Thermodynamics of the xenon + methyl chloride system

The total vapour pressure of the xenon + methyl chloride system has been measured as a function of composition at 175.44 and 182.32 K. The resulting data have been used to evaluate the excess Gibbs functions G^E at the same temperatures. The excess enthalpy and excess molar volume have also been measured at 182.32 K. The system shows large positive deviations from Raoult's law but negative volumes on mixing. These results are compared with theoretical predictions of a recent molecular theory and of standard engineering methods. The calculations show the superiority of the molecular theory over more empirical procedures such as those based on the Redlich-Kwong equation of state or the regular-solution model.     

Intense circularly polarized waves in plasmas

The nonlinear propagation of an intense circularly polarized electromagnetic wave in a cold plasma is investigated. A relativistic modulational instability and an exact localized solutions are found.     

Molecular thermodynamics on the basis of an equation of state for argon. II. Binary mixtures of weakly nonspherical molecules

Using a molecular perturbation theory based on an equation of state for pure argon, excess properties and vapor-liquid equilibria are predicted for various binary mixtures composed of weakly nonspherical molecules. The results are rather satisfactory and generally much better than obtained using typical empirical methods. It is further demonstrated that a binary parameter in the dispersion energy results in only modest improvement     

Electrical properties of a-antimony selenide

This paper reports conduction mechanism in a-Sb₂Se₃ over a wide range of temperature (238 to 338 K) and frequency (5 Hz to 100 kHz). The d.c. conductivity measured as a function of temperature shows semiconducting behaviour with activation energy ΔE=0.42 eV. Thermally induced changes in the electrical and dielectric properties of a-Sb₂Se₃ have been examined. The a.c. conductivity in the material has been explained using modified CBH model. The band conduction and single polaron hopping is dominant above room temperature. However, in the lower temperature range the bipolaron hopping dominates.     

Absolute stereochemistry of the insect antifeedant cadinene from eupatorium adenophorum

Chemical correlation studies and application of Horeau's method establish the absolute stereochemistry of the major cadinene from $\text{E}$. $\text{adenophorum}$ as shown in {=1}.     

Self-consistent and quasiharmonic approximations: The equation of state and the high temperature lattice instability

The self-consistent average-phonon (SCAP) treatment, developed in earlier papers for monoatomic solids was extended to the alkali halides for which self-consistent calculations were not available. The quantitative comparison of SCAP with an average quaiharmonic (AQH) treatment for Ar and for NaCl showed that AQH highly overestimated the thermal pressure. Because of this overestimation, we conclude that the lattice instability reported by Boyer for NaCl, which he considered to be related to melting, is a consequence of using a quasiharmonic approximation.     

Study of solvent-solvent interaction by paper chromatography. I. Dimethyl sulphoxide-water system

Summary The interaction between dimethyl sulphoxide (DMSO) and water, occurring when the two liquids are mixed together, has been studied: 1. by the measurement of the rate of migration of the different solvent mixtures, over the whole concentration range, on paper chromatograms, and 2. by observing the paper chromatographic behaviour of hexacyanoferrate II anions when these mixtures are used as mobile phases. The rate of migration gives a very pronounced maximum at the solvent concentration which corresponds to the composition DMSO·H₂O. The chromatographic behaviour of the hexacyanoferrate II ion besides confirming this conclusion shows the existence of three distinct zones of differing solvent structure and solvating behaviour.     

Dielectric studies in dilute solutions

Dielectric studies in dilute solutions of cyclohexane and benzene have been carried out in the temperature range 294–318°K. The observed data have been utilized to evaluate the relaxation times and thermodynamic parameters of these molecules. The high values ofα for 2-acetyl pyridine indicate the occurrence of more than one relaxation time. In the remaining systems, the observed lowα values indicate their rigid behaviour. The variation in the dielectric relaxation time is mostly correlated with the change in the heterocyclic configuration of the system.