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Membrane interfaces are critical to many cellular functions, yet the vast array of molecular components involved make the fundamental physics of interaction difficult to define. Water has been shown to play an important role in the dynamics of small biological systems, for example when trapped in hydrophobic regions, but the molecular details of water have generally been thought dispensable when considering large membrane interfaces. Nevertheless, spectroscopic data indicate that water has distinct, ordered behavior near membrane surfaces. While coarse-grained simulations have achieved success recently in aiding understanding the dynamics of membrane assemblies, it is natural to ask, does the missing chemical nature of water play an important role? We have therefore performed atomic-resolution simulations of vesicle fusion to understand the role of chemical detail, particularly the molecular structure of water, in membrane fusion and at membrane interfaces more generally. These membrane interfaces present a form of hydrophilic confinement, yielding surprising, non-bulk-like water behavior. 相似文献
134.
B. P. Singh Prabha Parveen Saini Tejendra Gupta Parveen Garg Gaurav Kumar Indresh Pande Shailaja Pande R. K. Seth S. K. Dhawan R. B. Mathur 《Journal of nanoparticle research》2011,13(12):7065-7074
High aspect ratio multi-walled carbon nanotubes (MWCNTs) reinforced low density polyethylene (LDPE) composites were prepared by solvent casting followed by compression molding technique. Electromagnetic interference (EMI) shielding effectiveness (SE) of these composites was investigated in the frequency range of 12.4?C18 GHz (Ku-band) for the first time. The experimental results indicate that the EMI-SE of these composites is sensitive to the MWCNT loading. The average value of EMI-SE reaches 22.4 dB for 10 wt% MWCNT-LDPE composites, indicating the usefulness of this material for EMI shielding in the Ku-band. The main reason for improved SE has been attributed to significant improvement in the electrical conductivity of the composites by 20 orders of magnitude, i.e., from 10?20 for pure LDPE to 0.63 S/cm for MWCNT-LDPE, which is three order of magnitude higher than the previous reports for MWCNT-LDPE composites. Differential scanning calorimetry of the MWCNT-LDPE composites showed around 37% improvement in the crystalline contents over pure LDPE samples which resulted into enhanced thermal stability of the composites. The thermal decomposition temperature of LDPE is shifted by 40 °C on addition of 5 wt% MWCNT. The studies therefore show that these composite can be used as light weight, thermally stable EMI shielding, and antistatic material. 相似文献
135.
We report fabrication and modeling of a fiber half-coupler based gain-flattening device for EDFA. Using such a device, flattening of the ASE spectrum of an EDFA is also demonstrated. 相似文献
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A relationship between the superconducting transition temperature Tc and the lattice constant “a”, for irradiated A15 compounds is derived on the basis of the nature of the defects observed previously in these materials using Electron Microscopy. The universality of this relationship for any kind of damage as proposed by Noolandi and Testardi is discussed. 相似文献
140.
An equation is obtained for the pairing amplitude in a many-electron-proton system at finite temperature. It is noted that
under certain approximations it can be solved to give temperature-dependent discrete energy spectra. 相似文献