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901.
Characterization and electrochemical investigation of boron-doped mesocarbon microbead anode materials for lithium ion batteries 总被引:1,自引:0,他引:1
Mao-Hui Chen Guo-Tao Wu Guang-Ming Zhu Jin-Kua You Zu-Geng Lin 《Journal of Solid State Electrochemistry》2002,6(6):420-427
The structure and anodic performance of boron-doped and undoped mesocarbon microbeads (MCMBs) have been comparatively studied
and the results obtained by XPS, XRD, SEM, Raman spectroscopy and electrochemical measurements are discussed. It is found
that boron doping introduces a depressed d
002 spacing and the larger amount of "unorganized carbon", which induces vacancy formation in the graphite planes and leads to
a quite different morphology from that of the undoped material. Electrochemical charge/discharge cycle tests indicated that
after boron doping the lithium intercalation was carried through at a somewhat higher potential, being attended by greater
irreversible capacity loss.
Electronic Publication 相似文献
902.
测定啤酒和白葡萄酒中有机酸的离子排斥色谱法 总被引:6,自引:0,他引:6
研究了离子排斥色谱法分离测定啤酒和白葡萄酒中有机酸;选用常见的盐酸溶液作淋洗液,以四丁基氢氧化铵为再生液,考察了淋洗液浓度、流量等因素对分离和测定的影响,对啤酒和白葡萄酒中常见有机酸在阴离子排斥色谱柱上的保留行为进行了系统的研究;通过试验确定最佳的色谱条件为盐酸浓度1.10mmol/L,流量0.80mL/min;四丁基氢氧化铵浓度5.0mmol/L,流量1.10mL/min;并在该条件下,测定了啤酒和白葡萄酒中的有机酸。 相似文献
903.
壳多糖与丙烯酸丁酯的乳液接枝共聚研究 总被引:10,自引:0,他引:10
以十二烷基苯磺酸钠为乳化剂,过硫酸钾-亚硫酸氢钠为引发剂,研究了壳多糖与丙烯酸丁醋的乳液共聚合,结果表明当[K2S2O8]=[NaHSO3]=2.57×10-3mol·1-1,[BA]=0.68mol.1-1,[Chitosan]=19.2g·l-1,在70℃下反应5小时,共聚反应的接技率和接枝效率均较高.用红外光谱,差热分析,X射线衍射,扫描电镜对接技共聚物进行了表征,此外测试了共聚物胶乳成膜的机械性能,表明用丙烯酸丁酯对壳多糖进行接枝改性,可提高壳多糖的韧性,扩大其应用范围. 相似文献
904.
Spectroscopic infrared ellipsometry was applied to determine the optical constants of thin metal layers deposited on dielectric substrates such as glass or CaF(2). The layers were produced by evaporating gold or silver in a vacuum, and the coverage, that is the deposited mass per area, was chosen in the range 80-1200 mg m(-2) for gold, which refers to thicknesses in the lower nanometer range; in the case of the specifically lighter silver, about half the coverage was applied. At low coverage a metal island structure is obtained, which gives rise to surface-enhanced infrared absorption (SEIRA). Depending on the coverage, the deposited films exhibit either dielectric or metallic optical properties. Atomic force microscopy and conductivity measurements complement the spectroscopic observation. 相似文献
905.
906.
Horseradish peroxidase catalyzed grafting of acrylamide (AM) onto Kevlar fibers has been studied. The modified fiber has been characterized with scanning electron microscopy (SEM), elemental analysis and the grafting yield. From the SEM micrographs, the surface of the grafted Kevlar fiber is rougher than that of the untreated fiber, and the elemental analysis indicated that the nitrogen content of the treated fibers is higher than that of the untreated fiber. All the results suggested that AM must have been grafted onto the Kevlar surface through HRP-mediated radical initiated grafting reaction. The probably mechanism of HRP catalyzed grafting of AM onto Kevlar surface is proposed. 相似文献
907.
人体微量元素平衡与健康饮食 总被引:4,自引:0,他引:4
综述了人体微量元素平衡与健康饮食的关系。微量元素参与机体内的各种代谢,在维持人的生命活动中发挥着重要的作用。正确理解微量元素的生理功能,树立科学的平衡营养观,是引导人们自觉地实现多样化饮食、促进健康长寿的关键。 相似文献
908.
Santi Tungprapa Tanarinthorn Puangparn Monchawan Weerasombut Ittipol Jangchud Porntiva Fakum Somsak Semongkhol Chidchanok Meechaisue Pitt Supaphol 《Cellulose (London, England)》2007,14(6):563-575
This paper reports an investigation of the effects of solvent system, solution concentration, and applied electrostatic field
strength (EFS) on the morphological appearance and/or size of as-spun cellulose acetate (CA) products. The single-solvent
systems were acetone, chloroform, N,N
-dimethylformamide (DMF), dichloromethane (DCM), methanol (MeOH), formic acid, and pyridine. The mixed-solvent systems were
acetone–DMAc, chloroform–MeOH, and DCM–MeOH. Chloroform, DMF, DCM, MeOH, formic acid, and pyridine were able to dissolve CA,
forming clear solutions (at 5% w/v), but electrospinning of these solutions produced mainly discrete beads. In contrast, electrospinning of the solution of
CA in acetone produced short and beaded fibers. At the same solution concentration of 5% (w/v) electrospinning of the CA solutions was improved by addition of MeOH to either chloroform or DCM. For all the solvent systems
investigated smooth fibers were obtained from 16% (w/v) CA solutions in 1:1, 2:1, and 3:1 (v/v) acetone–DMAc, 14–20% (w/v) CA solutions in 2:1 (v/v) acetone–DMAc, and 8–12% (w/v) CA solutions in 4:1 (v/v) DCM–MeOH. For the as-spun fibers from CA solutions in acetone–DMAc the average diameter ranged between 0.14 and 0.37 μm
whereas for the fibers from solutions in DCM–MeOH it ranged between 0.48 and 1.58 μm. After submersion in distilled water
for 24 h the as-spun CA fibers swelled appreciably (i.e. from 620 to 1110%) but the physical integrity of the fibrous structure
remained intact. 相似文献
909.
T. Datta Samanta S. Laskar D. Nayak S. Lahiri 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(2):323-325
Binding ability of mercury, thallium, lead and bismuth with Erythrina variegata seed protein have been investigated using tracer packet technique. Due to the lack of standard methods, inter-comparisons
have been made among three different approaches, like trichloroacetic acid (TCA) precipitation, isoelectric precipitation
and dialysis of protein after incubation with the metals. Good agreement was observed for all the cases except that of lead. 相似文献
910.
应用n级等摩尔浓度反应的热动力学理论,在30℃和40℃下研究了丙烯酰胺在水溶液中和CTAB胶束溶液中由亚硫酸钠引发的聚合反应动力学.讨论了引发剂和CTAB的浓度对聚丙烯酰胺分子量的影响。 相似文献