Synthesis and optoelectronic properties of silole‐containing polyfluorenes with binary structures

2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high M_w up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007     

On Two Parallel Matched Gratings Demodulation Method of Fiber Grating Strain Sensor

The method of demodulation with two parallel matched fiber Bragg gratings( FBGs)system is introduced to enlarge the range of strain that can be detected by the FBG sensor system.     

On the structure of stationary sets

We isolate several classes of stationary sets of [k]ωand investigate implications among them. Under a large cardinal assumption, we prove a structure theorem for stationary sets.     

Fuzzy Model of Regional Economic Competitiveness in GIS Spatial Analysis: Case Study of Gansu, Western China

After more than 20 years of impressive development since the economic reforms in 1978, today western China is facing an increasing development gap between its regions, particularly between urban and rural areas. Using the fuzzy comprehensive evaluation model, this paper aims to demonstrate the evolution of the economic competitiveness levels base on two categories of geographical unity in the province of Gansu located in Northwest China between 2000 and 2004. The results of fuzzy modeling are integrated into GIS spatiotemporal analyses in order to identify the spatial variation of each significant change in terms of the regional economic development. Our research effectively illustrates that there is a particular spatial dynamic of the economic development from region to region. Although the cities have improved very well in their economic competitiveness, the rural areas and minority regions still have a lot of progress to be achieved.     

综合网管中基于模型驱动的元数据管理

提出了一种基于模型驱动的元数据管理方案．方案采用了基于模型的形式化描述方法，统一了专业网管子系统间的元数据模式；通过引入模型驱动技术，从元模型的抽象层次消除了不同专业网管子系统之间存在的“信息孤岛”；方案还对综合网管环境下的元数据理论和交换机制进行了研究，并给出了元数据的管理框架以及元数据交换的Java接口映射．     

Hydrothermal synthesis of FeS2 for lithium batteries

Nanocrystalline FeS₂ cathode material of lithium cell was synthesized from cheap materials of FeSO₄, Na₂S₂O₃, and sulfur by a hydrothermal process. The scanning electron microscopy analysis showed the obtained material was nano-sized, about 500 nm. The X-ray powder diffraction analysis showed that the synthetic FeS₂ material had two phases of the crystalline structure, pyrite and marcasite. The phase of marcasite seems to have no negative effect on the electrochemical performance of the material. The synthetic FeS₂ showed a significant improvement of electrochemical performance for Li/FeS₂ cells.     

Measurability criteria for fuzzy random vectors

Fuzzy random vector is a measurable map from a probability space to a collection of fuzzy vectors. Our aim in this paper is to discuss the measurability criteria for fuzzy random vectors, and show that under mild assumption, the measurability criteria for upper semicontinuous fuzzy random vectors can be expressed in several different but equivalent formulations. Finally, applying the obtained results, we resolve an open problem about the relationship between fuzzy random vectors and fuzzy random variables.     

Analysis of Metabolites in Allantoic Fluid of Chicken Embryo by 900 MHz NMR Spectroscopy

900 MHz ¹H NMR (nuclear magnetic resonance) spectroscopy was used to analyze metabolites in allantoic fluid of the chicken embryo in the 9th incubation day without any chemical or physical sample separation. The result showed that superhigh spectral dispersion and sensitivity at 900 MHz are useful in directly analyzing a complex mixture, particularly in resolving the overlapped NMR resonances. In this study, we had assigned 61 metabolites and 26 chemical fragments in the allantoic fluid. The relative concentrations of the major metabolites were also measured. Among the assigned metabolites, some were detected by NMR in chicken embryo allantoic fluids for the first time. The biological functions of these compounds were briefly discussed. Authors' address: Maili Liu, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, People's Republic of China     

负折射指数物质中金属线对电磁波的影响

构造两种结构负折射指数物质(NRM)，利用数值模拟计算两种结构的S参数.由于这种结构尺度比波长小，为精确利用有限积分技术(FIT)进行模拟.通过对这两种结构中金属线位置变化对金属谐振频率影响进行模拟，最后得出由于金属线与谐振环耦合，金属线对称破缺影响谐振环谐振频率和通带，并对等效负折射指数为负的频带产生影响. 关键词： 负折射率 左手物质 通带 金属线对称破缺