The structure of hypericin in solution. Searching for hypericin's 1,6 tautomer

Hypericin in organic solvents displays two types of electronic spectra: one type which shows a distinct solvatochromic effect, the stable form, and the other, the unstable form, which lacks this property. The latter type is formed in dry nonprotic solvents (e.g. tetrahydrofuran, EtOAc) and can be converted to the stable form on addition of protic solvents. In order to establish the tautomeric structure of the unstable form we applied conventional nuclear magnetic resonance techniques as well as two-dimensional gradient-enhanced heteronuclear multiple-quantum correlation, gradient-enhanced ROESY and one-dimensional nuclear Overhauser effect difference experiments. All these techniques pointed to the fact that the unstable form has the 7,14-diketo tautomeric structure, like the stable form, and not the 1,6-diketo structure. Electronic spectroscopy indicated that the unstable form has acidic properties and therefore possesses two free OH groups at C3 and C4 at the bay region of the molecule.     

Methanol to hydrocarbons: enhanced aromatic formation using a composite Ga2O3-H-ZSM-5 catalyst

Addition of beta-Ga2O3 to H-ZSM-5, as a physical mixture, enhances the formation of aromatic hydrocarbons in the methanol to hydrocarbons reaction.     

Ultrafast magnetization reversal dynamics investigated by time domain imaging

Spatiotemporal magnetization reversal dynamics in a Ni(80)Fe(20) microstructure is studied using ps time scale scanning Kerr microscopy. Time domain images reveal a striking change in the reversal associated with the reduction in switching time when a transverse bias field is applied. Magnetization oscillations subsequent to reversal are observed at two resonance frequencies, which sensitively depend on the bias field strength. The oscillation at f = 2 GHz is caused by the damped precession of M, while the lower frequency approximately 0.8 GHz mode is interpreted in terms of domain wall oscillation.     

Polarity inversion in polar-nonpolar-polar heterostructures

We have observed an epilayer-thickness-dependent polarity inversion for the growth of CdTe on Sb(Bi)/CdTe(111)B. For films with Sb(Bi) thicknesses of less than 40 A (15 A), the CdTe layer shows a B (Te-terminated) face, but it switches to an A (Cd-terminated) face for thicker layers. On the other hand, a CdTe layer grown on Bi(Sb)/CdTe(111)A always shows the A face regardless of Sb or Bi layer thicknesses. In order to address the observations we have performed ab initio calculations, which suggest that the polarity of a polar material on a nonpolar one results from the binding energy difference between the two possible surface configurations.     

One Cubic Diophantine Inequality

Suppose that G(x) is a form, or homogeneous polynomial, of odddegree d in s variables, with real coefficients. Schmidt [15]has shown that there exists a positive integer s₀(d), whichdepends only on the degree d, so that if s s₀(d), then thereis an x Z^s\{0} satisfying the inequality |G(x)|<1. (1) In other words, if there are enough variables, in terms of thedegree only, then there is a nontrivial solution to (1). Lets₀(d) be the minimum integer with the above property. In thecourse of proving this important result, Schmidt did not explicitlygive upper bounds for s₀(d). His methods do indicate how todo so, although not very efficiently. However, in fact muchearlier, Pitman [13] provided explicit bounds in the case whenG is a cubic. We consider a general cubic form F(x) with realcoefficients, in s variables, and look at the inequality |F(x)|<1. (2) Specifically, Pitman showed that if s(1314)²⁵⁶–1, (3) then inequality (2) is non-trivially soluble in integers. Wepresent the following improvement of this bound.     

Ultrafast magneto-optics in nickel: magnetism or optics?

Several magnetic and optical processes contribute to the magneto-optical response of nickel thin films after excitation by a femtosecond laser pulse. We achieved a first complete identification by explicitly measuring the time-resolved Kerr ellipticity and rotation, as well as its temperature and magnetic field dependence in epitaxially grown (111) and (001) oriented Cu/Ni/Cu wedges. The first hundreds of femtoseconds the response is dominated by state filling effects. The true demagnetization takes approximately 0.5-1 ps. At the longer (sub-ns) time scales the spins are found to precess in their anisotropy field. Simple and transparent models are introduced to substantiate our interpretation.     

Progress in direct-drive inertial confinement fusion research at the laboratory for laser energetics

Direct-drive inertial confinement fusion (ICF) is expected to demonstrate high gain on the National Ignition Facility (NIF) in the next decade and is a leading candidate for inertial fusion energy production. The demonstration of high areal densities in hydrodynamically scaled cryogenic DT or D₂ implosions with neutron yields that are a significant fraction of the “clean” 1-D predictions will validate the ignition-equivalent direct-drive target performance on the OMEGA laser at the Laboratory for Laser Energetics (LLE). This paper highlights the recent experimental and theoretical progress leading toward achieving this validation in the next few years. The NIF will initially be configured for X-ray drive and with no beams placed at the target equator to provide a symmetric irradiation of a direct-drive capsule. LLE is developing the “polar-direct-drive” (PDD) approach that repoints beams toward the target equator. Initial 2-D simulations have shown ignition. A unique “Saturn-like” plastic ring around the equator refracts the laser light incident near the equator toward the target, improving the drive uniformity. LLE is currently constructing the multibeam, 2.6-kJ/beam, petawatt laser system OMEGA EP. Integrated fast-ignition experiments, combining the OMEGA EP and OMEGA Laser Systems, will begin in FY08.     

Elektroanalyse

Ohne Zusammenfassung