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91.
92.
Novel probes represented connection of pyrene as chromophore and sterically hindered amine stabilizers (HAS) in the form of esters of 2-(1-pyrenyl)acrylic acid were synthesized. HAS was in the form of parent amine (PAP) as well as stable nitroxyl radical form (PAP-NO.). Photophysics of these probes were compared with their precursor as 2-(1-pyrenyl)acrylic acid (PAA) and its methyl ester (PAM). The fluorescence spectrum of PAA strongly depends on the acidity of the solution. The spectrum in neutral methanol indicates that it originates from the anionic form –COO−. Changes of acidity or basicity of methanol solution resulted in the changes of shape, position as well as the intensity of fluorescence band. This is due to the presence of protolytic equilibria, either in the ground state or in the singlet excited state, leading to the formation of molecular form –COOH and the cationic form –COOH2+. The ester analogues did not show any changes in various pH conditions. Fluorescence of all probes depends on the polarity of solvents and the presence of oxygen. Intermolecular quenching was studied with external quenchers TEMPO and oxygen and the data were compared with the intramolecular quenching using 1′-oxo-2′,2′,6′,6′-tetramethyl-4′-piperidinyl-2-(1-pyrenyl)acrylate (PAP-NO.). 相似文献
93.
Taking into account the tetrahedral shape of a quantum-dot quantum well (QDQW) when describing excitonic states, phonon modes, and the exciton-phonon interaction in the structure, we obtain within a nonadiabatic approach a quantitative interpretation of the photoluminescence spectrum of a single CdS/HgS/CdS QDQW. We find that the exciton ground state in a tetrahedral QDQW is bright, in contrast to the dark ground state for a spherical QDQW. The position of the phonon peaks in the photoluminescence spectrum is attributed to interface optical phonons. We also show that the experimental value of the Huang-Rhys parameter can be obtained only within the nonadiabatic theory of phonon-assisted transitions. 相似文献
94.
We say that a family of graphs is p-quasi-random, 0<p<1, if it shares typical properties of the random graph G(n,p); for a definition, see below. We denote by the class of all graphs H for which and the number of not necessarily induced labeled copies of H in Gn is at most (1+o(1))pe(H)nv(H) imply that is p-quasi-random. In this note, we show that all complete bipartite graphs Ka,b, a,b2, belong to for all 0<p<1.Acknowledgments We would like to thank Andrew Thomason for fruitful discussions and Yoshi Kohayakawa for organizing Extended Workshop on Combinatorics in eq5 Paulo, Ubatuba, and Rio de Janeiro, where a part of this work was done. We also thank the referees for their careful work.The first author was partially supported by NSF grant INT-0072064The second author was partially supported by NSF grants DMS-9970622, DMS-0301228 and INT-0072064Final version received: October 24, 2003 相似文献
95.
In the semiclassical limit of open ballistic quantum systems, we demonstrate the emergence of instantaneous decay modes guided by classical escape faster than the Ehrenfest time. The decay time of the associated quasibound states is smaller than the classical time of flight. The remaining long-lived quasibound states obey random-matrix statistics, renormalized in compliance with the recently proposed fractal Weyl law for open systems [W.T. Lu, S. Sridhar, and M. Zworski, Phys. Rev. Lett. 91, 154101 (2003)]. We validate our theory numerically for a model system, the open kicked rotator. 相似文献
96.
97.
Ján Jakubík 《Czechoslovak Mathematical Journal》2003,53(1):103-111
In this paper we apply the notion of cell of a lattice for dealing with graph automorphisms of lattices (in connection with a problem proposed by G. Birkhoff). 相似文献
98.
99.
100.
Alena Juríková Kornel Csach Jozef Miškuf Václav Ocelík 《Central European Journal of Physics》2007,5(2):177-187
Creep strain recovery and structural relaxation of the amorphous metallic glass Fe40Ni41B19 after longtime loading at different annealing temperatures below the glass transition temperature have been studied using
anisothermal differential scanning calorimetry (DSC) and dilatometry (TMA). It has been demonstrated that structural relaxation
effects depend on the stress-annealing temperature of the amorphous ribbon. The structural relaxation states of the amorphous
ribbon annealed at different temperatures under and without applied stress have been compared. The activation energy spectra
were calculated from the anisothermal dilatometric measurements using the modern method based on the Fourier transformation
technique. The influence of the annealing temperature on the shape of creep strain recovery spectra has been analyzed.
相似文献