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901.
Xinhua Liang Zhentao Mi Yaquan Wang Li Wang Xiangwen Zhang 《Reaction Kinetics and Catalysis Letters》2004,82(2):333-337
The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of
acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone,
imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts
of catalyst and the NH3 to acetone molar ratio were investigated.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
902.
903.
由于含时波包方法具有经典的直观又不乏量子力学的准确 ,选择含时波包方法来处理F +CH2 D2 →CH2 D/CHD2 +DF/HF反应 .把半刚性振转子 (SVRT)模型应用到该反应体系中 ,研究了两个通道中该反应从基态反应物开始在修正过的J1(MJ1)势能面上计算出来了反应几率、积分截面、速率常数 .反应几率随能量变化的图的数值结果给出了振荡结构 ,这些振荡结构是可以和动力学振荡联系起来的 .而这些振荡结构在积分截面随着能量变化的图中就被反应几率求和后的平均结果所掩盖了 .速率常数和实验结果的比较也得到了较好的结果 . 相似文献
904.
A computably enumerable (c.e.) degree a is called nonbounding, if it bounds no minimal pair, and plus cupping, if every nonzero c.e. degree x below a is cuppable. Let NB and PC be the sets of all nonbounding and plus cupping c.e. degrees, respectively. Both NB and PC are well understood, but it has not been possible so far to distinguish between the two classes. In the present paper, we investigate the relationship between the classes NB and PC , and show that there exists a minimal pair which join to a plus cupping degree, so that PC ? NB . This gives a first known difference between NB and PC . (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
905.
906.
针对带约束的凸多面体线性不确定模型,提出了一种新型鲁棒预测控制方法,它采用离散化的不确定模型构造最小-最大优化控制问题,并在其中直接引入状态反馈机制,与其他最小-最大预测控制方法相比,这种方法等效于增加了控制序列的长度,为优化问题增加了更多的自由度,从而扩大了可行域,作为最小化目标的是离散化不确定系统在整个预测时域上二次型成本函数的最大值,而不是各预测阶段应成本项的上界之和,从而减少了与最小-最大优化相关的方程个数,有利于降低计算复杂性,文中进一步证明了不确定系统的闭环稳定性取决于优化问题在初始时刻的可行性,并将优化问题转化为线性矩阵不等式形式。最后,以数值仿赵例子验证了方法的有效性。 相似文献
907.
In this paper we consider the problem of estimating an unknown joint distribution which is defined over mixed discrete and continuous variables. A nonparametric kernel approach is proposed with smoothing parameters obtained from the cross-validated minimization of the estimator's integrated squared error. We derive the rate of convergence of the cross-validated smoothing parameters to their ‘benchmark’ optimal values, and we also establish the asymptotic normality of the resulting nonparametric kernel density estimator. Monte Carlo simulations illustrate that the proposed estimator performs substantially better than the conventional nonparametric frequency estimator in a range of settings. The simulations also demonstrate that the proposed approach does not suffer from known limitations of the likelihood cross-validation method which breaks down with commonly used kernels when the continuous variables are drawn from fat-tailed distributions. An empirical application demonstrates that the proposed method can yield superior predictions relative to commonly used parametric models. 相似文献
908.
Jin Sun Yihu Song Qiang Zheng Hong Tan Jie Yu Hong Li 《Journal of Polymer Science.Polymer Physics》2007,45(18):2594-2602
The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO2) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO2 causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO2 hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007 相似文献
909.
考虑带调和势的超临界非线性Schroedinger方程,解决了该方程整体解和爆破解存在所依赖的初始条件的最佳分界门槛.通过构造两类强制变分问题和建立局部不变半流,运用势井方法和凹方法,获得了该方程在两个不同的空间中的整体解和爆破解的最佳门槛条件. 相似文献
910.