Nonlocal conserved quantities,balance laws,and equations of motion

A formalism is developed whereby balance laws are directly obtained from nonlocal (integrodifferential) linear second-order equations of motion for systems described by several dependent variables. These laws augment the equations of motion as further useful information about the physical system and, under certain conditions, are shown to reduce to conservation laws. The formalism can be applied to physical systems whose equations of motion may be relativistic and either classical or quantum. It is shown to facilitate obtaining global conservation laws for quantities which include energy and momentum. Applications of the formalism are given for a nonlocal Schrödinger equation and for a system of local relativistic equations of motion describing particles of arbitrary integral spin.     

Quantum Lie Algebras, Their Existence, Uniqueness and q-Antisymmetry

Quantum Lie algebras are generalizations of Lie algebras which have the quantum parameter h built into their structure. They have been defined concretely as certain submodules of the quantized enveloping algebras . On them the quantum Lie product is given by the quantum adjoint action. Here we define for any finite-dimensional simple complex Lie algebra an abstract quantum Lie algebra independent of any concrete realization. Its h-dependent structure constants are given in terms of inverse quantum Clebsch-Gordan coefficients. We then show that all concrete quantum Lie algebras are isomorphic to an abstract quantum Lie algebra . In this way we prove two important properties of quantum Lie algebras: 1) all quantum Lie algebras associated to the same are isomorphic, 2) the quantum Lie product of any is q-antisymmetric. We also describe a construction of which establishes their existence. Received: 23 May 1996 / Accepted: 17 October 1996     

Time-resolved flash spectroscopic investigations of the reactions of singlet arylhalocarbenes

The results of time-resolved laser flash spectrometric studies of singlet arylhalocarbenes are reviewed. In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized. The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles. The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.