Ammonium violurate: a compact structure with extensive hydrogen bonding in three dimensions

The title compound [systematic name: ammonium pyrimidine‐2,4‐5,6(1H,3H)‐tetrone 5‐oximate], NH₄⁺·C₄H₂N₃O₄⁻, crystallizes from water in the triclinic space group P and is ismorphous with a known rubidium complex [Gillier (1965). Bull. Soc. Chim. Fr. pp. 2373–2384]. The principal feature of the structure is hydrogen bonding; each ammonium H atom acts as a bifurcated donor and three of the four violurate O atoms are bifurcated acceptors, with the fourth acting as a trifurcated acceptor. The pattern of hydrogen bonding around the cation is very similar to the rubidium coordination environment in the related structure. The violurate anions pack as hydrogen‐bonded crinkled tapes, which are linked and separated by the ammonium cations to give a compact three‐dimensional structure.     

Cognitive Demands and Second-Language Learners: A Framework for Analyzing Mathematics Instructional Contexts

The issues involved in teaching English language learners mathematics while they are learning English pose many challenges for mathematics teachers and highlight the need to focus on language-processing issues related to teaching mathematical content. Two realistic-type problems from high-stakes tests are used to illustrate the complex interactions between culture, language, and mathematical learning. The analyses focus on aspects of the problems that potentially increase cognitive demands for second-language learners. An analytical framework is presented that is designed to enable mathematics teachers to identify critical elements in problems and the learning environment that contribute to increased cognitive demands for students of English as a second language. The framework is proposed as a cycle of teacher reflection that would extend a constructivist model of teaching to include broader linguistic, cultural, and cognitive processing issues of mathematics teaching, as well as enable teachers to develop more accurate mental models of student learning.     

The effect of multiple optima on the simple GA run-time complexity

Genetic algorithms are stochastic search algorithms that have been applied to optimization problems. In this paper we analyze the run-time complexity of a genetic algorithm when we are interested in one of a set of distinguished solutions. One such case occurs when multiple optima exist. We define the worst case scenario and derive a probabilistic worst case bound on the number of iterations required to find one of these multiple solutions of interest.     

Dupin hypersurfaces with four principal Curvatures,II

If M is an isoparametric hypersurface in a sphere S ⁿ with four distinct principal curvatures, then the principal curvatures κ₁, . . . , κ₄ can be ordered so that their multiplicities satisfy m ₁ = m ₂ and m ₃ = m ₄, and the cross-ratio r of the principal curvatures (the Lie curvature) equals −1. In this paper, we prove that if M is an irreducible connected proper Dupin hypersurface in R ⁿ (or S ⁿ ) with four distinct principal curvatures with multiplicities m ₁ = m ₂ ≥ 1 and m ₃ = m ₄ = 1, and constant Lie curvature r = −1, then M is equivalent by Lie sphere transformation to an isoparametric hypersurface in a sphere. This result remains true if the assumption of irreducibility is replaced by compactness and r is merely assumed to be constant.      

Hölder continuity of the gradient of solutions of uniformly parabolic equations with conormal boundary conditions

Summary We study solutions of the conormal derivative problem for uniformly parabolic equations in divergence form. Under weak regularity hypotheses on the operator, the global Hölder continuity of the gradient of a weak solution is established. The method of proof is based on [5] and the results extend those in [7, Section V.7].Sponsored by the National Science Foundation under Grant DMS-8315545.     

Bioaccumulation and excretion of arsenic compounds by a marine unicellular alga,polyphysa peniculus

Polyphysa peniculus was grown in artificial seawater in the presence of arsenate, arsenite, monomethylarsonate and dimethylarsinic acid. The separation and identification of some of the arsenic species produced in the cells as well as in the growth medium were achieved by using hydride generation–gas chromatography–atomic absorption spectrometry methodology. Arsenite and dimethylarsinate were detected following incubation with arsenate. When the alga was treated with arsenite, dimethylarsinate was the major metabolite in the cells and in the growth medium; trace amounts of monomethylarsonate were also detected in the cells. With monomethylarsonate as a substrate, the metabolite is dimethylarsinate. Polyphysa peniculus did not metabolize dimethylarsinic acid when it was used as a substrate. Significant amounts of more complex arsenic species, such as arsenosungars, were not observed in the cells or medium on the evidence of flow injection–microwave digestion–hydride generation–atomic absorption spectrometry methodology. Transfer of the exposed cells to fresh medium caused release of most cell–associated arsenicals to the surrounding environment.     

Some Oscillatory Singular Integrals on Herz-type Spaces (Ⅱ)

In this paper, the authors prove that some oscillatory singular integral operators of non-convolution type with non-polynomial phases are bounded from the Herz-type Hardy spaces to the Herz spaces and from the Hardy spaces associated with the Beurling algebras to the Beurling algebras in higher dimensions, even though it is well-known that these operators are not bounded from the Hardy space H1(Rn) into the Lebesgue spaceL1(Rn).     

Rheological and diffusion properties of a dextran-con A polymer in the presence of Insulin and Magnesium

Previous work carried out in our laboratories has focused on the formation and investigation of a dextran and concanavalin A (con A) based gel, which has the ability to alter its conformational structure in the presence and absence of free and terminal glucoses such that a gel–sol phase transition occurs. Here we report the diffusion and rheological investigations in to the effects of the addition of insulin and varyingconcentrations of magnesium chloride hexahydrate (Mg₂Cl₂6H₂O) at 20 and 37 °C. Rheological examination of glucose-sensitive (dextran-con A) gels were conducted using a cone and plate viscometer used in continual rotation and oscillatory modes. The results are interpreted in terms of the structure of the gel network and suggest rheological assessment provides an effective method of assessing the properties of gel systems. The subsequent testing of such formulations in in-vitro diffusion experiments revealed a reduction in the rate of diffusivity in the insulin marker, poly R-478 dye. The performance of this self-regulating drug delivery system has been examined and the addition of insulin and magnesium chloride may alter the way in which the gel operates as a drug delivery device and in the delivery of insulin. This may have implications for other ligands.