Trimethyl(trihalomethyl)silanes as dihalomethylene transfer agents

Trimethyl(trichloromethyl)silane and trimethyl(tribromomethyl)silane react with anhydrous potassium fluoride in diglyme to give good yields of CX₂ transfer products (dihalocyclopropanes) with olefins. Catalysis by 18-crown-6 ether is observed.     

Single-photon generation from stored excitation in an atomic ensemble

Single photons are generated from an ensemble of cold Cs atoms via the protocol of Duan et al. [Nature (London), ()]]. Conditioned upon an initial detection from field 1 at 852 nm, a photon in field 2 at 894 nm is produced in a controlled fashion from excitation stored within the atomic ensemble. The single-quantum character of field 2 is demonstrated by the violation of a Cauchy-Schwarz inequality, namely w(1(2),1(2)|1(1))=0.24+/-0.05 not > or = 1, where w(1(2),1(2)|1(1)) describes the detection of two events (1(2),1(2)) conditioned upon an initial detection 1(1), with w-->0 for single photons.     

Synthesis and characterization of tetramethylene-syn-sesterbicyclo[2.2.2]octene

The synthesis of syn-sesterbicyclo[2.2.2]octene (7) bilaterally grafted by an exocyclic s-cis-butadiene moiety is achieved from 1,8,9,10-tetrachloro-11,11-dimethoxy-endo-tricyclo[6.2.1.0^2,7]undeca-3,5,9-triene (8) employing repetitive Diels-Alder cycloadditions between 1,3-cyclohexadiene, generated from p-benzoquinone, and diethyl fumarate or maleic anhydride as the exocyclic butadienyl equivalent, followed by subsequent transformation to the conjugated diene moieties. In comparison with the corresponding sesquibicyclo[2.2.2]octene 6, the ¹H NMR demonstrates the anisotropic shielding effect operating within the three parallel laticyclic double bonds. However, the UV absorption of 7 shows less effect by the increase of laticyclic conjugated ethylene units.     

Syntheses and remarkable photophysical properties of 5-(2-pyridyl) pyrazolate boron complexes; photoinduced electron transfer

A new series of pyridyl pyrazolate boron complexes 2a-e have been synthesized, in which 2a-c exhibit remarkable dual fluorescence properties due to the photoinduced electron transfer reaction.     

Polarized optical coherence imaging in turbid media by use of a Zeeman laser

A method that uses a Zeeman laser in conjunction with a Glan-Thompson analyzer to image an object in a turbid medium is proposed. A heterodyne signal is generated only when the scattering photons are partially polarized, and the spatial coherence is not seriously degraded after the signal propagates in the turbid medium. A system combining polarization discrimination with optical coherence detection to image the object in a scattering medium is successfully demonstrated. The medium is a solution of polystyrene microspheres measuring 1.072 mum in diameter suspended in distilled water contained in a 10-mm-thick quartz cuvette. The advantages of this optical system, including better selectivity of the weak partially polarized scattering photons and better imaging ability in higher-scattering media, are discussed.     

Reconfigurable time-domain spectral shaping of an optical pulse stretched by a fiber Bragg grating

We demonstrate a method for spectrally shaping optical pulses that is readily reconfigurable and can produce variable filter functions. This practical technique relies on a compact and robust 3.86-m-long linearly chirped fiber Bragg grating that chromatically disperses the pulse to ~30 ns. We then shape the pulse envelope, and thus the pulse spectrum, with a programmable arbitrary waveform generator and an amplitude modulator to obtain several filter functions.     

Error estimates in in covolume methods for elliptic and parabolic problems: A unified approach

In this paper we consider covolume or finite volume element methods for variable coefficient elliptic and parabolic problems on convex smooth domains in the plane. We introduce a general approach for connecting these methods with finite element method analysis. This unified approach is used to prove known convergence results in the norms and new results in the max-norm. For the elliptic problems we demonstrate that the error between the exact solution and the approximate solution in the maximum norm is in the linear element case. Furthermore, the maximum norm error in the gradient is shown to be of first order. Similar results hold for the parabolic problems.

     

Structural and electronic properties of HfO2 films on Si through H2O2 wet oxidation with improved thermal stability

The thermal stability and material properties of HfO₂ thin films on Si substrates with and without H₂O₂ wet chemical oxidation were investigated. The HfO₂ samples were deposited through plasma-enhanced atomic layer deposition and subjected to thermal annealing. They were then examined using X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, reflection electron energy loss spectroscopy, and conductive atomic force microscopy. For the Si substrate without H₂O₂ wet chemical oxidation, a native oxide (~1.8 nm) was formed on the substrate before HfO₂ deposition. After the annealing process at 600°C, the band gap (E_g) of the HfO₂ films increased from 6.0 to 6.2 eV due to the diffusion of Si into HfO₂. Furthermore, the conduction and valence band offsets (ΔE_c and ΔE_v, respectively) between HfO₂ and Si changed from 1.02 to 1.42 and 3.86 to 3.66 eV, respectively. After the H₂O₂ wet oxidation of the Si substrate, a 1.5-nm chemical oxide was formed instead of a native oxide. The band offset and E_g values of HfO₂ were similar before and after 600°C annealing (ΔE_v = 3.86 eV, ΔE_c = 1.02 eV, and E_g = 6.0 eV), implying the high thermal stability of the HfO₂ films. Accordingly, wet oxidation not only prevents diffusion from chemical oxide but also markedly improves the oxide leakage current, which is useful for developing highly efficient and thermally stable HfO₂ gate oxides in Si-based integrated circuit devices.     

控制致裂岩体应力量测的模型试验研究

本文阐明了控制致裂岩体应力量测的基本原理、试验方法。介绍了几种控制致裂的模型试验结果及其分析，证明了控制致裂理论的正确性。