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61.
Frontispiece: Aligning Electronic and Protonic Energy Levels of Proton‐Coupled Electron Transfer in Water Oxidation on Aqueous TiO2 下载免费PDF全文
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Dr. Eduard O. Bobylev Julian Ruijter Dr. David A. Poole III Dr. Simon Mathew Prof. Dr. Bas de Bruin Prof. Dr. Joost N. H. Reek 《Angewandte Chemie (International ed. in English)》2023,62(16):e202218162
Metabolic pathways are highly regulated by effector molecules that influences the rate of enzymatic reactions. Inspired by the catalytic regulation found in living cells, we report a Pt2L4 cage of which the activity can be controlled by effectors that bind inside the cage. The cage shows catalytic activity in the lactonization of alkynoic acids, with the reaction rates dependent on the effector guest bound in the cage. Some effector guests enhance the rate of the lactonization by up to 19-fold, whereas one decreases it by 5-fold. When mixtures of specific substrates are used, both starting materials and products act as guests for the Pt2L4 cage, enhancing its catalytic activity for one substrate while reducing its activity for the other. The reported regulatory behavior obtained by the addition of effector molecules paves the way to the development of more complex, metabolic-like catalyst systems. 相似文献
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Frigato T VandeVondele J Schmidt B Schütte C Jungwirth P 《The journal of physical chemistry. A》2008,112(27):6125-6133
We present a computational study of the structure and dynamics of an excess electron in a medium-sized water cluster aimed at addressing the question of interior vs exterior solvation. Ab initio Born-Oppenheimer molecular dynamics simulations were performed within the DFT framework, employing a hybrid Gaussian and plane-wave formalism together with the PBE exchange-correlation functional and norm-conserving pseudopotentials. Analysis of a 15-ps trajectory allowed us to reach the following conclusions: (i) the excess electron is predominantly located at the cluster surface (even if it is initially placed in the interior), (ii) the computed electron binding energies correlate with the electron localization rather than with its bulk vs surface location, and (iii) a dynamical interconversion between two different H-bond patterns around the electron occurs. The computed electron binding energies and the most relevant features of the IR spectrum are in a very good agreement with results of previous experimental studies. 相似文献
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Dr. Catriona C. James Prof. Dr. Bas de Bruin Prof. Dr. Joost N. H. Reek 《Angewandte Chemie (International ed. in English)》2023,62(41):e202306645
The importance of transition metal catalysis is exemplified by its wide range of applications, for example in the synthesis of chemicals, natural products, and pharmaceuticals. However, one relatively new application is for carrying out new-to-nature reactions inside living cells. The complex environment of a living cell is not welcoming to transition metal catalysts, as a diverse range of biological components have the potential to inhibit or deactivate the catalyst. Here we review the current progress in the field of transition metal catalysis, and evaluation of catalysis efficiency in living cells and under biological (relevant) conditions. Catalyst poisoning is a ubiquitous problem in this field, and we propose that future research into the development of physical and kinetic protection strategies may provide a route to improve the reactivity of catalysts in cells. 相似文献
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Kuil M Goudriaan PE Kleij AW Tooke DM Spek AL van Leeuwen PW Reek JN 《Dalton transactions (Cambridge, England : 2003)》2007,(22):2311-2320
The template-induced formation of chelating bidentate ligands by the selective self-assembly of two monodentate pyridyl phosphorus ligands on a rigid bis-zinc(II) salphen template with two identical binding sites was studied. Using UV-vis, NMR-spectroscopy and X-ray analysis the formed structures were unambiguously proven. The application of these templated bidentate ligands in transition metal catalysis showed, in most cases, typical bidentate character. Compared to previous work based on a more flexible bis-zinc(II) porphyrin template, the current catalytic data suggest that the rigidity of the template is not an important factor for the improvement of the regio- and enantioselectivity under the applied reaction conditions. 相似文献
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Supramolecular bidentate phosphite ligands are presented as a new class of ligands for rhodium catalysed asymmetric hydrogenation. 相似文献
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Belpassi L Tarantelli F Sgamellotti A Quiney HM van Stralen JN Visscher L 《The Journal of chemical physics》2007,126(6):064314
The nuclear quadrupole moment for (197)Au has been determined on the base of the state-of-art relativistic molecular calculations. The experimental shifts in the nuclear coupling constants in the series of molecules AuF, XeAuF, KrAuF, ArAuF, (OC)AuF, and AuH have been combined with highly accurate determinations of the electric field gradient (EFG) at the gold nucleus, obtained by molecular relativistic Dirac-Coulomb-Gaunt Hartree-Fock calculations. The electronic correlation contribution to the EFG is included with the CCSD(T) and CCSD-T approaches, also in the four-component framework, using a finite-difference method. In order to estimate the accuracy of their approach the authors have thoroughly investigated the convergence of the results with respect to the basis set employed and the size of the correlated orbital space. The effect of the full Breit electron-electron interaction on the nuclear quadrupole moment of gold has also been considered explicitly for the AuF molecule. They obtain for (197)Au a nuclear quadrupole moment of 510+/-15 mb, which deviates by about 7% from the currently accepted muonic value. 相似文献
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