全文获取类型
收费全文 | 5334篇 |
免费 | 185篇 |
国内免费 | 19篇 |
专业分类
化学 | 3234篇 |
晶体学 | 23篇 |
力学 | 280篇 |
数学 | 973篇 |
物理学 | 1028篇 |
出版年
2023年 | 53篇 |
2022年 | 51篇 |
2021年 | 160篇 |
2020年 | 131篇 |
2019年 | 115篇 |
2018年 | 116篇 |
2017年 | 109篇 |
2016年 | 251篇 |
2015年 | 175篇 |
2014年 | 171篇 |
2013年 | 311篇 |
2012年 | 304篇 |
2011年 | 337篇 |
2010年 | 202篇 |
2009年 | 184篇 |
2008年 | 317篇 |
2007年 | 302篇 |
2006年 | 243篇 |
2005年 | 257篇 |
2004年 | 189篇 |
2003年 | 175篇 |
2002年 | 131篇 |
2001年 | 65篇 |
2000年 | 60篇 |
1999年 | 60篇 |
1998年 | 42篇 |
1997年 | 38篇 |
1996年 | 62篇 |
1995年 | 48篇 |
1994年 | 50篇 |
1993年 | 39篇 |
1992年 | 28篇 |
1991年 | 33篇 |
1990年 | 32篇 |
1989年 | 38篇 |
1988年 | 29篇 |
1987年 | 46篇 |
1986年 | 29篇 |
1985年 | 46篇 |
1984年 | 43篇 |
1983年 | 27篇 |
1982年 | 30篇 |
1981年 | 33篇 |
1980年 | 39篇 |
1979年 | 26篇 |
1978年 | 24篇 |
1977年 | 37篇 |
1976年 | 13篇 |
1975年 | 20篇 |
1974年 | 16篇 |
排序方式: 共有5538条查询结果,搜索用时 328 毫秒
31.
Andrea Lodi Monica Caselli Alessandro Casnati Fabio Momicchioli Francesco Sansone Davide Vanossi Glauco Ponterini 《Journal of Molecular Structure》2007,846(1-3):49-54
The sulfonated calixarene I8C12 acts as a host for homologous merocyanines Mc1 and Mc2 in organic solvents, exhibiting neither selectivity towards the guest dyes nor solvent dependence of the complexation equilibria. In water, on the contrary, only the lower homologue, Mc1, is solubilized in the presence of the calixarene. A combination of UV–visible and fluorescence spectroscopic and photophysical analysis and MD structural simulation of the calixarene-dye complexes was employed to account for the observations, and suggests that a radical change in the complexation mode occurs upon moving from an organic to an aqueous environment. 相似文献
32.
Paolo Battocchio Francesco Menoncin Olivier Scaillet 《Annals of Operations Research》2007,152(1):141-165
In a financial market with one riskless asset and n risky assets whose prices are lognormal, we solve in a closed form the problem of a pension fund maximizing the expected
CRRA utility of its surplus till the (stochastic) death time of a representative agent. We consider a unique asset allocation
problem for both accumulation and decumulation phases. The optimal investment in the risky assets must decrease during the
first phase and increase during the second one. We accordingly suggest it is not optimal to manage the two phases separately,
and outsourcing of allocation decisions should be avoided in both phases.
JEL: G23, G11
MSC 2000: 62P05, 91B28, 91B30, 91B70, 93E20 相似文献
33.
Beverina L Abbotto A Landenna M Cerminara M Tubino R Meinardi F Bradamante S Pagani GA 《Organic letters》2005,7(19):4257-4260
[graph: see text] Condensation of squaric acid with a number of differently substituted 2-pyrrolyl derivatives afforded three new classes of squaraines. Their sharp and intense absorption bands in the biological window (700-900 nm), inherent singlet oxygen generation capabilities, together with proper functionalization allowing good water solubility make them suitable candidates as new non-porphyrinic singlet oxygen photosensitizers for photodynamic therapy (PDT). 相似文献
34.
Francesco De Sarlo Antonio Guarna Andrea Goti Alberto Brandi 《Journal of organometallic chemistry》1984,269(2):115-121
Organomercury fulminates react with acetylene derivatives to give unstable 3-(organomercurio)isoxazoles, which isomerize to 2-cyanoenolates. These are hydrolyzed with hydrochloric acid to the corresponding enols and are cleaved by water at the double bond. With monosubstituted acetylenes, substitution at the free position by the organomercury residue is predominant. 相似文献
35.
Francesco Ghetti Giuliano Colombetti Francesco Lenci Enzo Campani Erseo Polacco Maurizio Quaglia 《Photochemistry and photobiology》1985,42(1):29-33
Abstract— The spectroscopic characterization of the photoreceptor pigment is one of the main questions in the study of the photosensory transduction chains in photomotile microorganisms. One of the possible techniques that can be used is in vivo microspectrofluorometry. By means of a tunable dye-laser microspectrofiuorometer developed by us, we have investigated some of the spectroscopic properties of the photoreceptor pigment of the green flagellate Euglena gracilis. The in vivo fluorescence excitation spectrum has been determined and the fluorescence quantum yield has been measured. The results show that flavins are indeed present in the paraflagellar body of E. gracilis and that their fluorescence quantum yield is much lower than that of a free flavin. An estimate of the order of magnitude of the rate constants for primary molecular reactions is tentatively given. 相似文献
36.
A. Torrisi P. Horák J. Vacík A. Cannavò G. Ceccio J. Vaniš 《Phosphorus, sulfur, and silicon and the related elements》2020,195(11):932-935
AbstractOn the perspective to develop CuO–TiO2 MOS, multilayered Cu and Ti thin layers were alternatively deposited on silicon wafers using 25?keV Ar?+?ion beam sputtering and, subsequently, oxidized by thermal annealing in air at 400?°C for 24?h. The deposited films have variable ratios of the Cu and Ti % at. One of the main goal is to obtain such multilayers avoiding the presence of Cu–Ti–O compounds. The samples were characterized in terms of composition (by RBS and SIMS analyses) and morphology (by AFM and SEM investigations). In particular, SIMS maps allows to observe the spatial distribution and thickness of each phase of the Cu/Ti multilayers, and further to observe Cu diffusion and mixing with Ti, as well as phase separation of CuO and TiO2 in the samples. The reasons of this effect represent an open issue that has to investigated, in order to improve the MOS fabrication. 相似文献
37.
38.
Alessandro Boido Francesco Savelli Fernando Sancassan 《Journal of heterocyclic chemistry》1997,34(5):1643-1644
Following a previous experiment, an original heteropolycyclic structure 4 was obtained by a reaction of chloroacetyl chloride with compound 3 bearing a conjugated double bond system. The condensation develops with an initial NH-chloroacetylation and ring closure by quaternarization of the pyridine nitrogen. This is achieved through an 1,4 -cycloaddition of chloroketene to make a pyranone ring. 相似文献
39.
Marino Cavazza Gioia Morganti Antonio Guerriero Francesco Pietra 《Tetrahedron letters》1980,21(38):3703-3704
EtO? in DMSO adds to ethylthiopicrate at C-3 to generate an ephemeral -adduct which ends into 1-ethylthio-4-ethoxy-2,5-dinitrobenzene, whilst ethyl picrate gives two adducts of attack of EtS? at C-3 or C-1. 相似文献
40.
Hypocotyl growth in etiolated seedlings of wild-type and an aurea mutant of tomato (Lycopersicon esculenturn Mill.), that appears to be deficient in labile phytochrome, is strongly inhibited by UV radiation in the region of 300–400 nm. The role of phytochrome in the UV-mediated inhibition of hypocotyl growth was studied using different experimental approaches: (1) by comparing the effectiveness of treatments of increasing duration of exposure to 692 nm and UV radiation; (2) by modifying the UV spectral range with specific cut-off filters. The experimental results suggest that the UV-induced inhibition of growth in wild-type tomato is mediated to a large extent by the longer wavelengths of the UV-A region and is mediated mainly by phytochrome. In contrast, at wavelengths < 305 nm a strong UV-B effect was found in the aurea mutant, suggesting a preeminent action of a specific UV-B absorbing photoreceptor that displays less action in the wild-type. 相似文献