopy in heterogeneous catalysis: A brief overview and recent study on paramagnetic features detected in catalytic centres of Fe-ZSM-5

A short retrospection is given on the development of M?ssbauer spectroscopy and on the early period of its application to heterogeneous catalysis in Hungary. Besides the historical view, we present results of recent studies of a latest application on a nanosystem. Namely, catalytic centres in Fe-ZSM-5 are studied by in situ spectroscopy, the results are correlated with parallel activity measurements in the decomposition of N₂O. Changes in paramagnetic relaxation features are interpreted as the effects of Fe²⁺/Fe³⁺ interconversions. From the analysis, the dominance of the mononuclear species is suggested at lower temperature (620 K). The dinuclear Fe⁽³⁺⁾ _framework-O-Fe⁽²⁺⁾ _{extra-framework} species play probably more expressed role at higher temperatures (∼ 770 K) in the decompositon of nitrous oxide.     

Über die v. Haerdtlsche Bahn

Ohne Zusammenfassung     

Dynamische interpretation von infrarotspektren

(Dynamic Interpretation of Infrared Spectra) Results of investigation of an algorithm, based on a novel static-dynamic method, for interpretation of infrared spectra are presented. The IRSCAN-D algorithm can recognize 103 infrared-active substructures comprising C, H, N, O, S, halogen, P and Si atoms. The results indicate that the algorithm is efficient; roughly 97% of the substructures are correctly ascribed, with a surprisingly low number (60%) of false recognition.