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101.
Horacio Corti Rosa Crovetto Roberto Fernández-Prini 《Journal of solution chemistry》1979,8(12):897-908
The conductivity of LiOH aqueous solutions has been determined at 15, 25, and 45°C. The data analysis showed that LiOH is a slightly associated electrolyte, its association increasing with temperature. The association constant and distance parameter obtained from the conductivity data were successfully employed to calculate the activity coefficients of the solutions. The same procedure applied to very precise conductivity data for NaOH aqueous solutions enabled us to assess the reliability of this method of calculation of activity coefficients up to 0.1m. The alkali metal hydroxides show a reverse trend in the way their properties change with cationic radius, as is the case for the fluorides with which they are compared. 相似文献
102.
103.
Summary The Lie group structure of the group Up of isometries of Hp,1⩽p<∞, p≠2, is studied. In particular, it is shown that Up is an extension of the circle group by the group of all M?bius transformations of the disc. The cocycle of the extension
is calculated. It is further shown that only the trivial subspaces of Hp are invariant under Up.
Entrata in Redazione il 19 ottobre 1977.
The work of this author was supported by a National Science Foundation grant.
The research of this author was done while he was a Visiting Professor at the University of Florence through a grant from
the Consiglio Nazionale delle Ricerche (Italy). 相似文献
104.
Summary Rhodium(I) tropolonate and salicylaldehydate complexes of the general formula Rh(A)(diolefin) (A = tropolonate, -iso-propyltropolonate, -methyltropolonate and salicylaldehydate; diolefin = 1,5-cyclooctadiene, 2,5-norbornadiene and tetrafluorobenzobarrelene) have been prepared by several routes. The ability of Rh(trop)(COD) to function as an intermediate for the synthesis of other neutral and cationic rhodium(I) complexes has been studied and its hydroformylation activity has been explored briefly. 相似文献
105.
A simple, precise absorptiomotric method for bismuth based upon its reaction with Thorin is described. The effect of foreign elements was established. 相似文献
106.
Near-field coupling between an excited atom and a surface-polariton mode can dramatically modify atomic branching ratios, because of surface-induced enhancement of a resonant decay channel. We show here that Cs(6D(3/2)) transfer towards Cs(7P(1/2)) (at lambda = 12.15 microm), negligible in free space, becomes efficient in the vicinity (< or =100 nm) of a sapphire window, due to a 12 microm resonance in the surface-polariton modes. The experiment relies on a selective reflection probing on the 7P(1/2)-10D(3/2) transition. 相似文献
107.
108.
109.
The 2-phenylbenzoxazoles were obtained in moderate to good yields by reaction of the substituted o-aminophenols with benzaldehydes in the presence of one equivalent of potassium cyanide as an equimolecular catalyst in N,N-dimethylformamide at room temperature. 相似文献
110.
Licarion Pinto César Horacio Díaz Nieto María Alicia Zón Héctor Fernández Mario Cesar Ugulino de Araujo 《Analytica chimica acta》2016
Biogenic amines (BAs) are used for identifying spoilage in food. The most common are tryptamine (TRY), 2-phenylethylamine (PHE), putrescine (PUT), cadaverine (CAD) and histamine (HIS). Due to lack of chromophores, chemical derivatization with dansyl was employed to analyze these BAs using high performance liquid chromatography with a diode array detector (HPLC-DAD). However, the derivatization reaction occurs with any primary or secondary amine, leading to co-elution of analytes and interferents with identical spectral profiles, and thus causing rank deficiency. When the spectral profile is the same and peak misalignment is present on the chromatographic runs, it is not possible to handle the data only with Multivariate Curve Resolution and Alternative Least Square (MCR-ALS), by augmenting the time, or the spectral mode. A way to circumvent this drawback is to receive information from another detector that leads to a selective profile for the analyte. To overcome both problems, (tri-linearity break in time, and spectral mode), this paper proposes a new analytical methodology for fast quantitation of these BAs in fish with HPLC-DAD by using the icoshift algorithm for temporal misalignment correction before MCR-ALS spectral mode augmented treatment. Limits of detection, relative errors of prediction (REP) and average recoveries, ranging from 0.14 to 0.50 µg mL−1, 3.5–8.8% and 88.08%–99.68%, respectively. These are outstanding results obtained, reaching quantification limits for the five BAs much lower than those established by the Food and Agriculture Organization of the United Nations and World Health Organization (FAO/WHO), and the European Food Safety Authority (EFSA), all without any pre-concentration steps. The concentrations of BAs in fish samples ranged from 7.82 to 29.41 µg g−1, 8.68–25.95 µg g−1, 4.76–28.54 µg g−1, 5.18–39.95 µg g−1 and 1.45–52.62 µg g−1 for TRY, PHE, PUT, CAD, and HIS, respectively. In addition, the proposed method spends less than 4 min in an isocratic run, consuming less solvent in accordance with the principles of green analytical chemistry. 相似文献