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1.
It is shown that the introduction of heavy inert gas impurities into the condensed phase of a lighter inert gas can significantly change the kinetic properties of the latter at high pressures. The electronic structure of the ordered Ar15Xe solid solution is calculated. Doping of the condensed phase of a light inert gas with atoms of a heavier inert gas may become a new convenient tool in high-pressure experiments. 相似文献
2.
We analyze the analog of the Kelvin-Helmholtz instability on the free surface of a superfluid liquid. This instability is
induced by the relative motion of superfluid and normal components of the same liquid along the surface. The instability threshold
is found to be independent of the value of viscosity, but turns out to be lower than in the absence of dissipation. The result
is similar to that obtained for the interface between two sliding super-fluids (with different mechanisms of dissipation)
and confirmed by the first experimental observation of the Kelvin-Helmholtz instability on the interface between 3He-A and 3He-B by Blaauwgeers et al. (cond-mat/0111343). 相似文献
3.
M. A. Korshunov 《Optics and Spectroscopy》2002,92(2):189-190
Polarized spectra of low-frequency Raman scattering in solid solutions of paradibromobenzene with parachloronitrobenzene in the α phase are studied at temperatures of 293 and 77 K. The solid solution spectrum is found to be similar to the paradibromobenzene spectrum (in accordance with the X-ray diffraction data), but has a series of additional low-intensity lines resulting from disordering. As the parachloronitrobenzene concentration increases, frequencies of the solid solution orientation vibrations decrease steadily, and the half-widths grow. Frequency spectra of the mixed crystal are calculated by the Dean method. 相似文献
4.
E. V. Sennikova A. S. Antsyshkina G. G. Sadikov A. V. Bicherov O. Yu. Korshunov G. S. Borodkin M. S. Korobov V. S. Sergienko N. N. Kharabaev A. D. Garnovskii 《Russian Journal of Coordination Chemistry》2008,34(5):315-321
The chelate and molecular complexes of 2-(2-benzazolyl, perimidyl)-indandiones-1,3 were synthesized for the first time. The structures of the ligands (tautomeric forms) and complex compounds were determined from the X-ray diffraction, 1H, 13C NMR, and IR data and the quantum-chemical calculations (RHF SCF in 6-31 G** basis). 相似文献
5.
Based on polarization measurements of the low-frequency Raman spectra of p-bromochlorobenzene and calculations of the frequency spectra of lattice vibrations by the Dean method it is shown that the
structure may contain vacancies. Their presence affects the appearance of additional lines in the low-frequency spectrum,
particularly in the vicinity of 70 cm−1, and their positions depend weakly on the orientational disorder of the molecules with respect to the para substituents. The activation energies for diffusion in a randomly disordered p-bromochlorobenzene crystal with vacancies in the structure is calculated from atom-atom potentials. It is shown that the
value of the activation energy varies along a selected direction and depends on the arrangement of the p-bromochlorobenzene molecules with respect to the para substituents, in contrast to the results for ordered p-dibromobenzene and p-dichlorobenzene.
Fiz. Tverd. Tela (St. Petersburg) 40, 1835–1838 (October 1998) 相似文献
6.
N. N. Kolos V. D. Orlov E. K. Slobodina E. Yu. Yur'eva S. P. Korshunov Zyong van Tué 《Chemistry of Heterocyclic Compounds》1992,28(2):222-227
1,2,4-Triazolo[3,4-b]-1,3,4-thiadiazines, hydrazones, and -thio adducts were obtained by reactions of 4-amino-3-mercapto-1,2,4-triazole with -bromoacetophenones, aldehydes, and ,-unsaturated ketones. Conditions that promote the cyclocondensation of the -thio adducts to the previously undescribed 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazepines were found. The chemical and spectral properties of the compounds obtained are discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 267–272, February, 1992. 相似文献
7.
MM. J. Duflos D. Letouz G. Queguiner P. Pastour 《Journal of heterocyclic chemistry》1973,10(6):1083-1084
This communication describes the synthesis of l-methyl-2,3-diformylpyrrole. This new compound is used to prepare a new heterocycle, l-methylcyclohepta[b]pyrrol-6-one and thus allows a new synthesis of l-methylpyrrolo[2,3-d]pyridazine. 相似文献
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