X-ray crystal structure of tetraaquabis (xanthosinato)nickel(II) hexahydrate

The complex [Ni(XsH_–1)₂(H₂O)₄]·6H₂O (XsH_–1: xanthosinate) was isolated from the reaction of nickel carbonate with xanthosine in aqueous solution. The octahedral coordination is supported by the reflectance measurements. Single-crystal X-ray diffraction studies show that the crystals belong to the triclinic P1 space group, with a = 7.152(1), b = 8.830(1),c = 13.783(1) Å, = 82.024(1)°, = 86.155(1)°, = 70.900(1)°, and D = 1.643 mg/m³, forZ = 1. Nickel is six coordinate with four water molecules, and two N7 atoms from xanthosinato ligands. A complicated hydrogen-bonding network is present, all possible donors taking part in it.     

Synthesis of slagenins A, B, and C

[structure: see text] A short synthesis of the marine sponge metabolites slagenins A (1), B (2), and C (3) is described. The synthetic route features the preparation of beta-hydroxyimidazolone 4 from ornithine and its subsequent oxidative cyclization to the slagenin core.     

On the moving plane method for nonlocal problems in bounded domains

We consider a nonlocal problem involving the fractional Laplacian and the Hardy potential in bounded smooth domains. Exploiting the moving plane method and some weak and strong comparison principles, we deduce symmetry and monotonicity properties of positive solutions under zero Dirichlet boundary conditions.     

Ultra-high repetition rate InAs/InP quantum dot mode-locked lasers

We have designed, grown and fabricated InAs/InP quantum dot (QD) waveguides as the gain materials of mode-locked lasers (MLLs). Passive InAs/InP QD MLLs based on single-section Fabry-Perot (F-P) cavities with repetition rates from 10 GHz to 100 GHz have been demonstrated in the C- and L-band. Femtosecond (fs) pulses with pulse duration of 295 fs have been achieved. The average output power is up to 50 mW at the room temperature of 18 °C. By using the external fiber mixed cavities fs pulse train with a repetition rate of 437 GHz has been generated. We have also discussed the working principles of the developed QD MLLs.     

Velocity and timing of multiple spherically converging shock waves in liquid deuterium

The fuel entropy and required drive energy for an inertial confinement fusion implosion are set by a sequence of shocks that must be precisely timed to achieve ignition. This Letter reports measurements of multiple spherical shock waves in liquid deuterium that facilitate timing inertial confinement fusion shocks to the required precision. These experiments produced the highest shock velocity observed in liquid deuterium (U(s) = 135 km/s at ～2500 GPa) and also the first observation of convergence effects on the shock velocity. Simulations model the shock-timing results well when a nonlocal transport model is used in the coronal plasma.