全文获取类型
收费全文 | 357篇 |
免费 | 63篇 |
国内免费 | 5篇 |
专业分类
化学 | 258篇 |
晶体学 | 2篇 |
力学 | 16篇 |
综合类 | 1篇 |
数学 | 61篇 |
物理学 | 87篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 10篇 |
2017年 | 1篇 |
2016年 | 16篇 |
2015年 | 14篇 |
2014年 | 18篇 |
2013年 | 28篇 |
2012年 | 36篇 |
2011年 | 21篇 |
2010年 | 16篇 |
2009年 | 16篇 |
2008年 | 15篇 |
2007年 | 34篇 |
2006年 | 19篇 |
2005年 | 12篇 |
2004年 | 7篇 |
2003年 | 13篇 |
2002年 | 6篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 12篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 9篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1969年 | 2篇 |
1968年 | 1篇 |
排序方式: 共有425条查询结果,搜索用时 125 毫秒
81.
el Hajjouji H Belmonte E García-López J Fernández I Iglesias MJ Roces L García-Granda S El Laghdach A López Ortiz F 《Organic & biomolecular chemistry》2012,10(29):5647-5658
ortho-Lithiation of N,N-diisopropyl-P,P-diphenylphosphinothioic amide using n-BuLi in the presence of TMEDA in diethyl ether followed by electrophilic trapping is described as an efficient method for the synthesis of ortho-functionalised derivatives in high yields. The structural modification of the phosphinothioic amide includes C-X (X = P, S, Si, Sn, I) and C-C bond forming reactions with a large variety of electrophiles. Additional applications based on functional group transformations are also reported. They include imine formation, desulfurization and Suzuki cross-coupling reactions on selected compounds. 相似文献
82.
Hctor Novoa de Armas Oswald M. Peeters Norbert M. Blaton Camiel J. De Ranter Ramn Poms Hernndez Jos L. Mola Carlos Serafín Prez Leticia Surez García Martín A. Iglesias Francisco Coll Manchado 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(1):78-79
In the title compound, C24H36O6, the ester linkage in ring A is equatorial. The six‐membered rings A, B and C have chair conformations. The five‐membered ring D adopts a 13β,14α‐half‐chair conformation and the E ring adopts an envelope conformation. The A/B, B/C and C/D ring junctions are trans, whereas the D/E junction is cis. 相似文献
83.
用分子动力学方法和不同参数的指数 6势函数计算了T =30 4K的高密度氦的等温压缩线和能量分布 .给出了能精确描述高密度氦原子间相互作用的指数 6势函数优化参数 .并用优化的势函数计算了高密度氦T =30 0K和T =2 98K的等温压缩线 ,计算结果和实验值非常吻合 .进一步用优化的势函数模拟了高温高密度氦的状态方程及其结构 ,发现当把 ρ限定为 1 .6 0g /cm3 时 ,其径向分布函数的第 2个峰将在 2 0 0 0~ 30 40K区间消失 ,表明此时发生了固 液相变过程 . 相似文献
84.
85.
86.
Rosangela H. LoschiPilar L. Iglesias Reinaldo B. Arellano-Valle 《Journal of multivariate analysis》2003,85(1):10-23
De Finetti style theorems characterize models (predictive distributions) as mixtures of the likelihood function and the prior distribution, beginning from some judgment of invariance about observable quantities. The likelihood function generally has its functional form identified from invariance assumptions only. However, we need additional conditions on observable quantities (typically, assumptions on conditional expectations) to identify the prior distribution. In this paper, we consider some well-known invariance assumptions and establish additional conditions on observable quantities in order to obtain a predictivistic characterization of the multivariate and matrix-variate Student-t distributions as well as for the Student-t linear model. As a byproduct, a characterization for the Pearson type II distribution is provided. 相似文献
87.
88.
89.
90.
ter Steege DH Smits M de Lange CA Westwood NP Peel JB Visscher L 《Faraday discussions》2000,(115):259-69; discussion 303-30
A (2 + 1) one-colour resonance-enhanced multiphoton ionisation study is carried out on the C 2 sigma- state of the ClO radical in the one-photon energy range 29,500-31,250 cm-1. The ClO radical is produced by one-photon photolysis of ClO2 employing 359.2 nm photons derived from a separate laser. In this way a significant concentration of vibrationally excited ClO in its spin-orbit split X 2 pi omega (omega = 3/2 or 1/2) electronic ground state is produced. In addition to mass-resolved excitation spectra, kinetic-energy resolved photoelectron spectra for the X 3 sigma-(v+)<--C 2 sigma-(v' = 3-5) transitions are measured. These transitions are not completely Frank-Condon diagonal, and indicate a decrease in bond length on removal of the Rydberg electron from the C 2 sigma- state. In addition to an unambiguous assignment of the C 2 sigma- state, valuable information is obtained on the degree of vibrational excitation with which the nascent ClO radical is formed in the photolysis of ClO2. Analysis of the photoelectron spectra is supported by Franck-Condon calculations based on potential energy curves either from experimental spectroscopic parameters, or obtained by theoretical ab initio methods. 相似文献