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排序方式: 共有229条查询结果,搜索用时 31 毫秒
31.
I. Shirotani S. Yoshida Y. Wada T. Kajiwara M. Murakami S. Yoshimura 《Solid State Communications》1981,38(7):653-656
The electrical resistivity of N-n-propylpyridinium-TCNQ2 (NPPy-TCNQ2) and N-n-butylpyridinium-TCNQn (NBPy-TCNQn) has been measured as a function of temperature and pressure. Phase transitions in these salts have been studied at high pressures. The transition temperature (Tc) in NPPy-TCNQ2 at atmospheric pressure increased with increasing pressure at the rate of dTc/dP = + 12.0 degkbar?1. The value of volume change calculated from the Clapeylon-Clausius relation was + 4.4 cm3 mol?1. The electrical resistivity along the a- and c-axis increased with increasing pressure below 7 kbar. This anomalous electrical behaviour is closely related to the crystal structure of NPPy-TCNQ2. The resistivity dropped sharply at about 11 kbar. This abrupt change may be due to a new pressure induced phase transition.The Tc of the NBPy-TCNQn increased remarkably with increasing pressure up to 0.7 kbar, above which the phase transition disappeared. The phase transitions of N-n-alkyl-substituted pyridinium TCNQ salts depend strongly on the nature of cations. 相似文献
32.
Itsuro Matsuo Muneo Ohkido Hitoshi Fujita Kenshi Suzuki 《Photochemistry and photobiology》1980,31(2):175-178
Abstract— When a suspension of Escherichia coli was irradiated with near-UV light in the presence of chlorpromazine (at a concentration below a cytotoxic level), the cells were killed. Efficiency of the photodynamic killing was not influenced by the deficiency of the uvrA gene or the recA gene. Neither phenotypic reversion of E. coli Hs30R (arginine auxotroph) nor induction of lambda prophage in lysogenic bacteria was detected after this treatment. 相似文献
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Yuji Utsunomiya Takashi Kajiwara Takashi Nishiyama Kunihito Nagayama Shiro Kubota 《Applied Physics A: Materials Science & Processing》2010,99(3):641-649
We studied a new pulse laser ablation phenomenon on a liquid surface layer, which is caused by the difference between the
refractive indices of the two materials involved. The present study was motivated by our previous study, which showed that
laser ablation can occur at the interface between a transparent material and a gas or liquid medium when the laser pulse is
focused through the transparent material. In this case, the ablation threshold fluence is reduced remarkably. In the present
study, experiments were conducted in water and air in order to confirm this phenomenon for a combination of two fluid media
with different refractive indices. This phenomenon was observed in detail by pulse laser shadowgraphy. A high-resolution film
was used to record the phenomenon with a Nd:YAG pulse laser with 10-ns duration as a light source. The laser ablation phenomenon
on the liquid surface layer caused by a focused Nd:YAG laser pulse with 1064-nm wavelength was found to be followed by the
splashing of the liquid surface, inducing a liquid jet with many ligaments. The liquid jet extension velocity was around 1000
m/s in a typical case. The liquid jet decelerated drastically due to rapid atomization at the tips of the ligaments. The liquid
jet phenomenon was found to depend on the pulse laser parameters such as the laser fluence on the liquid surface, laser energy,
and laser beam pattern. The threshold laser fluence for the generation of a liquid jet was 20 J/cm2. By increasing the incident laser energy with a fixed laser fluence, the laser focused area increased, which eventually led
to an increase in the size of the plasma column. The larger the laser energy, the larger the jet size and the longer the temporal
behavior. The laser beam pattern was found to have significant effects on the liquid jet’s velocity, shape, and history. 相似文献
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Thanatuksorn P Kajiwara K Murase N Franks F 《Physical chemistry chemical physics : PCCP》2008,10(35):5452-5458
We report on the polymorphic transitions of ice in aqueous solutions of glucose during freezing and thawing over a temperature range of 298-153 K. Emphasis is placed on the sub-glass temperature range where the systems consist of cubic ice (ice-1c) crystals embedded in a freeze concentrated, vitrified glucose solution. The systems were studied by a combination of thermal, cryomicroscopic and X-ray diffraction techniques. At the glass transition (230 K) the solution phase contained 80 mol% of unfrozen water which, on further cooling, was shown to crystallise as cubic ice (ice-1c), nucleated in the vitrified matrix. The thermal stability of the ice-1c formed was studied by annealing and isothermal changes in the diffraction patterns with time. The polymorphic transition 1c --> 1h could be fitted to first order kinetics. Contrary to currently held belief, this study has provided evidence that ice-1c can be formed directly in the bulk water phase of a vitrified solution. 相似文献
39.
Dr. Ziqian Xue Dr. Jia-Jia Zheng Dr. Yusuke Nishiyama Dr. Ming-Shui Yao Dr. Yoshitaka Aoyama Zeyu Fan Dr. Ping Wang Prof. Takashi Kajiwara Prof. Yoshiki Kubota Prof. Satoshi Horike Prof. Ken-ichi Otake Prof. Susumu Kitagawa 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(2):e202215234
Exploring new porous coordination polymers (PCPs) that have tunable structure and conductivity is attractive but remains challenging. Herein, fine pore structure engineering by ligand conformation control of naphthalene diimide (NDI)-based semiconducting PCPs with π stacking-dependent conductivity tunability is achieved. The π stacking distances and ligand conformation in these isoreticular PCPs were modulated by employing metal centers with different coordination geometries. As a result, three conjugated PCPs (Co−pyNDI, Ni−pyNDI, and Zn−pyNDI) with varying pore structure and conductivity were obtained. Their crystal structures were determined by three-dimensional electron diffraction. The through-space charge transfer and tunable pore structure in these PCPs result in modulated selectivity and sensitivity in gas sensing. Zn−pyNDI can serve as a room-temperature operable chemiresistive sensor selective to acetone. 相似文献
40.
Hiraga H Miyasaka H Nakata K Kajiwara T Takaishi S Oshima Y Nojiri H Yamashita M 《Inorganic chemistry》2007,46(23):9661-9671
Two unique materials based on Mn4 single-molecule magnet (SMM) clusters (ST=9) and integer or non-integer average valent platinum maleonitriledithiolate (mnt2-) complexes, [{MnII2MnIII2(hmp)6(MeCN)2}{Pt(mnt)2}2][Pt(mnt)2]2.2MeCN (1) and [{MnII2MnIII2(hmp)6(MeCN)2}{Pt(mnt)2}4][Pt(mnt)2]2 (2), were synthesized by the material diffusion method and electrochemical oxidation, respectively (hmp-=2-hydroxymethylpyridinate). 1 and 2 are comprised of four and six [Pt(mnt)2]n- units, respectively, in addition to a common MnII2MnIII2 double-cuboidal unit, [MnII2MnIII2(hmp)6(MeCN)2]4+ (hereinafter [Mn4]4+). Among the [Pt(mnt)2]n- units, two units in 1 and four units in 2 are coordinated with the [Mn4]4+ unit, forming a 1D chain of {-[Mn4]-[Pt(mnt)2]2-} for 1 and a discrete subunit of {[Pt(mnt)2]2-[Mn4]-[Pt(mnt)2]2} for 2. The other two [Pt(mnt)2]n- units, occupying void space of the packing, form a stacking column with the coordinating [Pt(mnt)2]n- units, finally constructing hybrid frames of aggregates consisting of [Mn4]4+ units and [Pt(mnt)2]n- units. Electronic conductivity measurements revealed that 1 is an insulator and 2 is a semiconductor with sigma=0.22 S.cm(-1) at room temperature and an activation energy of 136 meV. Detailed magnetic measurements proved that the [Mn4]4+ units in 1 and 2 behave as SMMs with an ST=9 ground state at low temperatures. There is no significant interaction between [Mn4]4+ units and [Pt(mnt)2]n- units, but interactions between localized spins of [Pt(mnt)2]n- were detected even in 2 at low temperatures where the conductivity is electronically insulated. 2 is the first example of a hybridized material exhibiting SMM behavior and electronic conductivity. 相似文献