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811.
812.
813.
Arabinda Mallick Paramita Das Nitin Chattopadhyay 《Journal of Photochemistry and Photobiology, C: Photochemistry Reviews》2010,11(2-3):62-72
The photobehavior of norharmane (9H-pyrido[3,4-b]-indole) (NHM), one of the vastly used skeleton of drugs in therapeutic applications, has recently been the subject of increasing interest due to the finding of their phototoxic and photocarcinogenic properties. Its absorption and fluorescence behavior from different prototropic species show remarkable sensitivity towards the polarity, viscosity and local pH, exhibited by various microheterogeneous bio and biomimetic environments like micelles, reverse micelles, proteins, etc. The significant results obtained for NHM in homogeneous and a series of microheterogeneous environments is reviewed in this account. Much attention has been given to the properties of the excited states, location and biodistribution of NHM in different biological environments. The results can help in understanding the photophysics of the probe in biological environments and in assessing the correlation between different prototropic forms and biological activity. 相似文献
814.
S Bala G C Uniyal S K Chattopadhyay V Tripathi K V Sashidhara M Kulshrestha R P Sharma S P Jain A K Kukreja S Kumar 《Journal of chromatography. A》1999,858(2):239-244
A reversed-phase column liquid chromatography method for the analysis of taxol, 10-deacetylbaccatin III, baccatin IV, 1-hydroxybaccatin I, 2-acetoxybrevifoliol, brevifoliol, 2'-deacetoxydecinnamoyltaxinine J and 2'-deacetoxytaxinine J in yew needles has been developed using a Nova-Pak Phenyl column and a binary gradient profile. The various aspects of analysis such as extraction efficiency, detection limits, reproducibility and peak purity were validated using UV-Vis as well as photodiode array detection. 相似文献
815.
816.
Savita Kumari Aswini K. Mishra Dipak K. Chattopadhyay K. V. S. N. Raju 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2673-2688
Polyurethane (PU) coatings are widely used for variety of high‐performance applications in today's coating technology. The emerging hyperbranched polymers having three‐dimensional morphology have opened a new avenue to tailor the architecture of PU coatings. The methodology followed here is based on preparation of PU coatings from hyperbranched polyester. Initially, different hyperbranched polyester polyols (HPs) were synthesized by varying the hydroxyl‐terminated precursors that is, pentaerythritol, trimethylol propane or glycerol and keeping the diacid that is, adipic acid quantity constant at various mole ratios of 1:0.6, 1:0.8, 1:0.9, and 1:1, respectively. The obtained HPs were characterized by nuclear magnetic resonance (NMR) spectroscopy, matrix‐assisted laser desorption/ionization time‐of‐flight (MALDI‐TOF)‐mass spectrometry, and Fourier transform‐infrared (FTIR) spectroscopy. The degree of branching and the quantity of different structural units present in the various HPs were calculated by integrating the quaternary carbon and carbonyl zone in 13C NMR spectroscopy. The extent of condensation in different HPs was also calculated from 1H NMR spectra. Later on, NCO‐terminated PU prepolymers (NCO‐PU) were synthesized by reacting HPs with isophorone diisocyanate (IPDI) at NCO/OH ratio of 1.6:1. In the third step, the excess NCO content in the NCO‐capped PU prepolymers were reacted with atmospheric moisture and hyperbranched polyurethane (HPU) coatings were formed. The coating films were analyzed by FTIR and dynamic mechanical thermal analysis instruments. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2673–2688, 2007 相似文献
817.
A neural network has been used to predict the flow intermittency from velocity signals in the transition zone in a boundary
layer. Unlike many of the available intermittency detection methods requiring a proper threshold choice in order to distinguish
between the turbulent and non-turbulent parts of a signal, a trained neural network does not involve any threshold decision.
The intermittency prediction based on the neural network has been found to be very satisfactory.
Received: 15 December 1997/Accepted: 30 December 1998 相似文献
818.
Comparative studies of the Raman and infrared spectra of 1,3-diacetylbenzene and 2,6-diacetylpyridine have been made. The spectra are interpreted with the aid of normal mode analysis following full structure optimization based on the density functional method using different levels of theories and various basis sets combination. The unscaled DFT LSDA frequencies approximate the experimental ones in much more uniform fashion than B3LYP or B3PW91 theories do. Nevertheless the use of overall scale factor leads to further significant improvement with less than 2% error. The scaled B3PW91 6-31G result is best, even though LSDA 6-311G frequencies are superior to the B3PW91 ones before scaling. While making complete assignments of vibrational wavenumbers on the basis of potential energy distribution, some interesting observation in the vibrational spectra of these two molecules have been noticed. Instances of Fermi resonances between fundamentals and some combination modes of vibration have also been ascertained. Following the quantum chemical calculation optimized geometries of the both molecules are predicted. The theoretical global minimum energy calculation helps to find the structural symmetries of the molecules. 相似文献
819.
Amares Chattopadhyay Volker Michel 《Archive of Applied Mechanics (Ingenieur Archiv)》2006,75(2-3):113-124
We study a spherical wave propagating in the radial and latitude directions and oscillating in the longitude direction in
the case of fibre-reinforced linearly elastic material. A function system solving Euler's equation of motion in this case
and depending on certain Bessel and associated Legendre functions is derived. 相似文献
820.
A.N. Banerjee C.K. Ghosh S. Das K.K. Chattopadhyay 《Physica B: Condensed Matter》2005,370(1-4):264-276
P-type transparent-conducting CuAlO2+x thin films were deposited on silicon and glass substrates by reactive direct current sputtering of a prefabricated metal powder target having 1:1 atomic ratio of Cu and Al in oxygen-diluted argon atmosphere. XRD spectrum confirmed the proper phase formation of the material. UV-Vis-NIR spectrophotometric measurements showed high transparency of the films in the visible region with direct and indirect band gap values around 3.90 and 1.89 eV, respectively. The room temperature conductivity of the film was of the order of 0.22 S cm−1 and the activation energy was 0.25 eV. Seebeck coefficient at room temperature showed a value of +115 μV/K confirming the p-type nature of the film. Room temperature Hall effect measurement also indicated positive value of Hall coefficient with a carrier concentration 4.4×1017 cm−3. We have also observed the low macroscopic field emission, from the wide band gap p-CuAlO2+x thin film deposited on glass substrate. The emission properties have been studied for different anode-sample spacing. The threshold field was found to be as low as around 0.5–1.1 V/μm. This low threshold is attributed primarily to the internal nanostructure of the thin film, which causes considerable geometrical field enhancement inside the film as well as at the film/vacuum interface. 相似文献