全文获取类型
收费全文 | 1319篇 |
免费 | 21篇 |
国内免费 | 3篇 |
专业分类
化学 | 682篇 |
晶体学 | 33篇 |
力学 | 34篇 |
数学 | 201篇 |
物理学 | 393篇 |
出版年
2020年 | 14篇 |
2019年 | 7篇 |
2018年 | 10篇 |
2017年 | 8篇 |
2016年 | 17篇 |
2015年 | 14篇 |
2014年 | 22篇 |
2013年 | 93篇 |
2012年 | 59篇 |
2011年 | 58篇 |
2010年 | 30篇 |
2009年 | 16篇 |
2008年 | 62篇 |
2007年 | 50篇 |
2006年 | 68篇 |
2005年 | 60篇 |
2004年 | 56篇 |
2003年 | 30篇 |
2002年 | 40篇 |
2001年 | 32篇 |
2000年 | 26篇 |
1999年 | 24篇 |
1998年 | 12篇 |
1997年 | 14篇 |
1996年 | 25篇 |
1995年 | 25篇 |
1994年 | 22篇 |
1993年 | 28篇 |
1992年 | 21篇 |
1991年 | 17篇 |
1990年 | 15篇 |
1989年 | 21篇 |
1988年 | 12篇 |
1987年 | 19篇 |
1986年 | 28篇 |
1985年 | 26篇 |
1984年 | 10篇 |
1983年 | 15篇 |
1982年 | 18篇 |
1981年 | 11篇 |
1980年 | 15篇 |
1979年 | 8篇 |
1978年 | 15篇 |
1977年 | 24篇 |
1976年 | 24篇 |
1975年 | 24篇 |
1974年 | 12篇 |
1973年 | 7篇 |
1971年 | 7篇 |
1970年 | 11篇 |
排序方式: 共有1343条查询结果,搜索用时 421 毫秒
101.
Coan TE Gao YS Liu F Maravin Y Stroynowski R Artuso M Boulahouache C Blusk S Bukin K Dambasuren E Moneti GC Mountain R Muramatsu H Nandakumar R Skwarnicki T Stone S Wang JC Mahmood AH Csorna SE Danko I Bonvicini G Cinabro D Dubrovin M McGee S Bornheim A Lipeles E Pappas SP Shapiro A Sun WM Weinstein AJ Briere RA Chen GP Ferguson T Tatishvili G Vogel H Adam NE Alexander JP Berkelman K Boisvert V Cassel DG Drell PS Duboscq JE Ecklund KM Ehrlich R Galik RS Gibbons L Gittelman B Gray SW Hartill DL 《Physical review letters》2003,90(10):101801
Using 13.8 fb(-1) of data collected at or just below the Upsilon(4S) with the CLEO detector, we report the result of a search for the flavor changing neutral current process D0-->gammagamma. We observe no significant signal for this decay mode and determine 90% confidence level upper limits on the branching fractions B(D0-->gammagamma)/B(D0-->pi(0)pi(0))<0.033 and B(D0-->gammagamma)<2.9 x 10(-5). 相似文献
102.
Thermally reversible formation of microspheres through non-covalent polymer cross-linking 总被引:3,自引:0,他引:3
Thibault RJ Hotchkiss PJ Gray M Rotello VM 《Journal of the American Chemical Society》2003,125(37):11249-11252
Bis-thymine units were used to noncovalently cross-link a complementary diamidopyridine-functionalized copolymer. Upon combination in noncompetitive solvents, discrete micron-scale spherical aggregates were formed arising from specific three-point polymer-cross-linker hydrogen bonding interactions. The diameter of these microspheres could be controlled through spacer structure. The cross-linking process was fully thermally reversible, with complete dissolution observed at 50 degrees C and reformation of the aggregates upon return to ambient temperature. This process could be repeated multiply, with lower particle dispersity observed arising from the annealing process. 相似文献
103.
Legrand YM Gray M Cooke G Rotello VM 《Journal of the American Chemical Society》2003,125(51):15789-15795
A series of flavins were synthesized bearing electron-withdrawing and -donating substituents. The electrochemical properties of these flavins in a nonpolar solvent were determined. The recognition of these flavins by a diamidopyridine (DAP) receptor and the effect this receptor has on flavin redox potential was also quantified. It was found that the DAP-flavin binding affinity and the reduction potentials (E(1/2)) for both the DAP-bound and unbound flavins correlated well with functions derived from linear free energy relationships (LFERs). These results provide insight and predictive capability for the interplay of electronics and redox state-specific interactions for both abiotic and enzymatic systems. 相似文献
104.
[reaction: see text] Mellitic triimides undergo three sequential one-electron reduction processes whose potentials are significantly lowered in the presence of alkyl thioureas. The two sequential reductions of benzene diimides are similarly stabilized. Calculation of the relative free energy change between the different electronic states of the imide acceptors and their corresponding alkyl thiourea complexes indicates dramatic increases in hydrogen bond strength with increasing acceptor charge density. 相似文献
105.
The resolving power of four reversed-phase-reversed-phase two-dimensional (2D) chromatographic systems was evaluated using information theory (IT) and a geometric approach to factor analysis. The first separation dimension employed a C18 column, while the second separation dimension employed a carbon clad zirconia column. Mobile phases in each dimension were either methanol or acetonitrile. The sample matrix that was employed in this study contained a mixture of 58 components, comprised of stereoisomers and structural isomers of a systematic variation in molecular weight. Each of the components were oligostyrenes, with between two and five configurational repeating units having either n-butyl, sec-butyl or tert-butyl end groups. In the two-dimensional systems employed in this study, between 46 and 49 of the 58 components could be separated, depending on the mobile phase combinations--with apparent resolution that could not possibly be achieved in a single one-dimensional separation. The results from this study indicate that in order to fully evaluate the resolving power of a 2D system multiple methods of analysis that evaluate the separation potential are most appropriate. This becomes increasingly important when the sample contains components that are very closely related and the retention of solutes displays a high degree of solute crowding. 相似文献
106.
We introduce and analyze a simple probabilistic cellular automaton which emulates the flow of cars along a highway. Our Traffic CA captures the essential features of several more complicated algorithms, studied numerically by K. Nagel and others over the past decade as prototypes for the emergence of traffic jams. By simplifying the dynamics, we are able to identify and precisely formulate the self-organized critical evolution of our system. We focus here on the Cruise Control case, in which well-spaced cars move deterministically at maximal speed, and we obtain rigorous results for several special cases. Then we introduce a symmetry assumption that leads to a two-parameter model, described in terms of acceleration () and braking () probabilities. Based on the results of simulations, we map out the (, ) phase diagram, identifying three qualitatively distinct varieties of traffic which arise, and we derive rigorous bounds to establish the existence of a phase transition from free flow to jams. Many other results and conjectures are presented. From a mathematical perspective, Traffic CA provides local, particle-conserving, one-dimensional dynamics which cluster, and converge to a mixture of two distinct equilibria. 相似文献
107.
K. G. Baigent D. A. Shaddock M. B. Gray D. E. McClelland 《General Relativity and Gravitation》2000,32(3):399-409
In order to measure the thermal noise of a mirror suspended in a vacuum it is necessary for the length measurement error due to intensity and frequency noise of the probe laser to be reduced below the thermal noise level. Here we report on an experiment to reduce the frequency and intensity noise of a 40mW Nd:YAG laser for this purpose. The frequency is stabilised using the standard reflection locking technique. To stabilise the laser intensity a technique which uses the properties of an in loop light field has been developed. This technique is capable of suppressing the intensity noise below the shot noise limit without reducing the useful laser power. A servo based on this technique has been designed and tested. The experimental results indicate that the laser noise can be reduced to a level which will allow a displacement sensitivity of 1.5 × 10-19m/
Hz for the detection of thermal noise in a frequency band of 10 to 500Hz. 相似文献
108.
Smith JG Alexander JP Baker R Bebek C Berger BE Berkelman K Blanc F Boisvert V Cassel DG Dickson M Drell PS Ecklund KM Ehrlich R Foland AD Gaidarev P Gibbons L Gittelman B Gray SW Hartill DL Heltsley BK Hopman PI Jones CD Kreinick DL Lohner M Magerkurth A Meyer TO 《Physical review letters》2000,84(7):1393-1397
We present the first observation of the decay B-->J/psistraight phiK. Using 9.6x10(6) B&Bmacr; meson pairs collected with the CLEO detector, we have observed ten fully reconstructed B-->J/psistraight phiK candidates, whereas the estimated background is 0.5+/-0.2 event. We obtain a branching fraction of B(B-->J/psistraight phiK) = (8. 8(+3.5)(-3.0)[stat]+/-1.3[syst])x10(-5). This is the first observed B meson decay requiring the creation of an additional s&smacr; quark pair. 相似文献
109.
Graeme W. Carlile Robert A. Keyzers Katrina A. Teske Renaud Robert David E. Williams Roger G. Linington Christopher A. Gray Ryan M. Centko Luping Yan Suzana M. Anjos Heidi M. Sampson Donglei Zhang Jie Liao John W. Hanrahan Raymond J. Andersen David Y. Thomas 《Chemistry & biology》2012,19(10):1288-1299
110.
Some comments are made concerning the multiple stationary-state patterns found in reaction-diffusion systems, including the Schlögl and Autocatalator models. 相似文献