One of the most complex "small molecule structures" ever reported: 16 independent molecules in the asymmetric unit for an ortho-palladated primary amine

The presumably "small molecule structure" of the organopalladium complex rac-PdCl(C(6)H(3)-4-OMe-CHMeNH(2))(py) crystallizes with 16 molecules in the asymmetric unit, a highly unusual situation according to the CSD database. The symmetrically independent residues differ with respect to soft conformational degrees of freedom. Packing in the acetonitrile solvate of the same compound is unexceptional.     

The molecular conformation of pentan‐3‐one studied in cholic acid pentan‐3‐one solvate

The crystal structure of cholic acid–pentan‐3‐one (1/1), C₅H₁₀O·C₂₄H₄₀O₅, has been determined in order to deduce the molecular conformation of the small volatile ketone. Data were collected at 100 K to a resolution of (sin θ)/λ = 0.91 Å⁻¹. The structure contains a hydrogen‐bonded cholic acid host network, forming only van der Waals interactions with the guest pentan‐3‐one molecules. The ketone molecules are disordered on general positions, with two clearly identifiable conformations. The majority conformer exhibits approximate C₂ symmetry and is similar to that recently observed by microwave spectroscopy in the gas phase.     

A unified quantum <Emphasis Type="Italic">SO</Emphasis>(3) invariant for rational homology 3-spheres

Given a rational homology 3-sphere M with |H ₁(M,ℤ)|=b and a link L inside M, colored by odd numbers, we construct a unified invariant I _M,L belonging to a modification of the Habiro ring where b is inverted. Our unified invariant dominates the whole set of the SO(3) Witten–Reshetikhin–Turaev invariants of the pair (M,L). If b=1 and L=∅, I _M coincides with Habiro’s invariant of integral homology 3-spheres. For b>1, the unified invariant defined by the third author is determined by I _M . Important applications are the new Ohtsuki series (perturbative expansions of I _M ) dominating quantum SO(3) invariants at roots of unity whose order is not a power of a prime. These series are not known to be determined by the LMO invariant.     

Die Verfahren zur jodometrischen Zinnbestimmung in Mineralien

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Einen Analysengang zur Identifizierung von Giften in verd?chtigen Lebensmitteln

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Steroide

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Kreatininbestimmug im Urin

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Zur gravimetrischen Bestimmung von Wolfram

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Eine Methode zur schnellen Bestimmung von Quecksilber und Phosphor in quecksilberorganischen Verbindungen

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