全文获取类型
收费全文 | 557篇 |
免费 | 13篇 |
国内免费 | 3篇 |
专业分类
化学 | 360篇 |
晶体学 | 20篇 |
力学 | 11篇 |
数学 | 34篇 |
物理学 | 148篇 |
出版年
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 10篇 |
2014年 | 8篇 |
2013年 | 17篇 |
2012年 | 29篇 |
2011年 | 31篇 |
2010年 | 19篇 |
2009年 | 19篇 |
2008年 | 25篇 |
2007年 | 30篇 |
2006年 | 26篇 |
2005年 | 33篇 |
2004年 | 23篇 |
2003年 | 27篇 |
2002年 | 14篇 |
2001年 | 5篇 |
2000年 | 12篇 |
1999年 | 15篇 |
1998年 | 5篇 |
1997年 | 16篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 15篇 |
1991年 | 9篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 10篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 6篇 |
1979年 | 12篇 |
1978年 | 8篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
排序方式: 共有573条查询结果,搜索用时 31 毫秒
71.
A high-spin ground state is possible if a molecule has degenerate or pseudo-degenerate frontier orbitals. Since strong vibronic couplings, or electron-vibration interactions give rise to reduce the degeneracy or pseudo degeneracy, a lower-spin state is the ground state in such a molecule. Therefore small vibronic couplings are desirable for designing molecules with a high-spin ground state. Vibronic coupling constants of derivatives of m-phenylene diamine are evaluated. The calculated results are analyzed based on vibronic coupling density which enables us to control the vibronic coupling constants. Based on the vibronic coupling density analysis, we succeed in recovering the high-spin ground state from the closed-shell singlet ground state of a methoxy derivative of m-phenylene diamine by introducing an appropriate substituent. 相似文献
72.
Maehara S Ikeda M Haraguchi H Kitamura C Nagoe T Ohashi K Shibuya H 《Chemical & pharmaceutical bulletin》2011,59(8):1042-1044
We investigated the microbial conversion of curcumin (1) using endophytic fungi associated with the rhizome of Curcuma longa (Zingiberaceae). We found that Diaporthe sp., an endophytic filamentous fungus, converts curcumin (1) into four colorless derivatives, namely (3R,5R)-tetrahydrocurcumin (2), a novel (3R,5S)-hexahydrocurcumin (3) named neohexahydrocurcumin, (3S,5S)-octahydrocurcumin (4) and meso-octahydrocurcumin (5). 相似文献
73.
Kim SY Kashiwada Y Kawazoe K Murakami K Sun HD Li SL Takaishi Y 《Chemical & pharmaceutical bulletin》2011,59(10):1281-1284
Four new lindenane sesquiterpenoid dimers, spicachlorantins G-J (1-4), were isolated from the roots of Chloranthus spicatus together with seven known compounds, including chloramultilide A, shizukaol B, shizukaol D, shizukaol F, shizukaol P, chlorahololide D, and cycloshizukaol A. The planar structures of the new compounds were established by 1D-, 2D-NMR, and MS analyses. The absolute configurations of these compounds were determined by analyzing rotating Overhauser enhancement and exchange spectroscopy (ROESY) and circular dichroism (CD) spectra. 相似文献
74.
Eiichi Masumoto Hiroshi Maruoka Fumi Okabe Sho Nishida Yuki Yoshimura Toshihiro Fujioka Kenji Yamagata 《Journal of heterocyclic chemistry》2011,48(1):96-104
Dihydropyridazinones 4a , 4b , N‐substituted dihydropyrazoles 5b , 5c , 5d , and O‐substituted pyrazoles 6a , 6b , 6c , 6d have been synthesized starting from spirocyclopropanepyrazole derivative 2 . Treatment of 2 with α‐chloro esters, e.g., methyl chloroacetate, ethyl chloroacetate, isopropyl chloroacetate, and tert‐butyl chloroacetate, in potassium carbonate/sodium iodide system caused ring opening and subsequent C‐ or N‐attack nucleophilic substitution to give the corresponding dihydropyridazinones 4a , 4b and N‐substituted dihydropyrazoles 5b , 5c , 5d . On the other hand, in the absence of sodium iodide, O‐substituted pyrazoles 6a , 6b , 6c , 6d were obtained from 2 via an O‐attack nucleophilic substitution. J. Heterocyclic Chem., 2011. 相似文献
75.
Hideo Kojima Kazuyoshi Ozaki Noboru Matsumura Hiroo Inoue 《Journal of heterocyclic chemistry》1990,27(6):1845-1846
7-Substituted 2,3-bis(isopropylthio)naphth[1,8-bc]azepines 3a-c were synthesized in good yields by the reactions of 5-substituted 1-naphthylamines 2a-c with tris(isopropylthio)cyclopropenylium perchlorate ( 1 ) in acetonitrile under reflux. This reaction proceeds through the facile ring opening of 1 , followed by the intermediary formation of iminium salts 5a-c and then intramolecular cyclization. 相似文献
76.
Hiroshi Kageyama Takashi Watanabe Yoshihiro Tsujimoto Atsushi Kitada Yuji Sumida Kazuyoshi Kanamori Kazuyoshi Yoshimura Naoaki Hayashi Shigetoshi Muranaka Mikio Takano Monica Ceretti Werner Paulus Clemens Ritter Gilles Andr 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2008,120(31):5824-5829
77.
A. Yoshioka K. Nomura M. Takeya K. Shimura K. Masumoto M. Yagi 《Journal of Radioanalytical and Nuclear Chemistry》1988,122(1):175-182
Determination of carbon in copper has been studied by photon activation analysis using 30 MeV bremsstrahlung. Chemical separation of carbon as CO2 was performed by the combustion method in a high flow rate of oxygen stream. It has been demonstrated that the trace amount of carbon in copper can be determined accurately and precisely, and that the detection limit is 0.02 g. 相似文献
78.
Yasuaki Masumoto Haruo Kunitomo Shigeo Shionoya Hiro Munekata Hiroshi Kukimoto 《Solid State Communications》1984,51(4):209-212
Photoluminescence of aSixC1?x:H (x~0.2) is studied with a particular interest on the localization of carriers. Taking the polarization memory of luminescence as a probe, we clarify the localized character of photo-generated carriers as functions of excitation photon energy, emitted photon energy, temperature and time. The picosecond time-resolved measurement of the polarization memory is shown useful to study dynamical relaxation processes of carriers in disordered systems. 相似文献
79.
Kensuke Takahashi Kaoru Yamada Kazuyoshi Wakata Ryuzo Asami 《Magnetic resonance in chemistry : MRC》1974,6(1):62-63
The natural abundance C-13 NMR spectra of 1,1-diphenylethylene and α-methylstyrene dimer dianions have been obtained using the proton noise decoupling technique. The extra negative charge distributions in the carbanions have been discussed and compared with those obtained from the proton chemical shifts. The chemical shifts of the two ortho carbons in a phenyl ring are equivalent to each other for the former carbanion but not for the latter. 相似文献
80.
Pico-second time-resolved measurements of the two-photon resonant Raman scattering via excitonic molecules in CuCl were carried out for the first time. The Raman scattering leaving transverse excitons decays as fast as the laser light. When the energy of the incident light falls in the vicinity of the two-photon resonant absorption, both Raman and luminescence lines are simultaneously observed. In case of just resonant excitation, the transient response indicates that the secondary radiation can be decomposed into the Raman and the luminescence components as regards its temporal and spectral behavior. 相似文献