Crystal structure of 1,4,7,10-tetraoxa-13-(4-acetylaminobenzosulfamido)azocyclopentadecane

All-Union Monomer Research and Project Institute. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 3, pp. 133–135, May–June, 1991.     

Dependence of the energy of surface-active substances/metal interaction on their ionization potentials. Evaluation of hydrophilicity of metal

The function Δ(ΔG _A ⁰), which is the difference of Gibbs energies characterizing surface-active substance (surfactant, SAS) adsorption at metal/solution and air/solution surfaces, has been introduced. The equation connecting the function Δ(ΔG _A ⁰) with SAS ionization potential has been obtained using the elementary theory of donor-acceptor interactions. Published experimental data on SAS adsorption at mercury, bismuth and gold have been used for Δ(ΔG _A ⁰) calculation. The dependence of Δ(ΔG _A ⁰) on ionization potentials can be described by an equation derived in this work. It has been demonstrated that the value of the hydrophilicity of gold is much higher than the values for mercury and bismuth. The lifetime of SAS molecules at a metal surface has been estimated. The question of the possibility of theoretica l estimation of standard energies ΔG _A ⁰ characterizing SAS adsorption at a metal/solution surface has been discussed. Received: 9 December 1996 / Accepted: 13 January 1997     

Analysis of a shielded TE011 mode composite dielectric resonator for stable frequency reference

Analysis of a TE₀₁₁ mode composite sapphire-rutile dielectric resonator has been carried out to study the temperature variation of resonance frequency, close to the Cs atomic clock hyperfine frequency of 9.192 GHz. The complementary behavior of dielectric permittivity with temperature of the composite has been exploited to obtain the desired turning point in the resonant frequency. The frequency of the composite structure is found to be independent of the shield diameter beyond four times the puck diameter.     

Production of a monochromatic γ-ray beam by a Li7(p, γ)Be8 reaction

A procedure is described for producing a monochromatic beam of 17.6 and 14.8 MeV -rays. Energy calibrations are reported for a single-crystal total-absorption -spectrometer and for the proton beam of an electrostatic generator during the resonant capture of protons by lithium target nuclei in a Li⁷(p, )Be⁸ reaction.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, Vol. 12, No. 5, pp. 18–21, May, 1969.The authors thank E. M. Vasil'ev and G. V. Zinger for arranging stable operation of the ÉSG-2.5 of the Scientific Research Institute of Nuclear Physics, Tomsk Polytechnic Institute.     

Conducting Polymer Coated DNA

Gold electrode was modified with a 4-aminothiophenol layer (4-ATPh) to immobilize DNA. The immobilized DNA served as a template for the alignment of positively charged anilinium ions. The electrochemical oxidation of the anilinium ions resulted in wrapping of the DNA with polyaniline. This polyaniline coated DNA was characterized by cyclic voltammetry (CV), impedance spectroscopy and UV-VIS absorption spectroscopy.     

Self-assembly of C60 fullerenes on quasi-one-dimensional Si(111)4 × 1-In surface

Using scanning tunneling microscopy observations, self-assembly of C₆₀ fullerenes in the course of room-temperature adsorption onto Si(111)4 × 1-In reconstruction and after subsequent annealing at temperatures ranging from 150 to 450 °C has been studied. Adsorbed C₆₀ fullerenes have been found to occupy off-centered positions on In-atom rows forming linear chains with a maximal length of eight C₆₀ molecules. Intermolecular spacing within the regular chains equals three lattice constants of Si(111) surface. Two energetically different adsorption states of C₆₀ have been detected, one of which is occupied preferentially at room temperature, while occupation of the second (more tight) state dominates at temperature above ~ 150 °C. In the first state, C₆₀ fullerene resides plausibly in a continuous rotation, while in the second state a C₆₀ molecule is fixed tightly in a single orientation with a C₆₀ hexagon pointing upward. Transition of C₆₀ fullerenes to the more stable state is accompanied by expelling In atoms from the Si(111)4 × 1-In reconstruction.     

Evolution of the Shape of the Anode Boundary under Electrochemical Dimensional Machining of Metals

This paper presents a method for calculating the anode boundary under unsteady conditions of electrochemical dimensional machining of metals. The plane quasistationary problem of determining the shape of the anode boundary for various machining times is considered.     

Numerical investigation and self-similar solutions of the glacier-ocean interaction problem

The mathematical modeling of the heat and mass transfer processes in glaciers is an effective means of investigating and predicting their development. A full explanation of the problem of constructing appropriate mathematical models is given in [1–5]. By analyzing the equations involved [3, 6] it is possible to establish the principal factors and dimensionless numbers determining glacier dynamics and provide justification for neglecting the secondary terms. In particular, a simplified closed system of differential equations for the detailed calculation of all the hydrodynamic characteristics of the glacier can be obtained for K_hj « 1 up to O(K _h ² ), where K_h is the ratio of the vertical and horizontal scales of the ice mass investigated (K_h 10^–4–10^–6). In this case many of the qualitative characteristics of glacier dynamics are preserved even in one-dimensional models within the subisothermal approximation.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 3–7, September–October, 1986.