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41.
The total synthesis of 1-(Z)-atractylodinol, a natural polyacetylenic alcohol with several biological activities, has been achieved using a newly developed telluride synthon and a novel use for the Negishi type coupling reaction employing vinyl tellurides. 相似文献
42.
Huenerbein A Sipoli Marques MA Pereira Ados S de Aquino Neto FR 《Journal of chromatography. A》2003,985(1-2):375-386
The Medical Commission of the International Olympic Committee forbids the use of anabolic androgenic steroids and beta2-agonists to improve athletic performance. In this work we have selected examples of anabolic androgenic compounds and their metabolites to evaluate the GC-MS analysis of some trimethylsilyl derivatives. The aim is to set the best GC conditions to improve the detection within the whole range of analyte elution temperatures. The initial column temperature was changed to 105 or 140 degrees C followed by 40 degrees C min(-1) to 200 degrees C and then 15 degrees C min(-1) to 300 degrees C. Using 140 degrees C as the initial oven temperature it was possible to obtain narrower initial analyte distributions for the compounds that elutes at the beginning of the chromatogram as clenbuterol, mabuterol, epimethylenediol and norandrosterone, without loss of derivatized metabolites signal. Later. eluting analytes, such as the stanozolol metabolites, furazabol and oxandrolone were not affected. Temperatures below 140 degrees C. resulted in partial derivatization for some analytes mainly stanozolol related structures. Therefore evaluation of derivatization conditions as occurring in three steps, the vial, vaporization chamber and capillary column, was thoroughly assessed. The new program temperature improves the signal-to-noise ratio for some compounds and shows adequate resolution for endogenous compounds. Some of the difficult key separations necessary for doping control enforcement were also obtained with the proposed method. 相似文献
43.
Penna Thereza Christina Vessoni Marques Marcelo Machoshvili Irena A. Ishii Marina 《Applied biochemistry and biotechnology》2002,98(1-9):539-551
Large-volume parenteral solutions were submitted to heat treatments after being inoculated with Bacillus stearothermophilus ATCC 7953 (T
r
=121°C) and Bacillus subtilis ATCC 9372 (T
r
=104.5°C) spores. The average decimal reduction time for B. stearothermophilus ranged from a D
121°C value of 1.31 to 3.14 min, in glucophysiologic and Ringer’s solutions respectively. For B. subtilis, D
104.5°C value increased from 0.69 to 1.37 min, in Ringer’s (pH=5.91) and 50% glucose (pH 3.05) solutions respectively. The z value ranged from 7.95°C (20% mannitol solution) to 13.14°C (50% glucose solution), corresponding to an activation energy
(Ea) of 81.48 and 49.30 kcal/mol, respectively. 相似文献
44.
The effects of anionic, non-ionic, and cationic surfactants and thallium(I) nitrate on the paper-substrate room-temperature phosphorescence (RTP) of eleven phenothiazine derivatives are described. Enhancement factors within the range 1.5–10 are observed after addition of sodium dodecylsulfate, dodecyltrimethylammonium chloride and thallium(I) nitrate. The influence of surfactant on phosphor characteristics as well as effects of moisture are discussed. Limits of detection were in the range 0.2–2 ng. Results are also reported for p-aminobenzoic acid, carbazole and o-terphenyl. 相似文献
45.
M. D. P. Monteiro Marques A. Ornelas 《Journal of Optimization Theory and Applications》1995,86(2):421-431
This paper is concerned with the existence of a minimum in a Sobolev space for the functional $$F_g (x): = \int_0^T {g(x(t)){\text{ }}dt + \int_0^T {h(x'(t)){\text{ }}dt,{\text{ }}x(0) = a,{\text{ }}x(T) = b,} }$$ wherea,b are real numbers,g is a continuous map, andh is lower semicontinuous, satisfying adequate growth conditions. As shown by Cellina and Mariconda, there exists a dense subset of the space of continuous functions bounded below such that, forg in this subset, the above functional attains its minimum no matter whichh is used. This subset contains in particular the monotone maps, as shown by Marcellini, and the concave maps, as shown by Cellina and Colombo. Our aim is twofold: first to show that this subset, although dense, is meager in the sense of the Baire category; and second to show that it contains a class of functions which we call concave-monotone, because it generalizes both the classes of concave and of monotone functions. 相似文献
46.
This paper is concerned with BV periodic solutions for multivalued perturbations of an evolution equation governed by the sweeping process (or Moreau's process). The perturbed equation has the form –DuN
C
(t)(u(t))+F(t,u(t)), whereC is a closed convex valued continuousT-periodic multifunction from [0,T] to
d
,N
C
(t)(u(t)) is the normal cone ofC(t) atu(t),F: [0,T]×
d
d
is a compact convex valued multifunction and Du is the differential measure of the periodic BV solutionu. Several existence results for this differential inclusion are stated under various assumptions on the perturbationF. 相似文献
47.
Armstrong TA Bettoni D Bharadwaj V Biino C Borreani G Broemmelsiek D Buzzo A Calabrese R Ceccucci A Cester R Church M Dalpiaz P Dalpiaz PF Dimitroyannis D Fabbri M Fast J Gianoli A Ginsburg CM Gollwitzer K Govi G Hahn A Hasan M Hsueh S Lewis R Luppi E Macrí M Majewska AM Mandelkern M Marchetto F Marinelli M Marques J Marsh W Martini M Masuzawa M Menichetti E Migliori A Mussa R Palestini S Pallavicini M Passaggio S Pastrone N Patrignani C Peoples J Petrucci F Pia MG Pordes S Rapidis P Ray R 《Physical review D: Particles and fields》1996,54(11):7067-7070
48.
Radul has recently introduced a map from the Lie algebra of differential operators on the circle of W
n
. In this Letter, we extend this map to W
KP
(q)
, a recently introduced one-parameter deformation of WKP - the second Hamiltonian structure of the KP hierarchy. We use this to give a short proof that W is the algebra of additional symmetries of the KP equation. 相似文献
49.
José M. Figueroa-O'Farrill Javier Mas Eduardo Ramos 《Communications in Mathematical Physics》1993,158(1):17-43
The KP hierarchy is hamiltonian relative to a one-parameter family of Poisson structures obtained from a generalized Adler map in the space of formal pseudodifferential symbols with noninteger powers. The resulting W-algebra is a one-parameter deformation of WKP admitting a central extension for generic values of the parameter, reducing naturally to W
n
for special values of the parameter, and contracting to the centrally extended W1+, W and further truncations. In the classical limit, all algebras in the one-parameter family are equivalent and isomorphic tow
KP. The reduction induced by setting the spin-one field to zero yields a one-parameter deformation of
which contracts to a new nonlinear algebra of the W-type.Address after October 1993: Queen Mary and Westfield College, UK 相似文献
50.
We study theoretically mixed solutions of homopolymer and diblock copolymer chains. The solvent is a poor solvent for the homopolymers and a selective solvent for the copolymers. We find that the formation of copolymer micelles containing also the insoluble chains allows for an increased solubility of the homopolymers in the solution. In agreement with experiments, we find also that the solubilization power of the micelles, that is, the maximum amount of total homopolymer weight solubilized per unit weight of copolymers in solution, decreases strongly with the homopolymer index of polymerization. 相似文献