全文获取类型
收费全文 | 18432篇 |
免费 | 3159篇 |
国内免费 | 2117篇 |
专业分类
化学 | 13124篇 |
晶体学 | 187篇 |
力学 | 1077篇 |
综合类 | 114篇 |
数学 | 1844篇 |
物理学 | 7362篇 |
出版年
2024年 | 80篇 |
2023年 | 422篇 |
2022年 | 674篇 |
2021年 | 767篇 |
2020年 | 765篇 |
2019年 | 759篇 |
2018年 | 684篇 |
2017年 | 609篇 |
2016年 | 922篇 |
2015年 | 892篇 |
2014年 | 1061篇 |
2013年 | 1332篇 |
2012年 | 1655篇 |
2011年 | 1551篇 |
2010年 | 1071篇 |
2009年 | 994篇 |
2008年 | 1109篇 |
2007年 | 1044篇 |
2006年 | 956篇 |
2005年 | 861篇 |
2004年 | 614篇 |
2003年 | 518篇 |
2002年 | 512篇 |
2001年 | 401篇 |
2000年 | 359篇 |
1999年 | 431篇 |
1998年 | 348篇 |
1997年 | 338篇 |
1996年 | 324篇 |
1995年 | 278篇 |
1994年 | 226篇 |
1993年 | 199篇 |
1992年 | 156篇 |
1991年 | 135篇 |
1990年 | 157篇 |
1989年 | 111篇 |
1988年 | 76篇 |
1987年 | 54篇 |
1986年 | 59篇 |
1985年 | 59篇 |
1984年 | 30篇 |
1983年 | 30篇 |
1982年 | 30篇 |
1981年 | 19篇 |
1980年 | 10篇 |
1979年 | 3篇 |
1977年 | 3篇 |
1942年 | 2篇 |
1930年 | 2篇 |
1916年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
41.
A sensitive and selective method using liquid chromatography with electrospray ionization mass spectrometric detection was
developed for the quantification of bilobalide and ginkgolides in canine plasma. The analytes were extracted with diethyl
ether-dichloromethane-isopropanol (6:3:1, v/v) after spiking the samples with daidzein (internal standard). The lower limit
of quantification (LLOQ) of the method was 2.5 μg L−1 for ginkgolide B and 10.0 μg L−1 for bilabolide, ginkgolide A and ginkgolide C. The accuracy of the method was within 15% of the actual values over a wide
range of plasma concentrations. The intra-day and inter-day precision was better than 15% (R.S.D.). Finally, the LC-ESI-MS
method was successfully applied to study the pharmacokinetics of ginkgolides and bilabolide after administration of Ginkgo biloba extracts to dogs. 相似文献
42.
A DNA sequence can be identified with a word over an alphabet N = [A, C, G, T]. Characteristic sequences of a DNA sequence are given in term of classifications of bases of nucleic acids. Using the characteristic sequences, we construct a set of 2 x 2 matrices to represent DNA primary sequences, which are based on counting of the frequency of occurrence of all (0,1) triplets of characteristic sequences. Furthermore, the leading eigenvalues of these matrices are computed and considered as invariants for the DNA primary sequences. Similarity and dissimilarity analysis based on the characteristic sequences are given for eight exon-1 genes of beta-globin about eight species. 相似文献
43.
Protection of carbonyls as acetals or ketals using Brønsted acidic ionic liquid [Hmim]BF4 as catalyst as well as solvent was investigated. Satisfactory results were obtained for the protection of carbonyls as cycloacetals or ketals with diols. The product can be separated conveniently from the reaction system, and the ionic liquid can be reused after removal of water. 相似文献
44.
Guoyi Bai Chenfang Zhang Yuecheng Zhang Haijun Yu Fei He Huisen Ning Ligong Chen 《Reaction Kinetics and Catalysis Letters》2007,90(2):373-380
The racemization of R-(-)-2-amino-1-butanol in a reaction using Co/γ-Al2O3 catalysts and catalysts modified by Mg or Ca was investigated in this paper. Complete racemization was achieved with a yield
of over 83% at using the Mg modified Co/γ-Al2O3 catalyst under optimized reaction conditions of 170°C and 2.5 MPa of H2. The catalysts were thoroughly characterized by XRD, XPS, TPR, SEM and TEM. The addition of Mg and Ca may be advantageous
for dispersing and stabilizing the active species of the Co/γ-Al2O3 catalyst, protecting from sintering, significantly improving its catalytic activity and stability. 相似文献
45.
46.
47.
用电沉积方法将苯乙烯-马来酸酐、乙酸乙烯酯-马来酸酐、甲基丙烯酸甲酯-马来酸酐共聚物沉积于碳纤维表面。通过实验初步证实了此过程的负离子-自由基机理,以及沉积层在纤维表面的物理粘附。由于电沉积的聚合物中间层改善了碳纤维增强塑料中纤维-基体树脂间的界面粘接作用,使原来的剪切破坏基本上发生于界面的情况转变成发生于基体本身为主。并将单向碳纤维增强环氧树脂复合材料的层间剪切强度,由原来的600kg/cm~2左右提高到1000kg/cm~2以上,经沸水浸泡100小时后的强度损失也减少了。 相似文献
48.
A series of samples with the composition Ca(1)(-)(x)Na(2)(x)Al(2)B(2)O(7) (0 < x < or = 1) was investigated and a hexagonal structure with unusually large range of homogeneity (at least from x = 0.01 to 0.95) was revealed. The hexagonal phase consists of [Al(2)B(2)O(7)](infinity)(2)(-) lamellae stacked along the c axis, as in CaAl(2)B(2)O(7) and Na(2)Al(2)B(2)O(7). Nevertheless, the configuration and stacking sequence of the [Al(2)B(2)O(7)](infinity)(2)(-) lamellae are different in these three structures. In the hexagonal structure of Ca(1)(-)(x)()Na(2)(x)()Al(2)B(2)O(7), Ca and half Na cations (Na1) statistically occupy the same crystallographic site which is located between the [Al(2)B(2)O(7)](infinity)(2)(-) lamellae, the other half Na cations (Na2) distribute in the planes bisecting the [Al(2)B(2)O(7)](infinity)(2)(-) lamellae. Depending on the composition, the site occupation factor of Na2 site can vary in the same range as x, leading to a tunable density of Na(+) vacancies in the structure. The AlO(4) tetrahedra and BO(3) triangles in the structure tilt in appropriate ways to improve the bond valence sum of Na2 cations which are not sufficiently bonded to the anions. 相似文献
49.
中子成像作为一种快速、直观的无损检测技术,在核工业、航空航天、新能源、地质、考古、先进制造等多个领域得到广泛应用。中子成像利用中子不带电、穿透能力强、对轻元素敏感、可区分同位素和近邻元素等特性,非常适合开展含氢元素、近邻元素和同位素等材料的无损检测。本文概述了中子成像技术的基本原理及特点,并结合中国先进研究堆(CARR)中子成像装置上的应用案例, 重点介绍了国内外中子成像技术在储氢材料、燃料电池、岩石、核燃料元件、古代文物等领域的典型应用。随着中子成像技术的不断发展和广泛应用,有望为我国更多领域研究提供更强有力的技术支撑。 相似文献
50.
锗在国防工业、航空航天和通信等领域中的战略性,锗含量的测定对于保证材料质量和满足国际标准至关重要。本文综述了锗含量测定方法的多种技术,包括分光光度法、原子荧光光谱法、原子吸收光谱法、电感耦合等离子体原子发射光谱法、电感耦合等离子体质谱法以及滴定法。在每个检测方法的介绍中,详细探讨了方法的原理、前处理步骤以及应用范围,并分别总结了各个方法的优势和不足。最后,强调了锗含量测定方法的意义,特别是在满足出口监管和促进科学研究方面的作用。同时对锗元素的测定方法进行了展望,为未来的发展提供了参考方向。 相似文献