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D. Charalambidis B. H. Feng C. Fotakis 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1989,14(3):223-227
Photoelectron angular distributions have been measured for the three-photon resonant one-photon ionization, (3+1), of Xe via the 7s[1 1/2]0 1 and 8s[1 1/2]0 1 states. The results are in good agreement with the theoretical predictions of Tang and Lambropoulos [13] for the 8s[1 1/2]0 1, but not for the 7s[1 1/2]0 1 state. Furthermore, the results are compared to those which have been obtained by Blazewicz et al. [1] for the three-photon resonant two-photon ionization, (3+2), of Xe via the 6s[1 1/2]0 1 state. 相似文献
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Isomeric structures and energies of three kinds of lithofluorosilylenoids, R2SiLiF (R = NH2, OH, F) were studied using theab initio molecular orbital theory. The calculations show that thermal stability of the three-membered ring structures of these three
kinds of silylenoids decreases in the order of substituents NH2 > OH > F because of the conjugation between NH2, OH or F and Si atom. The interaction of substituents R with Li atom makes R2SiLiF have a structure with two Li-A-Si-F (A = N, O, F) four-membered rings, which is the most stable of the isomers of each
of three kinds of silylenoids and whose stability decreases in the order of substituents F > OH > NH2. Inductive effect of substituents influences the thermal stability of the linear structure of silylenoids. 相似文献
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高效液相色谱手性流动相添加剂法拆分酪氨酸甲酯对映体 总被引:2,自引:0,他引:2
分别将β-环糊精、羟丙基-β-环糊精作为手性流动相添加剂,研究了酪氨酸甲酯对映体在反相HPLC系统中的拆分,考察了流动相种类、pH和手性流动相添加剂浓度对手性拆分的影响,建立了β-环糊精手性流动相添加剂法拆分酪氨酸甲酯对映体的方法。 相似文献
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The 1205 classical isomers of fullerene C58, as well as one quasi-fullerene C58 isomer with a heptagonal ring (labeled as Cs:hept) have been investigated by the quantum chemical methods PM3, HCTH/3-21G, and B3LYP/6-31G(d). Isomer C3v:0001, which has the lowest number of adjacent pentagons, is predicted to be the most stable isomer, but the quasi-fullerene isomer Cs:hept is only 2.50 kcal mol-1 higher in energy. Systematic investigations of the electronic properties of C3v:0001 and Cs:hept find that the C3v:0001 isomer has high vertical electron affinity (3.19 eV). The nucleus-independent chemical shifts (NICS) value at the center of Cs:hept (-5.1 ppm) is more negative than that of C60 (-2.8 ppm). The NICS value at the center of the heptagonal ring in Cs:hept (-2.5 ppm) indicates weakly aromatic character. In contrast, the C58(6-) and C58(8-) ions of the C3v:0001 and Cs:hept geometries possess large aromatic character, with NICS values between -14.0 and -26.2 ppm. To clarify the thermodynamic stabilities of C58 isomers at different temperatures, the entropy contributions are taken into account on the basis of the Gibbs energy at the B3LYP/6-31G(d) level. The C3v:0001 isomer prevails in a wide range of temperatures, and the Cs:hept isomer is also an important component around 2800 K. The IR spectra of C58 isomers are simulated to facilitate experimental identification of different isomers. In addition, the electronic spectra and the second-order hyperpolarizabilities are predicted by ZINDO and the sum-over-states model. The static second-order hyperpolarizability of the C3v:0001 isomer is 96.5 % larger than that of C60, and its second-order hyperpolarizabilities at external field frequencies are at least nine times larger than those of C60. 相似文献
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Journal of Optimization Theory and Applications - This paper is to establish a sufficient maximum principle for one kind of stochastic optimal control problem with three types of delays: a discrete... 相似文献
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A full-wave solution is presented for the waveguide to microstrip transition. The exact Green's function of the transition is used in a moment method procedure. The behavior of the microstrip transition to a rectangular waveguide is studied with respect to the critical dimensions of the microstrip width, length and backshort location. The convergence characteristics of the full wave analysis method are investigated, along with the current distribution and the input impedance. Results given for the return loss is compared with measurements. 相似文献