全文获取类型
收费全文 | 236篇 |
免费 | 15篇 |
国内免费 | 1篇 |
专业分类
化学 | 193篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 4篇 |
物理学 | 50篇 |
出版年
2023年 | 5篇 |
2022年 | 4篇 |
2021年 | 7篇 |
2020年 | 16篇 |
2019年 | 15篇 |
2018年 | 9篇 |
2017年 | 7篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 11篇 |
2013年 | 17篇 |
2012年 | 12篇 |
2011年 | 17篇 |
2010年 | 10篇 |
2009年 | 7篇 |
2008年 | 14篇 |
2007年 | 15篇 |
2006年 | 6篇 |
2005年 | 12篇 |
2004年 | 5篇 |
2003年 | 16篇 |
2002年 | 6篇 |
1999年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有252条查询结果,搜索用时 15 毫秒
61.
Dr. Hikaru Yanai Teru Kawazoe Nobuyuki Ishii Prof. Dr. Bernhard Witulski Prof. Dr. Takashi Matsumoto 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(44):11442-11449
4-Aryl-1,3-dihydroxy-2-naphthoates having the less accessible 1,2,3,4-tetrasubstituted naphthalene scaffold and that show photoluminescence emission from solid state as well as in solutions, were selectively synthesized from brominated lactol silyl ethers through the 1,2-aryl-migrative ring rearrangement reaction. 相似文献
62.
Yoko Tanaka Yu Kitamura Dr. Ryuji Kawano Dr. Kan Shoji Moe Hiratani Dr. Tetsuo Honma Dr. Hikaru Takaya Dr. Hirofumi Yoshikawa Dr. Takaaki Tsuruoka Dr. Daisuke Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(41):8889-8896
To diversify metal-organic frameworks (MOFs), multi-component MOFs constructed from more than two kinds of bridging ligand have been actively investigated due to the high degree of design freedom afforded by the combination of multiple ligands. Predicting the synthesis conditions for such MOFs requires an understanding of the crystallization mechanism, which has so far remained elusive. In this context, microflow systems are efficient tools for capturing non-equilibrium states as they facilitate precise and efficient mixing with reaction times that correspond to the distance from the mixing point, thus enabling reliable control of non-equilibrium crystallization processes. Herein, we prepared coordination polymers with pillared-layer structures and observed the intermediates in the syntheses with an in-situ measurement system that combines microflow reaction with UV/Vis and X-ray absorption fine-structure spectroscopies, thereby enabling their rapid nucleation to be monitored. Based on the results, a three-step nonclassical nucleation mechanism involving two kinds of intermediate is proposed. 相似文献
63.
64.
The basic salt-initiated polymerization of α-aminoisobutyric acid NCA in acetonitrile was studied using various alkaline alcoholates and in the presence or absence of various protic (very weak acid) additives. The cation effect observed was the one expected from either the N-carboxy-α-amino acid anhydride (NCA) anion mechanism (activated monomer mechanism) or the alcoholate anion mechanism (Blout's mechanism). The anion effect appeared to be abnormal for the former mechanism, but did not agree nor disagree substantially with the latter. Furthermore, such additives as methanol (conjugate acid of the initiator), 3-methylhydantoin, 2-oxazolidone, and N-acetylglycine NCA (prototype of the chain growing through the NCA anion mechanism) considerably enhanced the rate of initiation. A still higher rate of initiation could be obtained by the combined use of two additives. IR and DTA analyses of the polymerization products showed the formation of 5,5-dimethylhydan-toin-3-isobutyric acid in the sample using the alcohol-free initiator, hence the NCA anion mechanism is operative. This acid was absent in the low DP polymer obtained in the presence of added methanol, and this agrees with the alcoholate anion mechanism without, however, proving it. Thus, while only part of the results could be explained by one or the other of the previous interpretations, all the experimental facts were accounted for, without noticeable contradiction, by the hypothesis of a multiple mechanism which contains both interpretations among its elements. 相似文献
65.
Yuko Ichiyanagi Yuki Moro Hikaru Katayanagi Shinji Kimura Daiki Shigeoka Tomoyuki Hiroki Toshiyuki Mashino 《Journal of Thermal Analysis and Calorimetry》2010,99(1):83-86
Magnetic nanoparticles were prepared by a wet chemical method. Precursors of MFe2O4 (M = Co, Mn, Zn) were prepared from a mixture of metal chloride and metasilicate nonahydrate aqueous solutions. The precipitates
obtained in the wet chemical method were calcined to obtain MFe2O4 nanoparticles encapsulated by amorphous SiO2. The blocking temperatures T
B’s were between 20 and 320 K, in this temperature range, the anisotropy energy of the particles decreased below their thermal
energy. T
B increased with the particle size. In order to clarify the nanoparticle formation process, differential thermal analysis and
thermogravimetric (TG-DTA) measurements were performed for the as-prepared samples. 相似文献
66.
Haruko Ikeuchi Mitsuhiro Kanakubo Shin Okuno Rika Sato Koichi Fujita Manatsu Hamada Nobuhiro Shoda Kenta Fukui Koji Okada Hikaru Kanazawa Akira Iimori Daisaku Miyake Takeshi Takeda Gen P. Satô 《Journal of solution chemistry》2010,39(10):1428-1453
The densities and the viscosities of tris(acetylacetonato)cobalt(III) solutions in acetonitrile, dichloromethane, chloroform, tetrachloromethane, benzene, toluene, ethylbenzene, and p-xylene were measured in the dilute concentration regions at several temperatures ranging from 278 to 313 K under ambient pressure. The partial molar volumes of the solvents and solute were calculated. They are independent of concentration and increase slightly as the temperature increases. The viscosity A- and B-coefficients of the Jones-Dole equation were obtained. The A-coefficients were found to be zero within experimental error. The B-coefficients are positive and decrease as the temperature increases. Thermodynamic quantities of activation for viscous flow were calculated on the basis of Eyring’s viscosity equation. From the quantities obtained in this study, along with some information from the literature, it is suggested that structure-making interactions occur between the segments of the complex and the solvent molecules. These interactions include electrostatic interactions between the local charge on the complex and the dipole moment of the solvent in solutions of acetonitrile and dichloromethane, interlocking packing interactions along C 3-axis of the complex with solvent in solutions of chloroform and tetrachloromethane, and π-electron interactions between the chelate ring of the complex and the solvent in solutions of benzene, toluene, ethylbenzene, and p-xylene. 相似文献
67.
68.
The ratio of the scale parameter Λ in massless QCD defined on a lattice to the one in the continuum theory is determined by performing one-loop renormalization of the coupling constant. Our calculation method on a lattice directly relates Λlattice to the continuum one in the minimal subtraction scheme. The effect of incorporation of massless quarks depends on a parameter λ which is introduced to avoid trouble with fermions on a lattice. For λ=1, which is Wilson's value, the ratio previously calculated by Hasenfratz in the pure gauge theory is changed as follows: Critical properties of the lattice QCD will also be discussed briefly. 相似文献
69.
Hikaru Aramoto Motofumi Osaki Subaru Konishi Chiharu Ueda Yuichiro Kobayashi Yoshinori Takashima Akira Harada Hiroyasu Yamaguchi 《Chemical science》2020,11(17):4322
Stimuli-responsive hydrogels have attracted attention as soft actuators that act similarly to muscles. In this work, hydrogel actuators controlled by host–guest interactions have been developed. The introduction of a 1:1 inclusion complex into a hydrogel is a popular design for achieving a change in cross-linking density. To realize faster and larger deformation properties, the introduction of a 1:2 inclusion complex is effective because the alteration in cross-linking density in a hydrogel with 1:2 complexes is larger than that in a hydrogel with 1:1 complexes. A redox-responsive hydrogel actuator cross-linked with 1:2 inclusion complexes is designed, where γ-cyclodextrin (γCD) and viologens modified with an alkyl chain derivative (VC11) were employed as the host and guest units, respectively. γCD includes two VC11 molecules in its cavity. The obtained γCD–VC11 hydrogel cross-linked with the 1:2 complex showed faster and larger deformation behaviour than the αCD–VC11 and the βCD–VC11 hydrogels cross-linked with a 1:1 complex. The deformation ratio and response speed of the γCD–VC11 hydrogel, which forms a supramolecular cross-linking structure by stimuli, are 3 and 11 times larger, respectively, than those of our previous hydrogel consisting of a βCD/ferrocene 1:1 inclusion complex.A hydrogel actuator with a 1:2 host–guest complex controlled by redox stimuli has been developed to realize faster and larger deformation. 相似文献
70.
Hikaru Sekiguchi Bernard Coutin 《Journal of polymer science. Part A, Polymer chemistry》1973,11(7):1601-1614
The anionic polymerization of lactams at low temperatures is not governed by thermodynamic equilibrium between the cyclic monomer and the linear polymer. On the basis of our reaction mechanism we propose therefore a new criterion (in contrast to the thermodynamic one) for estimating the chemical polymerizability of lactam: kendo/klactam, where klactam is the rate constant of alkaline hydrolysis of the lactam and kendo that of the endocyclic imide bond in the corresponding N-acyl lactam. The value thus found for α-piperidone and giving the theoretical polymerizability of this lactam accounts, however, only partially for its low polymerizability. Finally, the behavior of α-piperidone derivatives in α-pyrrolidone polymerization, as well as that of α-pyrrolidone and α-piperidone in polymerization in the presence of inorganic salts such as LiCl and LiSCN, shows that the unusually low ability of this lactam to polymerize could be explained in terms of the hydrogen-bond-rich structure of the resulting polymer appearing at a lower stage of conversion than that of other lactams and which might encage the active site situated at the end of the growing chain and thus hinder the access of lactam anion. 相似文献