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61.
A surface preparation method with fine SiO2 particles in water is developed to flatten Si(0 0 1) surfaces on the nanometer scale. The flattening performance of Si(0 0 1) surfaces after the surface preparation method is investigated by scanning tunneling microscopy. The observed surface is so flat that 95% of the view area (100 × 100 nm2) is composed of only three atomic layers, namely, one dominant layer occupying 50% of the entire area and two adjacent layers. Furthermore, a magnified image shows the outermost Si atoms regularly distributed along the 〈1 1 0〉 direction on terraces. 相似文献
62.
A. Sagisaka A.S. Pirozhkov H. Daido A. Fukumi Z. Li K. Ogura A. Yogo Y. Oishi T. Nayuki T. Fujii K. Nemoto S. Orimo M. Nishiuchi Y. Hayashi M. Mori M. Kado S. Nakamura A. Noda I.W. Choi J.H. Sung D.-K. Ko J. Lee 《Applied physics. B, Lasers and optics》2006,84(3):415-419
A two-color interferometer for preformed plasma characterization is developed. We observe the electron density distribution of preformed plasmas on a 5 μm-thick copper target irradiated with a high-intensity Ti:sapphire laser. The two-color interferometer extended the observable electron density region using a fundamental (800 nm) probe beam to cover the lower density region and a second harmonic (400 nm) probe beam to cover the higher density region, simultaneously. This characterization of the electron density distribution of preformed plasmas with femtosecond time resolution significantly contributes to the understanding of high-intensity laser–thin-foil interactions during high-energy electron, ion, and X-ray generation. PACS 52.38.-r; 52.50.Jm; 52.70.-m 相似文献
63.
64.
65.
Bang JK Naka H Teruya K Aimoto S Konno H Nosaka K Tatsumi T Akaji K 《The Journal of organic chemistry》2005,70(25):10596-10599
[reaction: see text] The solid-phase Horner-Emmons reaction was successfully applied for the convenient syntheses of olefin-containing protease inhibitors. The isomerization during the solid-phase Horner-Emmons reaction can be minimized simply by the use of an appropriate amount of the base. The synthesized olefin peptides, which have an olefin gamma-amino acid at the scissile site, were found to act as effective inhibitors for the HTLV-1 protease for the first time. 相似文献
66.
Umebayashi Y Mroz B Asada M Fujii K Matsumoto K Mune Y Probst M Ishiguro S 《The journal of physical chemistry. A》2005,109(21):4862-4868
Solvation structure of the zinc(II) ion in N,N-dimethylpropionamide (DMPA) was studied by Raman spectroscopy at varying temperature and by quantum mechanical calculations. No significant ion-pair formation was found for the Zn(ClO4)2 solution in the molality range m(Zn) < 1.5 mol kg(-1), and the solvation number of the zinc(II) ion was determined to be 4, indicating that 6-coordination of DMPA is sterically hindered. Interestingly, DMPA molecules are under equilibrium between planar cis and nonplanar staggered conformers, and the latter is more preferred in the coordination sphere, while the reverse is the case in the bulk. The DeltaG degrees , DeltaH degrees , and TDeltaS degrees values of conformational change from planar cis to nonplanar staggered in the coordination sphere were obtained to be -0.9, -8.5, and -7.5 kJ mol(-1), respectively. Density functional theory (DFT) calculations show that the planar cis conformer is more favorable than the nonplanar staggered one in the 1:2 cluster, as is the case for a single DMPA molecule and H(DMPA)+, indicating that there hardly occurs solvent-solvent interaction through the metal ion in the Zn2+-DMPA 1:2 cluster. On the other hand, the SCF energy of [Zn(planar cis-DMPA)4-n(nonplanar staggered DMPA)n]2+ (n = 0-4) decreases with increasing n, implying that the nonplanar staggered conformer is preferred in the solvate ion. It is thus concluded that solvent-solvent interaction through space, or solvation steric effect, plays a crucial role in the conformational equilibrium in the coordination sphere of the four-solvate metal ion. 相似文献
67.
K. Oishi Y. Arai S. Mayama S. Murayama K. Fukuda 《Spectrochimica Acta Part B: Atomic Spectroscopy》1980,35(3):155-162
A new atomic-absorption spectrophotometer using the Zeeman effect, in which the magnetic field is applied to the light source, is described. A steady magnetic field of 3.8 kG was applied to conventional hollow-cathode lamps, which were operated using a high frequency power of 100 MHz.The π-and σ-components of the Zeeman split atomic lines were observed alternatively after traversing a flame. The absorbance difference between of the two Zeeman components was proportional to the atomic-absorption and was not influenced by background absorption. Dependences of atomic absorption signals on magnetic field strengths which were in close relation to profiles of absorption lines were measured for elements Cd, Mg, Pb, Cr, Cu and Mn by scanning of magnetic field strength. 相似文献
68.
Tetraalkylphosphonium-based amino-acid ionic liquids show lower viscosities and higher decomposition temperatures (>300 degrees C) than previously reported ammonium-based amino-acid ionic liquids. 相似文献
69.
Kawasaki T Suzuki K Hatase K Otsuka M Koshima H Soai K 《Chemical communications (Cambridge, England)》2006,(17):1869-1871
Enantiomorphous crystals composed of achiral hippuric acid, i.e., naturally occurring N-benzoylglycine, have been used successfully as chiral inducers in enantioselective synthesis in combination with asymmetric autocatalysis to afford the product with extremely high enantiomeric excess. 相似文献
70.
M. Mihara T. Izumikawa H. Ueno K. Matsuta D. Nishimura T. Nagatomo T. Moriguchi Y. Ito D. Nagae M. Fukuda A. Yoshimi K. Yamada M. Takechi Y. Ichikawa S. Momota Y. Hirayama T. Ohtsubo S. Suzuki T. Kubo Y. Namiki A. Ozawa Y. Ishibashi H. Oishi K. Suzuki I. Hachiuma K. Namihira D. Horikawa T. Minamisono T. Yamaguchi T. Kuboki T. Suzuki K. Satoh Y. Kobayashi K. Asahi K. Matsukawa K. Shirai 《Hyperfine Interactions》2010,197(1-3):143-147
The β-NMR study of short-lived nucleus 58Cu (I π ?=?1?+?, T 1/2?=?3.2 s) in Si has been performed. Spin polarization of 58Cu induced by the charge exchange reaction of 58Ni was observed in Si at 15 K. The 58Cu magnetic moment $|\upmu[^{58}\mbox{Cu}]| = (0.46 \pm 0.03)\upmu_{\rm N}$ deduced from the β-NMR spectrum is consistent with the previous results on the laser spectroscopy. The present result shows that the 58Cu nucleus is promising as a new nuclear probe for the microscopic study of Cu impurities in Si. 相似文献