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排序方式: 共有209条查询结果,搜索用时 46 毫秒
101.
Lazar A Danylyuk O Suwinska K Perret F Coleman AW 《Chemical communications (Cambridge, England)》2006,(8):903-905
An extremely complex solid state structure described by two virtual channels and a 2-D square grid of hydrogen bonds is generated by four carboxylic acids groups of calix[4]arene tetrabutyroxycarboxylic acid. 相似文献
102.
Ghosh R Shen X Villegas JC Ding Y Malinger K Suib SL 《The journal of physical chemistry. B》2006,110(14):7592-7599
Manganese oxide octahedral molecular sieves having 2 x 2 tunnel structure (OMS-2) and synthesized by different methods were used for studying styrene oxidation with tert-butyl hydroperoxide (TBHP) as the oxidant. The catalytic activity of the as-synthesized OMS-2 materials was investigated. The physical and chemical properties of the OMS-2 materials are related to their activity in styrene oxidation. This particular study emphasizes the acid-base properties and the porous nature of these materials, and their role in styrene oxidation. Results of styrene oxidation reveal that acidity coupled with high porosity play a crucial role in these catalytic reactions. A desired acidity coupled with pore volume found in OMS-2 synthesized by reflux methods (OMS-2(R)) and high-temperature methods (OMS-2(HT)) produces materials with higher styrene conversion and styrene oxide selectivity when compared with OMS-2 synthesized by solvent free (OMS-2(S)), microwave (OMS-2(MW)), or hydrothermal methods (OMS-2(HY)). Transition metal doped OMS-2 catalysts show better selectivity of styrene oxide when compared to their undoped catalysts. 相似文献
103.
A novel molecularly imprinted polymer (MIP) for vanillin was prepared by photo initiated polymerization in dichloromethane using a mixed semi-covalent and non-covalent imprinting strategy. Taking polymerisable syringaldehyde as “dummy” template, acrylamide was chosen as functional monomer on B3LYP/6-31+G(d,p) density functional theory computational method basis with counterpoise. The binding parameters for the recognition of vanillin on imprinted polymers were studied with three different isotherm models (Langmuir, bi-Langmuir and Langmuir–Freundlich) and compared. The results indicate an heterogeneity of binding sites. It was found and proved by DFT calculations that the specific binding of vanillin in the cavities is due to non-covalent interactions of the template with the hydroxyphenyl- and the amide-moieties. The binding geometry of vanillin in the MIP cavity was also modelled. The obtained MIP is highly specific for vanillin (with an imprinting factor of 7.4) and was successfully applied to the extraction of vanillin from vanilla pods, red wine spike with vanillin, natural and artificial vanilla sugar with a recovery of 80%. 相似文献
104.
Kinga Pielichowska Ewa Dryzek Zbigniew Olejniczak Elżbieta Pamuła Joanna Pagacz 《先进技术聚合物》2013,24(3):318-330
In this work, isothermal crystallization kinetics of polyoxymethylene copolymer (POM) in POM/hydroxyapatite (HAp) nanocomposites has been investigated. Melting behavior and crystalline structure formation were studied using TOPEM DSC, positron lifetime spectroscopy (PALS), atomic force microscopy (AFM) and 13C and 31P solid‐state NMR. The highest degree of crystallinity was found for POM/0.5% HAp nanocomposite and the lowest for POM/2.5% HAp. Isothermal crystallization analysis showed that an introduction of HAp nanoparticles led to effective heterogeneous nucleation and formation of crystals with higher Avrami exponent. Besides, changes in overall crystallization rate were observed – the highest overall crystallization rate was found for POM/0.5% HAp sample, while the lowest for POM/2.5% HAp was observed. Generally, for POM in POM/HAp nanocomposites, a significant decrease in nucleation activation energy (Kg), and the fold surface free energy (σe) was found. For nanocomposite containing 2.5% HAp, heterogeneous nucleation takes place as well, but too high concentration of nanoparticles hinders POM crystallization and enhances formation of more defected crystals as confirmed by AFM data. The presence of HAp nanoparticles in the POM matrix was confirmed by 31P MAS‐NMR, but their influence on the crystallization process was not observed in the 13C CP‐MAS‐NMR spectra. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
105.
106.
Vladimíra Novotná Kinga Mieczkowska Věra Hamplová Attila Domján Damian Pociecha Miroslav Kašpar 《Liquid crystals》2013,40(10):1252-1260
The synthesis and mesomorphic properties of new non-symmetrical bent-shaped compounds containing a chiral moiety are reported. These materials were built up from 3-hydroxybenzoic acid as a central unit with a chiral terminal group derived from lactic acid. A columnar phase of the B1REV type with tilted molecules was observed in a wide temperature range down to room temperature. The ferroelectric-like character of switching with one peak in a half-period of the triangular electric field was observed and supported by texture observations and electro-optical changes. A longer terminal group ending with a double bond makes the compounds ready for polymerisation. 相似文献
107.
108.
Bruska MK Czekaj I Delley B Mantzaras J Wokaun A 《Physical chemistry chemical physics : PCCP》2011,13(35):15947-15954
PdO is one of the most important catalytic materials currently used in the industry. In redox catalytic reactions involving PdO, the bulk phase is an additional source of oxygen. This leads to strong transformations not only at the surface of PdO but also in the near sub-surface and bulk regions. The redox process is, therefore, governed not only by the extent of PdO d-band filling, but also depends on the material properties of the PdO crystal--the ease with which its structure can be deformed. Methane oxidation is of key industrial interest, and therein the rate of CH(4) conversion depends strongly on the reversible oxygen defects formation on the surface and in the bulk of the catalyst. The present study gives a first insight into these complex phenomena at the atomistic level. Comparison of different density functional theory (DFT) approaches and their capacity to reproduce experimental values of the heat of formation as well as the band gap of the PdO are discussed in detail. Results from DFT calculations for an oxygen vacancy creation in the bulk and on the surface of PdO are presented and compared at the level of accuracy of the implemented approaches with defect calculations for ZnO. Many different modeling approaches based on functionals and pseudopotentials (non-modified PP and empirically tuned) have been evaluated in their aptness to capture key PdO properties. It was shown that simulations with the PP-115 pseudopotential gave the closest possible agreement to the relevant PdO thermodynamic data and energy of oxygen vacancy formation. 相似文献
109.
Henryk Piekarski Alina Piekarska Kinga Kubalczyk 《The Journal of chemical thermodynamics》2011,43(9):1375-1380
Heat capacities and speed of sound of (acetonitrile + 2-methoxyethanol) mixtures at 298.15 K and the densities of the same mixtures at T = (308.15 and 318.15) K were determined over the whole composition range. The excess of molar volume and isobaric heat capacity of the mixture, the partial molar volumes and heat capacities of both components of the mixture as well as the adiabatic and isothermal coefficients of compressibility and their excess were calculated from the obtained experimental data. The internal pressure of the examined system was also calculated. The results of investigations were analyzed and discussed. The behavior of the analyzed functions is similar to that observed in the case of the mixtures of acetonitrile with some aprotic solvents examined earlier. 相似文献
110.
Attempts to develop new technologies of NO
x
(NO + NO2) emission reduction are still carried out all around the world. One of the relatively new approaches is the application of
ozone injection into the exhaust gas stream followed by the absorption process. Ozone is used to transform NO
x
to higher nitrogen oxides which yield nitric acid with better effectiveness. The main objective of this paper was to study
the influence of mole ratio (MR) O3/NO used in the ozonation process of NO
x
on the effectiveness of NO
x
oxidation to higher oxides. The ozonation process was carried out in a flow reactor for concentrations of nitric oxide in
the range of 1.5 × 10−5−7.7 × 10−5 mol dm−3 and varying O3/NO mole ratios. Measurements were conducted with the use of a FTIR spectrometer. The results obtained prove that for MR higher
than 1, the oxidation effectiveness of nitric oxides generally reaches 95 %, whereas for MR higher than 2, oxidation of NO
x
to higher nitrogen oxides is completed. 相似文献