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921.
A simple and sensitive method was conducted for the determination of trace amounts of proteins with benzeneazo-8-acetylamino-1-naphthol-3,6-disulfonic acid sodium salt (azophloxine, AP) using a Rayleigh light-scattering (RLS) technique. At pH 2.60 and in the presence of an emulsifier OP microemulsion, the RLS of AP can be greatly enhanced by proteins, owing to the interaction between AP and protein. The enhanced intensity is proportional to the concentration of proteins. Four proteins, including bovine serum albumin (BSA), human serum albumin (HSA), lysozyme (Lys) and gamma globulin (gamma-G) have been tested. For example, the linear range of BSA was 0 - 0.06 microg mL(-1) with detection limits of 2.38 ng mL(-1). The method was applied to the analysis of protein in human urine and penicillin samples with satisfactory results. The relative standard deviation was in all instances less than 4.0%, and the recovery was in the range of 97.5 - 104%. 相似文献
922.
Activated carbon fiber (ACF) as extraction fiber for solid-phase microextraction (SPME) and its application for the analysis of banned organochlorine pesticides (OCPs) were investigated. Firstly, ACF was activated by different concentration of zinc chloride, which indicated that ACF activated by 60% zinc chloride had a reasonable specific surface area, pore volume and pore distribution. Secondly, the parameters for the ACF-SPME procedure, the adsorption and desorption conditions, were also optimized when coupled with gas chromatography-mass spectrometry (GC-MS). Thirdly, the ACF-SPME was used to analyze 17 kinds of OCPs in water. The linearity of most pesticides was found to be between 0.2 and 50 microg/l with GC-MS under the selected ion monitoring (SIM) acquisition mode. The limits of detection (LOD) at the sub microg/l were obtained. The work demonstrated here shows that ACF is a promising alternative for the SPME procedure. 相似文献
923.
The binding of lomefloxacin to bovine lactoferrin (BLf) in a dilute aqueous solution was studied using fluorescence spectra. The binding constant (K) and the number of binding sites (n) were obtained by a fluorescence quenching method. The binding distance (r) and energy-transfer efficiency (E) between lomefloxacin and bovine lactoferrin were also obtained according to the mechanism of Fo?rster-type dipole-dipole nonradiative energy-transfer. The effect of lomefloxacin on the conformation of bovine lactoferrin was also analyzed by synchronous fluorescence spectroscopy. The interaction between lomefloxacin and bovine lactoferrin is strong. Lomefloxacin can affect the conformation of bovine lactoferrin to some degree. 相似文献
924.
Positive Steady States of a Prey-predator Model with Diffusion and Non-monotone Conversion Rate 总被引:1,自引:0,他引:1
Rui PENG Ming Xin WANG Wen Van CHEN 《数学学报(英文版)》2007,23(4):749-760
In this paper, we study the positive steady states of a prey-predator model with diffusion throughout and a non-monotone conversion rate under the homogeneous Dirichlet boundary condition. We obtain some results of the existence and non-existence of positive steady states. The stability and uniqueness of positive steady states are also discussed. 相似文献
925.
Optical waveguide fabrication and integration with a micro-mirror inside photosensitive glass by femtosecond laser direct writing 总被引:1,自引:0,他引:1
Z. Wang K. Sugioka Y. Hanada K. Midorikawa 《Applied Physics A: Materials Science & Processing》2007,88(4):699-704
Photosensitive glass is a potentially important material for micro-fluidic devices that can be integrated with micro-optical
components for biochemical analysis. Here, we demonstrate the fabrication of optical waveguides inside glass by femtosecond
laser direct writing. The influence of the laser parameters on the waveguide properties is investigated, and it is revealed
that the waveguide mode can be well controlled. The single mode is achieved at a low writing energy, while the multimode is
achieved with increasing energy. In spite of a longitudinally elongated elliptical shape of the cross-sectional profile, the
far-field pattern of the single-mode waveguide shows an almost symmetric profile. The measured propagation loss and the coupling
loss are evaluated to be ∼0.6 dB/cm and ∼1.6 dB at a wavelength of 632.8 nm, respectively, under the conditions of 1.0–2.0 μJ
pulse energy and 200–500 μm/s scan speed. The increased optical loss is associated with a higher waveguide mode at higher
writing energy. Furthermore, the integration of waveguides and a micromirror made of a hollow microplate inside the glass
is demonstrated to bend the laser beam at an angle of 90° in a small chip. The bending loss is estimated to be smaller than
0.3 dB.
PACS 42.62.-b; 42.82.Cr; 82.50.Pt; 42.79.Gn; 42.81.Qb 相似文献
926.
采用常压金属有机物化学气相沉积技术(AP-MOCVD),以二乙基锌(DEZn)为Zn源,去离子水(H2O)为氧源,N2作载气,在外延ZnO薄膜的反应气氛中通入少量氢气,在c-Al2O3衬底上生长出了ZnO∶H薄膜。用X射线双晶衍射和光致发光谱对ZnO∶H薄膜的结晶性能和光学性质进行表征。结果表明,ZnO∶H薄膜(002)和(102)面的Ω扫描半峰全宽分别为46.1 mrad和81.4 mrad,表明该薄膜具有良好的结晶性能;室温下,ZnO∶H薄膜具有较强的紫外光发射(380 nm),在低温10 K光致发光谱中观测到位于3.3630 eV处与氢相关的中性施主束缚激子峰(I4)及其位于3.331 eV处的双电子卫星峰(TES)。采用退火的方法,通过观测I4峰的强度变化,研究了氢在ZnO∶H薄膜中的热稳定性。发现随着退火温度的升高,I4峰的强度逐渐减弱,表明在高温下退火,氢会从ZnO薄膜中逸出。 相似文献
927.
928.
A cobalt‐containing monodentate phosphine [(μ2‐PPh2CH2PPh2‐κ2P)Co2(CO)4][μ2‐η2‐PhC≡CP(i‐Pr)2] 2f , was prepared from the reaction of (μ2‐PPh2CH2PPh2‐κ2P)Co2(CO)6 1 with PhC≡CP(i‐Pr)2. It was accompanied by an oxidized compound, [(μ2‐PPh2CH2PPh2‐κ2P)Co2(CO)4][μ2‐η2‐PhC≡CP(=O)(i‐Pr2)] 2fo during the chromatographic process. Further reaction of 2f with Mo(CO)6 resulted in the formation of a 2f ‐ligated molybdenum complex 4 , [(μ2‐PPh2CH2PPh2‐κ2P)Co2(CO)4][μ2‐η2‐PhC≡CP(i‐Pr2)‐κP]‐Mo(CO)5. 相似文献
929.
5 TW/40 fs级台式钛宝石激光系统研究 总被引:2,自引:0,他引:2
在TSA-25系统输出35 mJ,800 nm啁啾脉冲的基础上,建立了以钛宝石作为增益介质的二级啁啾脉冲放大(CPA)系统。使用0.6 J和1.6 J,532 nm,10 Hz Nd∶YAG激光抽运,输出脉冲能量达到500 mJ,经压缩脉冲宽度为41 fs,压缩器的能量转换效率为63%,峰值功率可达7.6 TW。通过对放大器系统的钛宝石晶体、抽运密度以及多通结构通道数的选择等实验,有效地提高了能量放大器的萃取效率。其主放大器能量萃取效率达到32%,整个系统占用尺寸不到10 m2。 相似文献
930.
Model and empirical study on some collaboration networks 总被引:8,自引:0,他引:8
Pei-Pei Zhang Kan Chen Yue He Tao Zhou Bei-Bei Su Yingdi Jin Hui Chang Yue-Ping Zhou Li-Cheng Sun Bing-Hong Wang Da-Ren He 《Physica A》2006,360(2):599-616
In this paper we present an empirical study of a few practical systems described by cooperation networks, and propose a model to understand the results obtained. We study four non-social systems, which are the Bus Route Networks of Beijing and Yangzhou, the Travel Route Network of China, Huai-Yang recipes of Chinese cooked food, and a social system, which is the Collaboration Network of Hollywood Actors. In order to explain the results related to the degree distribution, act-degree distribution and act-size distribution (especially about the degree distribution, which may be better fitted using a stretched exponential distribution (SED)), we suggest a simple model to show a possible evolutionary mechanism for the emergence of such networks. The analytic and numerical results obtained from the model are in good agreement with the empirical results. 相似文献