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排序方式: 共有268条查询结果,搜索用时 125 毫秒
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Nicolas Soldermann Joerg Velker Olivier Vallat Helen Stoeckli‐Evans Reinhard Neier 《Helvetica chimica acta》2000,83(9):2266-2276
The novel tandem process Diels‐Alder reaction/Ireland‐Claisen rearrangement shows a high diastereoselectivity for the Ireland‐Claisen rearrangement starting from the endo‐product of the Diels‐Alder reaction. Based on this mechanistic knowledge, the novel tandem process could be applied to the synthesis of rac‐juvabione. 相似文献
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Frank Katzenberg Joerg C. Tiller 《Journal of polymer science. Part A, Polymer chemistry》2016,54(14):1381-1388
Charles Goodyear discovered the vulcanization of natural rubber (NR) 170 years ago and transferred the gooey natural compound into the first representative of an entirely new class of materials; the elastomers. Thenceforth, NR was intensively explored and was used for countless products to date. All the more surprising, it was found recently that NR exhibits superior and unexpected properties whenever it is cross-linked to a degree smaller than 0.4% which is fairly below the commonly used 1%–2%. This article gives a brief overview on the exceptional properties of lightly cross-linked NR, named shape memory natural rubber (SMNR), including the cold programmable shape memory effect, storing of extremely large strain, energy and cold, and its capability to sense and memorize environmental parameters. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1381–1388 相似文献
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Hybrids of silver nanoparticles with amphiphilic hyperbranched macromolecules exhibiting antimicrobial properties 总被引:1,自引:0,他引:1
Aymonier C Schlotterbeck U Antonietti L Zacharias P Thomann R Tiller JC Mecking S 《Chemical communications (Cambridge, England)》2002,(24):3018-3019
Hybrids of silver particles of 1 to 2 nm in size with highly branched amphiphilically modified polyethyleneimines adhere effectively to polar substrates providing environmentally friendly antimicrobial coatings. 相似文献
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TMQ is an important precursor in industrial vitamin E synthesis. We report a "green chemistry approach" with respect to the highly selective and environmentally friendly oxidation of 2,3,6-trimethylphenol (TMP) to trimethyl-1,4-benzoquinone (TMQ) with molecular oxygen as oxidant and a copper catalyst immobilized in a molten salt. n-Butanol as co-solvent has a positive effect on the activity and selectivity. The structurally characterized catalyst, a 1-n-butyl-3-methylimidazolium oxotetracuprat, is formed in situ via hydrolysis of CuCl2 in the presence of imidazolium chloride. We propose a mechanism of oxidative phenolate activation at a [Cu4(mu4-O)]6+ core as electronically coupled electron acceptor, formation of a copper-bound phenolate radical anion, spin delocalization into the aromatic ring, and attack by triplet oxygen at the para position. Attack of Cu(I) as reduction equivalent at the peroxy radical, proton-mediated elimination of a copper(II)-hydroxo species, will either substitute a copper(I) site in the reduced oxo cluster or take up an electron from the reduced mixed valent cluster [Cu4(mu4-O)]6+ to regenerate the oxidized cluster as the active electron acceptor. 相似文献
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Albers J Grunwald T Nebling E Piechotta G Hintsche R 《Analytical and bioanalytical chemistry》2003,377(3):521-527
Based on electrical biochips made in Si-technology cost effective portable devices have been constructed for field applications and point of care diagnosis. These miniaturized amperometric biosensor devices enable the evaluation of biomolecular interactions by measuring the redox recycling of ELISA products, as well as the electrical monitoring of metabolites. The highly sensitive redox recycling is facilitated by interdigitated ultramicroelectrodes of high spatial resolution. The application of these electrical biochips as DNA microarrays for the molecular diagnosis of viral infections demonstrates the measurement procedure. Self-assembling of capture oligonucleotides via thiol-gold coupling has been used to construct the DNA interface on-chip. Another application for this electrical detection principle is continuous measuring with bead-based biosensors. Here, paramagnetic nanoparticles are used as carriers of the bioanalytical interface in ELISA format. A Si-micromachined glucose sensor for continuous monitoring in interstitial fluid ex vivo shows the flexibility of the electrical platform. Here the novel approach is a pore membrane in micrometer-dimensions acting as a diffusion barrier. The electrochemical detection takes place in a cavity containing glucose oxidase and a Pt-electrode surface. The common hydrogen peroxide detection, together with Si technology, enable precise differential measurements using a second cavity. 相似文献