Relation between the Superconducting Transition Temperature and the Axial Ratio in R Ni 2 B 2 C ( R =Y,Ho, Er,Tm, Lu) Under High Pressure

The effect of pressure on the lattice parameters of R Ni 2 B 2 C ( R = Y, Ho, Er, Tm, Lu) has been measured in order to investigate the relation of T C to axial ratio c/a in the tetragonal lattice or the cohesive properties of these materials. The large anisotropies are observed in the lattice compression curves especially for R =Ho and Tm; the c -axis is more compressible than the a -axis. On the other hand, the anisotropy in the lattice compression is found to be relatively small for R =Y and Lu. The close relation between T C and c/a is pointed out particularly for R =Ho.     

Microstructure and magnetic property of electroless-plated CoNiFeB soft underlayer

An electroless-plated CoFeNiB film as a soft underlayer in perpendicular magnetic recording is studied by magneto-optical Kerr effect microscope, magnetic force microscopy (MFM), and transmission electron microscopy. A stray field is evidently suppressed for the anisotropic CoFeNiB film, which is under an applied field during the plating process. The lines of magnetic flux show that the Ni seed layer have no intrinsic effect on the homogenous magnetic state of the CoFeNiB layer. The interaction between a MFM tip and the CoFeNiB layer is clearly observed by electron holography indicating the excellent soft magnetic properties required by the soft underlayer.     

Fluorinated Vinylsilanes from the Copper‐Catalyzed Defluorosilylation of Fluoroalkene Feedstocks

Herein, a copper‐catalyzed C?F bond defluorosilylation reaction of tetrafluoroethylene and other polyfluoroalkenes is described. Mechanistic studies, based on a series of stoichiometric reactions with copper complexes, revealed that the key steps of this defluorosilylation reaction are 1) the 1,2‐addition of a silylcopper intermediate to the polyfluoroalkene and 2) a subsequent selective β‐fluorine elimination, which generates a Cu?F species. The β‐fluorine elimination is facilitated by Lewis acidic F?Bpin, which is generated in situ during the defluorosilylation.     

Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde

The formation of a nickeladihydrofuran by oxidative cyclization of an alkyne and an aldehyde with nickel(0) has been demonstrated; the transformation of the nickeladihydrofuran into an enone by decomposition, a lactone by carbonylation and an allylic alcohol by treatment with ZnMe(2) suggests that nickeladihydrofuran is an important key intermediate in a variety of catalytic reactions.     

Highly dispersed clay-polyolefin nanocomposites free of compatibilizers, via the in situ polymerization of alpha-olefins by clay-supported catalysts

In situ polymerization by certain transition metal catalysts supported on and activated by acid-treated montmorillonite produces well-dispersed clay-polyolefin nanocomposites, without requiring either organic surfactants to be present in the clay phase or modification of the polyolefin structure.     

Formation of acylruthenium promoted by coordination of AlMe(3) to (eta(4)-cyclopentadienone)Ru(CO)(3)

The reaction of AlMe(3) with (eta(4)-tetraphenylcyclopentadienone)Ru(CO)(3) leads to rapid and quantitative formation of an adduct arising from coordination of the enone oxygen to aluminium, which undergoes alkylation at the Ru(CO)(3) moiety to give (eta(5)-C(4)Ph(4)C(OAlMe(2)))Ru(CO)(2)(COMe) concomitant with a change of hapticity of the dienone ligand.     

Photoinduced tandem three-component coupling of propanedinitrile, 2,5-dimethylhexa-2,4-diene, and cyanoarenes

A tandem three-component coupling photoreaction proceeds upon photoirradiation of MeCN/H2O solutions containing propanedinitrile (1, malononitrile), 2,5-dimethylhexa-2,4-diene (2), and polycyanoarenes in the presence of phenanthrene and carbonate, leading to selective alpha-monoalkylation of 1. The reaction proceeds via photo-NOCAS (Nucleophile-Olefin Combination, Aromatic Substitution) type mechanism: nucleophilic attack of the anion of 1 to photogenerated 2(*+) is followed by ipso-substitution on the radical anion of the polycyanoarene. It advances under mild, safe, and environmentally friendly conditions such as proceeding at ambient temperature without metals and halogens, and in the presence of weak base. The reaction also represents a novel and metal-free cross-coupling reaction that leads to ipso-substitution on polycyanoarene via aryl-cyano bond cleavage. In addition, the reaction is a rare example of introducing carbon nucleophile in the photoinduced electron transfer reaction, except that of cyanide ion.     

Safety Evaluation of Far-UV-C Irradiation to Epithelial Basal Cells in the Corneal Limbus

Basal cells in the corneal limbus play an important role in the turnover cycle because they are the source of all cells that constitute the corneal epithelium. We examined the penetration depth of ultraviolet (UV) light in the corneal limbus and assessed the safety of Far-UV-C on stem cells in the basal area of the corneal limbus. Rats were irradiated with UV at peaks of 207, 222, 235, 254 and 311 nm while under anesthesia. The UV penetration depth in the rat corneal limbal epithelium was wavelength dependent: 311 nm UV-B and 254 nm UV-C reached the basal cells of the epithelium, and 235 nm radiation reached the middle area; however, 207 and 222 nm UV-C reached only the superficial layer of the epithelium. Porcine cornea, which is similar to the human eye in size and structure, were irradiated with 222 and 254 nm UV-C. As in rats, 222 nm UV-C reached only the superficial layer of the porcine corneal limbal epithelium. These results indicate that Far-UV-C, such as radiation of wavelengths of 207 and 222 nm, could not reach corneal epithelial stem cells, i.e. the cells remained intact. It is unlikely that the turnover of the corneal epithelium is obstructed or disrupted by exposure to Far-UV-C.