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991.
992.
Weiwei Gao Shiyong Ye Mingwang Shao 《Journal of Physics and Chemistry of Solids》2011,72(9):1027-1031
Manganese oxide (Mn3O4) nanoparticles with average diameter of 15 nm were prepared using alcohol solution of manganese chloride as starting material via a facile solution-combusting method. The flame core zone was chosen to prepare mono-dispersed and high crystalline products, which were employed to modify glassy carbon electrode and detect dopamine via cyclic voltammetry. The results exhibited excellent electrochemical sensitivity. A linear relationship between the concentration of dopamine and its oxidation peak current was obtained by differential pulse voltammetry, which will find wide application in the biological detection. 相似文献
993.
994.
Jie Ju Yu Jin Li Jian Rong Gao Jian Hong Jia Liang Han Wei Jian Sheng Yi Xia Jia 《中国化学快报》2011,22(4):382-384
An aqueous solution of hydrogen peroxide and hydrogen bromide illuminated by a 60 W incandescent light bulb serves as a source of bromine radicals.Various substituted toluenes(NO2,Cl,Br,H,CH3) were high selectively brominated at the benzyl position for monobromination in CH2C12 at ice water with catalyst free.This simple but effective bromination of toluene derivatives with an aqueous H2O2-HBr system is characterized with the use of inexpensive reagents and a lower impact on the environment, which make it a good alternative to the existing bromination methods. 相似文献
995.
A novel approach to the synthesis of 4-phenylethynylphthalic anhydride has been described.The target compound was synthesized by Pd/Cu catalyzed Sonogashira coupling reaction between phenylacetylene and 4-bromophthalic acid which was for the first time employed as start material,followed by dehydration of 4-phenylethynylphthalic acid.Compared with traditional synthetic routes,this method provides several advantages such as readily available raw materials,convenient manipulation and high yield.The product... 相似文献
996.
L.H. KongY.L. Gao T.T. SongQ.J. Zhai 《Journal of magnetism and magnetic materials》2011,323(16):2165-2169
Structure and magnetic properties of Nb-doped (FeZrB)100−xNbx alloy are investigated by X-ray diffraction (XRD), differential scanning calorimetry and vibrating sample magnetometer. The fully amorphous structure of the as-quenched ribbons is confirmed by the XRD pattern. With increasing Nb, the glass transition temperature and the onset crystallization temperature are increased, indicating increased stability of the amorphous structure. For x=1, the saturation magnetization of the ribbons is 125.7 emu/g and the optimized annealing temperature increases from 550 to 630 °C. The morphology of the crystallized phases is observed by scanning electron microscopy. The results show that nanocrystalline α-Fe grains are dispersed in the amorphous matrix. 相似文献
997.
Experimental study has been performed on nanosecond (ns) laser ablation of silicon at 1064 nm, through which a so-called “multi-pulse enhancement effect” has been revealed, which has been rarely reported in literature. The major features of this effect are: (1) for multi-pulse laser ablation at the same spatial location, the ablation efficiency increases as the pulse number increases and the pulse-to-pulse temporal distance decreases; (2) for multi-pulse ablation performed sequentially at a group of locations, the ablation quality and efficiency starting from the second location can be significantly enhanced if the distance between adjacent locations is sufficiently small. Further study is needed to confirm and understand the underlying physical mechanism for the multi-pulse enhancement effect, which can be utilized to significantly improve the quality and efficiency of laser silicon micromachining using the low-cost and low-energy-consumption infrared ns lasers. This may decrease the cost and energy consumption of many relevant areas, such as the solar cell industry. 相似文献
998.
In this paper, we incorporate a limitation on the interaction range between neighboring vehicles into the cellular automaton model proposed by Gao and Jiang et al. [K. Gao, R. Jiang, S. X. Hu, B. H. Wang and Q. S. Wu, Phys. Rev. E 76 (2007) 026105], which was established within the framework of Kerner’s three-phase traffic theory and has been shown to be able to reproduce the three-phase traffic flow. This modification eliminates an unrealistic phenomenon found in the previous model, where the velocity-adaptation effect between neighboring vehicles can exist even if those vehicles are infinitely far away from each other. Therefore, in the improved model, we regulate that such interactions can only occur within a finite distance. For simplicity, we suppose a constant value to describe this distance in this paper. As a result, when compared to the previous model, the improved model mainly simulates the following results which are believed to be an improvement. (1) The improved model successfully reproduces the expected discontinuous transition from free flow to synchronized flow and the related “moving synchronized flow pattern”, which are both absent in the original model but have been observed in real traffic. (2) The improved model simulates the correlation functions, time headway distributions and optimal velocity functions which are all more consistent with the empirical data than the previous model and most of the other models published before. (3) Together with the previous two models considering the velocity-difference effect, this model finally accomplishes a significative process of developing traffic flow models from the traditional “fundamental diagram approach” to the three-phase traffic theory. This process should be helpful for us to understand the traffic dynamics and mechanics further and deeper. 相似文献
999.
1000.
Sturmfels offered 100 Swiss Francs in 2005 to a conjecture, which deals with a special case of the maximum likelihood estimation
for a latent class model. This paper confirms the conjecture positively. 相似文献