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71.
Dr. Yitao Dai Dr. Corentin Poidevin Dr. Cristina Ochoa-Hernández Prof. Dr. Alexander A. Auer Priv.-Doz. Dr. Harun Tüysüz 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(14):5837-5845
Direct selective oxidation of hydrocarbons to oxygenates by O2 is challenging. Catalysts are limited by the low activity and narrow application scope, and the main focus is on active C−H bonds at benzylic positions. In this work, stable, lead-free, Cs3Bi2Br9 halide perovskites are integrated within the pore channels of mesoporous SBA-15 silica and demonstrate their photocatalytic potentials for C−H bond activation. The composite photocatalysts can effectively oxidize hydrocarbons (C5 to C16 including aromatic and aliphatic alkanes) with a conversion rate up to 32900 μmol gcat−1 h−1 and excellent selectivity (>99 %) towards aldehydes and ketones under visible-light irradiation. Isotopic labeling, in situ spectroscopic studies, and DFT calculations reveal that well-dispersed small perovskite nanoparticles (2–5 nm) possess enhanced electron–hole separation and a close contact with hydrocarbons that facilitates C(sp3)−H bond activation by photoinduced charges. 相似文献
72.
Al-Ameen Bariz OmarAli Ahmed Jasim M. Al-Karawi Adil A. Awad Necmi Dege Sevgi Kansz Erbil Agar Zaman Ahmed Hussein Iman Rajab Mohammed 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(5):476-482
Reaction of N,N′‐(cyclohexane‐1,2‐diylidene)bis(4‐fluorobenzohydrazide), C20H18F2N4O2, ( LF ), with zinc chloride and mercury(II) chloride produced different types and shapes of neutral coordination complexes, namely, dichlorido[N,N′‐(cyclohexane‐1,2‐diylidene)bis(4‐fluorobenzohydrazide)‐κ2N,O]zinc(II), [ZnCl2(C20H18F2N4O2)], ( 1 ), and dichlorido[N,N′‐(cyclohexane‐1,2‐diylidene)bis(4‐fluorobenzohydrazide)‐κ4O,N,N′,O′]mercury(II), [HgCl2(C20H18F2N4O2)], ( 2 ). The organic ligand and its metal complexes are characterized using various techniques: IR, UV–Vis and nuclear magnetic resonance (NMR) spectroscopies, in addition to powder X‐ray diffraction (PXRD), single‐crystal X‐ray crystallography and microelemental analysis. Depending upon the data from these analyses and measurements, a typical tetrahedral geometry was confirmed for zinc complex ( 1 ), in which the ZnII atom is located outside the bis(benzhydrazone) core. The HgII atom in ( 2 ) is found within the core and has a common octahedral structure. The in vitro antibacterial activities of the prepared compounds were evaluated against two different bacterial strains, i.e. gram positive Bacillus subtilis and gram negative Pseudomonas aeruginosa bacteria. The prepared compounds exhibited differentiated growth‐inhibitory activities against these two bacterial strains based on the difference in their lipophilic nature and structural features. 相似文献
73.
K Nilson J Åhlund MN Shariati J Schiessling P Palmgren B Brena E Göthelid F Hennies Y Huismans F Evangelista P Rudolf M Göthelid N Mårtensson C Puglia 《The Journal of chemical physics》2012,137(4):044708
X-ray spectroscopy studies of potassium intercalated metal-free phthalocyanine multilayers adsorbed on Al(110) have been undertaken. Photoelectron spectroscopy measurements show the presence of several charge states of the molecules upon K intercalation, due to a charge transfer from the alkali. In addition, the comparison of valence band photoemission spectra with the density functional theory calculations of the density of states of the H(2)Pc(-) anion indicates a filling of the formerly lowest unoccupied molecular orbital by charge transfer from the alkali. This is further confirmed by x-ray absorption spectroscopy (XAS) studies, which show a decreased density of unoccupied states. XAS measurements in different experimental geometries reveal that the molecules in the pristine film are standing upright on the surface or are only slightly tilted away from the surface normal but upon K intercalation, the molecular orientation is changed in that the tilt angle of the molecules increases. 相似文献
74.
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76.
Laser cleaning of copper roofing sheets subjected to long-lasting environmental corrosion 总被引:1,自引:0,他引:1
H. Garbacz E. Fortuna J. Marczak M. Strzelec A. Rycyk A. Koss J. Mróz A. Zatorska K. J. Kurzyd?owski 《Applied Physics A: Materials Science & Processing》2010,100(3):693-701
The study was concerned with the effect of the laser fluence and pulse duration on the microstructure of copper roofing of
the Wilanów Palace in Warsaw (Poland) subjected to environmental degradation since the turn 19th century. The techniques used
for the microstructure examinations included: SEM+EDS, X-ray diffraction analysis, surface profiling and colour analysis.
The measurements of colour of the laser-cleaned surfaces showed that series of 100-μs pulses offer the most effective cleaning.
It was also found that by controlling the number of laser pulses it is possible to control the roughness of the cleaned surface. 相似文献
77.
László Lázár Erika Mező Mihály Herczeg András Lipták Sándor Antus Anikó Borbás 《Tetrahedron》2012,68(36):7386-7399
A glucoronic acid-containing trisaccharide related to the antithrombin-binding DEFGH domain of heparin and its methanesulfonic acid analogues were synthesized. Trisaccharides without sulfonic acid content or possessing a sulfonatomethyl moiety at position 2 or 6 of unit F were prepared in high yields by [DE+F] couplings using the same disaccharide uronate donor, respectively. Synthesis of the trisaccharide with a 3-deoxy-3-sulfonatomethyl function was accomplished in three different pathways, from which a [D+EF] coupling and applying a non-oxidized precursor of the glucuronic acid afforded the trisaccharide in the highest yield. 相似文献
78.
A model for the differential capacitance of metal electrodes coated by solid polymer electrolyte membranes, with acid/base groups attached to the membrane backbone, and in contact with an electrolyte solution is developed. With proper model parameters, the model is able to predict a limit response, given by Mott–Schottky or Gouy–Chapman–Stern theories depending on the dissociation degree and the density of ionizable acid/base groups. The model is also valid for other ionic membranes with proton donor/acceptor molecules as membrane counterions. Results are discussed in light of the electron transfer rate at membrane-coated electrodes for electrochemical reactions that strongly depend on the double layer structure. In this sense, the model provides a tool towards the understanding of the electro-catalytic activity on modified electrodes. It is shown that local maxima and minima in the differential capacitance as a function of the electrode potential may occur as consequence of the dissociation of acid/base molecular species, in absence of specific adsorption of immobile polymer anions on the electrode surface. Although the model extends the conceptual framework for the interpretation of cyclic voltammograms for these systems and the general theory about electrified interfaces, structural features of real systems are more complex and so, presented results only are qualitatively compared with experiments. 相似文献
79.
Cholesterol-oleate-doped polymer-dispersed liquid-crystal voltage-controlled ring projector 总被引:1,自引:0,他引:1
Olivares-Pérez A Pérez-Cortéz M Juãârez-Pérez JL Treviã O-Palacios CG 《Optics letters》2002,27(12):1022-1024
We report a cholesterol-oleate-doped polymer-dispersed liquid-crystal (PDLC) device that, under laser illumination, exhibits a ring diffraction pattern, the radius of which is controlled by an externally applied voltage. This effect is accurately explained by modeling of the random distribution of spiral cells shown in the microstructure with a voltage-dependent shape variation. 相似文献
80.
O. Çakır İ. T. Çakır H. Duran Yıldız R. Mehdiyev 《The European Physical Journal C - Particles and Fields》2008,56(4):537-543
We study the single production of fourth-family quarks through the process pp→Q′jX at the Large Hadron Collider (LHC). We have calculated the decay widths and branching ratios of the fourth-family quarks
(b′ and t′) in the mass range 300–800 GeV. The cross sections for the signal and background processes have been calculated in a Monte
Carlo framework. It is shown that the LHC can discover single t′ and b′ quarks if the CKM matrix elements |V
t′q
|,|V
qb′|≳0.01. 相似文献