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61.
62.
Guo Xue Feng Yurun Ma Li Yu Jincheng Jing Jie Gao Dezhi Khan Adil Saleem Gong Hongyu Zhang Yujun 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(1):397-407
Nickel hydroxide solubility has been studied in this work in different cementitious systems. Our results indicate that once Glenium® 27, cement superplasticizer admixture, is added to water and then mixed with cement, this polymeric material is stabilized and not released back to the aqueous solution, with negligible effects on the mobility of nickel. Contrary to that, when Glenium® 27 is added directly in solution at high dosages, an important effect is observed on nickel behaviour. Thermodynamic calculations indicate that the effect of such component on Ni is likely the effect that other small organics could have over this element.
相似文献63.
Porphyrin-metal complexes are potentially useful to catalyze redox reactions, which convert toxic and biologically recalcitrant
compounds to compounds that are less toxic and more amenable to biotreatment. Porphyrins, in the absence of proteins as in
ligninases, peroxidases, and oxidases, are potentially more robust than enzymes and microbial cultures in the treatment of
inhibitory substances.
2,4,6-Trichlorophenol was used as a model compound for chlorinated phenols and as a substrate for various porphyrin-metal
complexes acting as oxidation catalysts. t-Butyl hydroperoxide was the oxidizing agent. TCP was shown to be at least partially
dechlorinated and the aromatic ring broken in reaction products. All porphyrins exhibited saturation kinetics with regard
to the initial TCP concentration in reaction mixtures. Electron-withdrawing substituents on the porphyrins were observed to
increase stability of the catalysts to inactivating ring-centered oxidation. 相似文献
64.
65.
Akbar Ali Mukhtar Ahmad Majid Niaz Akhtar Saleem Farooq Shaukat Ghulam Mustafa M. Atif W. A. Farooq 《Russian Journal of Applied Chemistry》2016,89(4):517-534
Nanobiotechnology has opened a new and exciting opportunities for exploring urea biosensor based on magnetic nanoparticles (NPs) mainly Fe3O4 and Co3O4. These NPs have been extensively exploited to develop biosensors with stability, selectivity, reproducibility and fast response time. This review gives an overview of the development of urea biosensor based on Fe3O4 and Co3O4 for in vitro diagnostic applications along with significant improvements over the last few decades. Additionally, effort has been made to elaborate properties of magnetic nanoparticles (MNPs) in biosensing aspects. It also gives details of recent developments in hybrid nanobiocomposite based urea biosensor. 相似文献
66.
Shaikh S Muneera MS Thusleem OA Tahir M Kondaguli AV Ruckmani K 《Journal of chromatographic science》2007,45(6):311-314
A new specific, accurate, precise, and reproducible selective online dissolution method for rosiglitazone maleate is developed and validated for the dissolution of rosiglitazone maleate in pharmaceutical formulations. The rationale of the method is based on the direct measurement of the absorbance of the analyte in the buffer medium at 242 nm using buffer as blank. Dissolution is achieved on a dissolution test apparatus consisting of photo diode array spectrophotometer, peristaltic pump, and temperature controller, using 0.01N HCl and 0.05M potassium chloride as the dissolution medium. The proposed method is developed, optimized, and validated in terms of linearity, reproducibility, accuracy, and selectivity for the dissolution of rosiglitazone maleate in pharmaceutical formulations. The method is found to be linear in the range of 1 to 14 microg/mL of rosiglitazone maleate with a correlation coefficient of 0.999. The dissolution studies of rosiglitazone maleate tablets obtained by the proposed method are in good agreement with those by high-performance liquid chromatography. 相似文献
67.
This paper describes the peristaltic motion of a non-Newtonian fluid in a channel having compliant boundaries. Constitutive equations for a Maxwell fluid have been used. Perturbation method has been used for the analytic solution. The influence of pertinent parameters is analyzed. Comparison of the present analysis of Maxwell fluid is made with the existing results of viscous fluid. 相似文献
68.
We propose a way to manipulate the landscape of the superconducting condensate in thin films via stripe-like (1D) and checkerboard (2D) periodic patterns. Our approach is based on the spatially localized heating of the superconductor, which is reflected in sinusoidal variations of the local temperature, which can be produced via, e.g., a focused laser beam or nanoheaters. This simple approach provides a very good alternative for modulation of the vortex collective, emerging in the type-II superconductors as a natural response to the applied magnetic field and the transport current, which was, up to now, controlled mainly via nanofabricated static pinning centers, whose distribution cannot be changed once the landscape is defined. 相似文献
69.
The present paper addresses the megnetohydrodynamic Jeffrey fluid flow with heat and mass transfer on an infinitely rotating upright cone. Inquiry is carried out with heat source/sink and chemical reaction effects. Further, constant thermal and concentration flux situations are imposed. Optimal homotopy analysis method (OHAM) is employed to achieve series solutions of the concerned differential equations. Important results of the flow phenomena are explored and deliberated by means of graphs and numerical tables. It is perceived that thermal boundary layer thickness possess contrast variations for the heat source and heat sink, respectively. The chemical reaction enhances the heat transfer rate but decline the mass transfer rate. Moreover, the precision of the existing findings is verified by associating them with the previously available work. 相似文献
70.
Muhammad Saleem Anser Ali Chang-Shik Choi Bong Joo Park Eun Ha Choi Ki Hwan Lee 《Journal of fluorescence》2014,24(4):995-1001
In recent years, fluorescent probes for the detection of environmentally and biologically important metal cations have received extensive attention for designing and development of fluorescent chemosensors. Herein, we report the photophysical results of 2-(2-fluorobenzoyl)-N-(2-methoxyphenyl) hydrazinecarbothioamide (4) functionalized as Ni (II) sensor in micromolar concentration level. Through fluorescence titration at 488 nm, we were confirmed that ligand 4 showed the remarkable emission by complexation between 4 and Ni (II) while it appeared no emission in case of the competitive ions (Cr3+, Fe2+, Co2+, Ba2+, Cu2+, Ca2+, Na+, K+, Cu+, Cs+). Furthermore, ligand 4 exhibited no toxicity with precise cell permeability toward normal living cells using L929 cell lines in bio imaging experiment investigated through confocal fluorescence microscope. The non-toxic behavior of ligand 4 (assessed by MTT assay) and its ability to track the Ni2+ in living cells suggest its possibility to use in biological system as nickel sensor. Figure
? 相似文献